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Article ; Online: Are your IT staff ready for the pandemic-driven insider threat?

Chapman, Phil

Network Security

Abstract: ... so heavily on recruiting graduates and rather looked towards hiring apprentices, argues Phil Chapman ...

Abstract	As this article is being written it's mid-March. The situation likely will have changed significantly by the time you read this, as it does by the day and even the hour. The World Health Organisation (WHO) has declared Covid-19 to be a global pandemic and the UK Government has stepped up its response from the ‘contain’ to the ‘delay’ phase. Public spaces and transport are noticeably quieter and many workplaces are getting emptier as staff members work from home. The Covid-19 pandemic and consequent lockdowns are hitting businesses hard. And as workforces move to remote working, IT departments are under pressure. At the same time, cyber criminals are exploiting the pandemic, with rises in phishing and other forms of attacks. The cyber security workforce, already suffering a skills crisis, may lack the soft skills required to effectively tackle these issues, many of which could be solved if the industry didn't rely so heavily on recruiting graduates and rather looked towards hiring apprentices, argues Phil Chapman of Firebrand Training.
Keywords	covid19
Publisher	Elsevier; PMC
Document type	Article ; Online
DOI	10.1016/s1353-4858(20)30042-8
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Article: DNA metabarcoding of the phytoplankton of Great Salt Lake’s Gilbert Bay: Spatiotemporal assemblage changes and comparisons to microscopy

Brown, Phil D. / Craine, Joseph M. / Richards, David / Chapman, Andrew / Marden, Brad

International Association for Great Lakes Research Journal of Great Lakes research. 2022 Feb., v. 48, no. 1

2022

Abstract: The Great Salt Lake (GSL) is a unique hypersaline system with an understudied phytoplankton assemblage supporting a productive open water ecosystem in the largest embayment of the lake, Gilbert Bay. Determination of phytoplankton by microscopy has ... ...

Abstract	The Great Salt Lake (GSL) is a unique hypersaline system with an understudied phytoplankton assemblage supporting a productive open water ecosystem in the largest embayment of the lake, Gilbert Bay. Determination of phytoplankton by microscopy has practical limitations that can constrain the scope of a study, but DNA metabarcoding may improve upon this through higher taxonomic resolution and the capacity to generate a large volume of assemblage data in comparatively little time. To determine if metabarcoding could replicate microscopy and expand the assessment of GSL phytoplankton, a 23S SSU rRNA metabarcoding and microscopy survey of Gilbert Bay was conducted in 2017 and 2018. Assemblage composition and relative abundances from each method were compared, and spatial and temporal assemblage changes from metabarcoding data were investigated using non-metric multidimensional scaling. Metabarcoding differed from microscopy in multiple taxonomic assignments and relative abundances, with poor correlation for most categories. Diatoms were overrepresented by metabarcoding relative to microscopy, and chlorophytes underrepresented. However, metabarcoding revealed seasonal and spatial patterns in assemblage, detected seasonal patterns within phytoplankton sequences of very low abundance, and detected potential cryptic speciation within the lake’s dominant Dunaliella viridis. Phylogenetic analysis revealed greater phytoplankton diversity than observed before in GSL, but demonstrated the need to improve taxonomic assignment of the resulting sequences, particularly within the diatoms. The expansion of detectable diversity and isolation of DNA sequences that can be traced through time and analyzed against environmental variables make metabarcoding a potentially effective tool for parallel use with microscopy in future GSL research.
Keywords	DNA barcoding ; Dunaliella ; cryptic speciation ; ecosystems ; hypersalinity ; lakes ; microscopy ; phylogeny ; phytoplankton ; research ; surveys ; Great Salt Lake
Language	English
Dates of publication	2022-02
Size	p. 110-124.
Publishing place	Elsevier B.V.
Document type	Article
ZDB-ID	2163239-X
ISSN	0380-1330 ; 0380-1330
ISSN (online)	0380-1330
ISSN	0380-1330
DOI	10.1016/j.jglr.2021.10.016
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Quantitative biomonitoring of polycyclic aromatic compounds (PACs) using the Sydney rock oyster (Saccostrea glomerata).

