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  1. Article ; Online: Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties.

    Dominic C D, Midhun / Joseph, Rani / Sabura Begum, P M / Raghunandanan, Aswathy / Vackkachan, Nelwin T / Padmanabhan, Dileep / Formela, Krzysztof

    Carbohydrate polymers

    2020  Volume 245, Page(s) 116505

    Abstract: ... of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based ... into chitin nanowhiskers - promising green filler in NBR for high-performance elastomeric applications. ... In this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells ...

    Abstract In this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength of nanocomposites by 116 % and 54 %, which was related to suitable dispersion of chitin nanowhiskers in matrix. Reinforcing effect of chitin nanowhiskers in acrylonitrile-butadiene rubber was also confirmed by Wolff activity coefficient, glass transition temperature and equilibrium swelling measurements. Moreover, it was found that higher content chitin nanowhiskers significantly improve the thermal stability of studied nanocomposites. The incorporation of chitin nanowhiskers resulted in increase of 74 °C for onset degradation temperature. This work confirmed that shrimp shell waste can be upcycled into chitin nanowhiskers - promising green filler in NBR for high-performance elastomeric applications.
    MeSH term(s) Acrylonitrile/chemistry ; Animal Shells/chemistry ; Animals ; Butadienes/chemistry ; Chitin/chemistry ; Elasticity ; Hydrolysis ; Nanocomposites/chemistry ; Penaeidae/chemistry ; Rubber/chemistry ; Tensile Strength ; Transition Temperature
    Chemical Substances Butadienes ; Chitin (1398-61-4) ; Rubber (9006-04-6) ; Acrylonitrile (MP1U0D42PE)
    Keywords covid19
    Language English
    Publishing date 2020-06-02
    Publishing country England
    Document type Journal Article
    ZDB-ID 1501516-6
    ISSN 1879-1344 ; 0144-8617
    ISSN (online) 1879-1344
    ISSN 0144-8617
    DOI 10.1016/j.carbpol.2020.116505
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties

    Dominic C.D., Midhun / Joseph, Rani / Sabura Begum, P.M. / Raghunandanan, Aswathy / Vackkachan, Nelwin T. / Padmanabhan, Dileep / Formela, Krzysztof

    Carbohydr Polym

    Abstract: ... of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based ... into chitin nanowhiskers - promising green filler in NBR for high-performance elastomeric applications. ... In this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells ...

    Abstract In this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength of nanocomposites by 116% and 54%, which was related to suitable dispersion of chitin nanowhiskers in matrix. Reinforcing effect of chitin nanowhiskers in acrylonitrile-butadiene rubber was also confirmed by Wolff activity coefficient, glass transition temperature and equilibrium swelling measurements. Moreover, it was found that higher content chitin nanowhiskers significantly improve the thermal stability of studied nanocomposites. The incorporation of chitin nanowhiskers resulted in increase of 74 °C for onset degradation temperature. This work confirmed that shrimp shell waste can be upcycled into chitin nanowhiskers - promising green filler in NBR for high-performance elastomeric applications.
    Keywords covid19
    Publisher Elsevier; PMC
    Document type Article ; Online
    DOI 10.1016/j.carbpol.2020.116505
    Database COVID19

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