Idowu, Oluyoye / Tran, Thi Kim Anh / Webster, Grant / Chapman, Ian / Baker, Phil / Farrel, Hazel / Zammit, Anthony / Semple, Kirk T / Hansbro, Phil M / O'Connor, Wayne / Thavamani, Palanisami

The Science of the total environment

2020 Volume 742, Page(s) 140497

Abstract: Increasing our understanding of the bioavailable fractions of polycyclic aromatic compounds (PACs) in an aquatic environment is important for the assessment of the environmental and human health risks posed by PACs. More importantly, the behaviour of ... ...

Abstract	Increasing our understanding of the bioavailable fractions of polycyclic aromatic compounds (PACs) in an aquatic environment is important for the assessment of the environmental and human health risks posed by PACs. More importantly, the behaviour of polar polycyclic aromatic hydrocarbons (polar PAHs), which are metabolites of legacy PAHs, are yet to be understood. We, therefore, carried out a study involving Sydney rock oysters (Saccostrea glomerata) sourced from two locations, that had been exposed to PAH contamination, within an Australian south-east estuary. Biomonitoring of these oysters, following relocation from the estuary to a relatively isolated waterway, was done at 24 and 72 h after deployment and subsequently at 7, 14, 28, 52 and 86 days. Control samples from Camden Haven River were sampled for PAC analyses just before deployment, after 28 days and at the end of the study (day 86). Lipid-normalised concentrations in oyster tissues across the 86-day sampling duration, elimination rate constants (k
MeSH term(s)	Animals ; Australia ; Biological Monitoring ; Environmental Monitoring ; Humans ; Ostreidae ; Polycyclic Aromatic Hydrocarbons/analysis ; Polycyclic Compounds/analysis ; Water Pollutants, Chemical/analysis
Chemical Substances	Polycyclic Aromatic Hydrocarbons ; Polycyclic Compounds ; Water Pollutants, Chemical
Language	English
Publishing date	2020-06-25
Publishing country	Netherlands
Document type	Journal Article
ZDB-ID	121506-1
ISSN	1879-1026 ; 0048-9697
ISSN (online)	1879-1026
ISSN	0048-9697
DOI	10.1016/j.scitotenv.2020.140497
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Article ; Online: Neural effects of a single dose of fluoxetine on resting-state functional connectivity in adolescent depression.

Capitão, Liliana P / Chapman, Robert / Filippini, Nicola / Wright, Lucy / Murphy, Susannah E / James, Anthony / Cowen, Phil J / Harmer, Catherine J

Journal of psychopharmacology (Oxford, England)

2020 Volume 34, Issue 12, Page(s) 1461–1465

Abstract: Fluoxetine is commonly prescribed in adolescent depression, but the neural mechanisms underlying its action remain poorly understood. Here, we used resting-state functional magnetic resonance imaging to investigate the effects of a single dose of ... ...

Abstract	Fluoxetine is commonly prescribed in adolescent depression, but the neural mechanisms underlying its action remain poorly understood. Here, we used resting-state functional magnetic resonance imaging to investigate the effects of a single dose of fluoxetine vs. placebo in adolescents with major depressive disorder. In contrast with previous studies in adults that have demonstrated an acute effect of antidepressants on activity within the default mode network, a single dose of fluoxetine did not alter activity in this network in adolescent depression. There were unexpected group activity differences in the motor network, which should be clarified in future research.
MeSH term(s)	Adolescent ; Cerebral Cortex/diagnostic imaging ; Cerebral Cortex/drug effects ; Cerebral Cortex/physiopathology ; Connectome ; Default Mode Network/diagnostic imaging ; Default Mode Network/drug effects ; Default Mode Network/physiopathology ; Depressive Disorder, Major/diagnostic imaging ; Depressive Disorder, Major/drug therapy ; Depressive Disorder, Major/physiopathology ; Female ; Fluoxetine/administration & dosage ; Fluoxetine/pharmacology ; Humans ; Magnetic Resonance Imaging ; Male ; Serotonin Uptake Inhibitors/administration & dosage ; Serotonin Uptake Inhibitors/pharmacology
Chemical Substances	Serotonin Uptake Inhibitors ; Fluoxetine (01K63SUP8D)
Language	English
Publishing date	2020-11-04
Publishing country	United States
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	639313-5
ISSN	1461-7285 ; 0269-8811
ISSN (online)	1461-7285
ISSN	0269-8811
DOI	10.1177/0269881120959608
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Article ; Online: The ability of a potassium oxalate gel strip to occlude human dentine tubules; a Novel in vitro: In situ Study.

Chapman, Nicholas R / Jones, Siân Bodfel / Bahal, Priya / He, Tao / Drake, Phil / Zou, Yuanshu / West, Nicola X

Journal of dentistry

2020 Volume 100, Page(s) 103437

Abstract: Objectives: To determine if an oxalate strip reduced fluid flow in dentine samples and whether this reduction was maintained following a 14 day intra-oral period.: Methods: Dentine tubule fluid flow was measured by a modified Pashley cell in 40 acid- ... ...

Abstract	Objectives: To determine if an oxalate strip reduced fluid flow in dentine samples and whether this reduction was maintained following a 14 day intra-oral period. Methods: Dentine tubule fluid flow was measured by a modified Pashley cell in 40 acid-etched dentine discs 1 mm thick, diameter >10 mm, with an acquired pellicle, pre-equilibrated with Hartmann's solution and conditioned by toothbrushing, pre and post treatment (10 min) with an oxalate (3.14 %) gel strip or no treatment. One control and one test sample were exposed in-situ for 14 days to the oral environment in 20 healthy adult volunteers, and fluid flow re-measured. The appliance containing the two samples was removed for brushing with water after mealtimes when the participant brushed their teeth and for a 2 min daily soak in chlorhexidine. Results: Fluid flow rate was reduced significantly immediately following treatment with the oxalate strip compared to baseline flow rate by 58 %. Following 14 days in-situ oral environment phase, a significant further reduction in fluid flow compared to baseline was identified in both control and oxalate strip treated samples, both (p < 0.0001), but the reduction was greater in the test samples, 94 % vs 87 %, p < 0.01. Conclusions: This novel investigation is the first to show fluid flow measurement using the Pashley model in dentine samples that have been housed in the mouth for 14 days. Treatment with an oxalate strip designed for dentine hypersensitivity alleviation reduced dentine fluid flow more than control providing evidence that the oxalate treatment withstood the oral environment over a prolonged time. Clinical significance: This study demonstrated the efficacy and durability of the oxalate precipitate over a 14 day period in achieving and maintaining dentine tubule occlusion when participants had no dietary restrictions. This demonstrates the suitability of the oxalate strip for the treatment of patients suffering from dentine hypersensitivity pain.
MeSH term(s)	Adult ; Dentin ; Dentin Sensitivity/drug therapy ; Humans ; Microscopy, Electron, Scanning ; Oxalic Acid ; Toothpastes
Chemical Substances	Toothpastes ; Oxalic Acid (9E7R5L6H31)
Language	English
Publishing date	2020-07-28
Publishing country	England
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	186068-9
ISSN	1879-176X ; 0300-5712
ISSN (online)	1879-176X
ISSN	0300-5712
DOI	10.1016/j.jdent.2020.103437
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Article ; Online: Dissolved trace element concentrations and fluxes in the Irrawaddy, Salween, Sittaung and Kaladan Rivers.

Bridgestock, Luke / Henderson, Gideon M / Holdship, Phil / Khaing, Aung Myo / Naing, Tin Tin / Myint, Tin Aung / Htun, Wint Wint / Khant, Win / Thu, Win Myo / Chi, Mo Aung Nay / Baronas, J Jotautas / Tipper, Edward / Chapman, Hazel / Bickle, Mike

The Science of the total environment

2022 Volume 841, Page(s) 156756

Abstract: The Irrawaddy (Ayeyarwaddy) and Salween (Thanlwin) globally rank among the largest rivers for supplying dissolved and particulate material to the ocean. Along with the Sittaung and Kaladan rivers they have societal importance to Myanmar in terms water ... ...

Abstract	The Irrawaddy (Ayeyarwaddy) and Salween (Thanlwin) globally rank among the largest rivers for supplying dissolved and particulate material to the ocean. Along with the Sittaung and Kaladan rivers they have societal importance to Myanmar in terms water sources and food production. Despite their importance for global biogeochemical cycles and the ~50 million people who live in their catchments, the chemistry of these rivers is poorly known. This study presents a comprehensive survey of dissolved (<0.22 μm) trace element concentrations (Sr, Fe, Al, Ba, Mn, V, Rb, Cu, Zn, As, Li, Ni, Mo, Cr, U, Pb, Sb, Co, Cs, Tl and Cd) at 38 locations within these river catchments, spanning a period of 2 years. The results highlight the global importance of the Irrawaddy and Salween rivers for trace element global biogeochemical cycles; contributing between 1 and 17 % of global dissolved riverine fluxes to the land-ocean interface for the studied elements. Area normalized dissolved fluxes in these catchments are ~2 to 10 times higher than global average values for most elements, consistent with high rates of chemical weathering. In general, anthropogenic activities have yet to significantly perturb dissolved trace element fluxes in these river systems. The presented dataset should therefore serve as a useful 'natural' baseline, against which future perturbations driven by climate change and/or the development of Myanmar's mining industry could be assessed. Exceptions to this include As in the Sittaung River and Sb, Zn, Pb and As in the Salween River, which may already be significantly impacted by anthropogenic inputs. The former represents a water quality issue of concern for public health, and so constraining the exact sources of As in the Sittaung River should be considered a priority for future research.
MeSH term(s)	Environmental Monitoring ; Lead ; Metals, Heavy/analysis ; Myanmar ; Rivers/chemistry ; Trace Elements/analysis ; Water Pollutants, Chemical/analysis
Chemical Substances	Metals, Heavy ; Trace Elements ; Water Pollutants, Chemical ; Lead (2P299V784P)
Language	English
Publishing date	2022-06-17
Publishing country	Netherlands
Document type	Journal Article
ZDB-ID	121506-1
ISSN	1879-1026 ; 0048-9697
ISSN (online)	1879-1026
ISSN	0048-9697
DOI	10.1016/j.scitotenv.2022.156756
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Article: Quantitative biomonitoring of polycyclic aromatic compounds (PACs) using the Sydney rock oyster (Saccostrea glomerata)

Idowu, Oluyoye / Tran, Thi Kim Anh / Webster, Grant / Chapman, Ian / Baker, Phil / Farrel, Hazel / Zammit, Anthony / Semple, Kirk T / Hansbro, Phil M / O'Connor, Wayne / Thavamani, Palanisami

Science of the total environment. 2020 Nov. 10, v. 742

2020

Abstract	Increasing our understanding of the bioavailable fractions of polycyclic aromatic compounds (PACs) in an aquatic environment is important for the assessment of the environmental and human health risks posed by PACs. More importantly, the behaviour of polar polycyclic aromatic hydrocarbons (polar PAHs), which are metabolites of legacy PAHs, are yet to be understood. We, therefore, carried out a study involving Sydney rock oysters (Saccostrea glomerata) sourced from two locations, that had been exposed to PAH contamination, within an Australian south-east estuary. Biomonitoring of these oysters, following relocation from the estuary to a relatively isolated waterway, was done at 24 and 72 h after deployment and subsequently at 7, 14, 28, 52 and 86 days. Control samples from Camden Haven River were sampled for PAC analyses just before deployment, after 28 days and at the end of the study (day 86). Lipid-normalised concentrations in oyster tissues across the 86-day sampling duration, elimination rate constants (k₂), biological half-lives (t₁/₂) and time required to reach 95% of steady-state (t₉₅) were reported for parent PAHs and the less-monitored polar PAHs including nitrated/oxygenated/heterocyclic PAHs (NPAHs, oxyPAHs and HPAHs) for the three differently sourced oyster types. Most of the depurating PAHs and NPAHs, as well as 9-FLO (oxyPAH), had k₂ values significantly different from zero (p < 0.05). All other oxyPAHs and HPAHs showed no clear depuration, with their concentrations remaining similar. The non-depuration of polar PAHs from oyster tissues could imply greater human health risk compared to their parent analogues.
Keywords	Saccostrea glomerata ; aquatic environment ; bioavailability ; depuration ; environmental monitoring ; estuaries ; half life ; heterocyclic compounds ; human health ; metabolites ; oysters ; risk ; rivers
Language	English
Dates of publication	2020-1110
Publishing place	Elsevier B.V.
Document type	Article
Note	NAL-AP-2-clean
ZDB-ID	121506-1
ISSN	1879-1026 ; 0048-9697
ISSN (online)	1879-1026
ISSN	0048-9697
DOI	10.1016/j.scitotenv.2020.140497
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Article: Dissolved trace element concentrations and fluxes in the Irrawaddy, Salween, Sittaung and Kaladan Rivers

Bridgestock, Luke / Henderson, Gideon M. / Holdship, Phil / Khaing, Aung Myo / Naing, Tin Tin / Myint, Tin Aung / Htun, Wint Wint / Khant, Win / Thu, Win Myo / Chi, Mo Aung Nay / Baronas, J. Jotautas / Tipper, Edward / Chapman, Hazel / Bickle, Mike

Science of the total environment. 2022 Oct. 01, v. 841

2022

Abstract	The Irrawaddy (Ayeyarwaddy) and Salween (Thanlwin) globally rank among the largest rivers for supplying dissolved and particulate material to the ocean. Along with the Sittaung and Kaladan rivers they have societal importance to Myanmar in terms water sources and food production. Despite their importance for global biogeochemical cycles and the ~50 million people who live in their catchments, the chemistry of these rivers is poorly known. This study presents a comprehensive survey of dissolved (<0.22 μm) trace element concentrations (Sr, Fe, Al, Ba, Mn, V, Rb, Cu, Zn, As, Li, Ni, Mo, Cr, U, Pb, Sb, Co, Cs, Tl and Cd) at 38 locations within these river catchments, spanning a period of 2 years. The results highlight the global importance of the Irrawaddy and Salween rivers for trace element global biogeochemical cycles; contributing between 1 and 17 % of global dissolved riverine fluxes to the land-ocean interface for the studied elements. Area normalized dissolved fluxes in these catchments are ~2 to 10 times higher than global average values for most elements, consistent with high rates of chemical weathering. In general, anthropogenic activities have yet to significantly perturb dissolved trace element fluxes in these river systems. The presented dataset should therefore serve as a useful ‘natural’ baseline, against which future perturbations driven by climate change and/or the development of Myanmar's mining industry could be assessed. Exceptions to this include As in the Sittaung River and Sb, Zn, Pb and As in the Salween River, which may already be significantly impacted by anthropogenic inputs. The former represents a water quality issue of concern for public health, and so constraining the exact sources of As in the Sittaung River should be considered a priority for future research.
Keywords	climate change ; data collection ; environment ; food production ; people ; public health ; riparian areas ; rivers ; surveys ; water quality ; Myanmar
Language	English
Dates of publication	2022-1001
Publishing place	Elsevier B.V.
Document type	Article
ZDB-ID	121506-1
ISSN	1879-1026 ; 0048-9697
ISSN (online)	1879-1026
ISSN	0048-9697
DOI	10.1016/j.scitotenv.2022.156756
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Article ; Online: Delivering hydrophilic peptide inhibitors of heat shock protein 70 into cancer cells.

Han, Zifei / McAlpine, Shelli R / Chapman, Robert

Bioorganic chemistry

2022 Volume 122, Page(s) 105713

Abstract: ... as an attractive target in a wide range of cancers. Here we used a polymer nanogel to deliver two hydrophilic ... of hydrophilic cargo such as peptides and demonstrate the viability of these peptide inhibitors for targeting ...

Abstract	Heat shock protein 70 (Hsp70) plays a major role in protein folding and has emerged as an attractive target in a wide range of cancers. Here we used a polymer nanogel to deliver two hydrophilic peptide inhibitors that block the interaction between the C-terminus of Hsp70 and heat shock organizing protein (HOP). The nanogels are able to load ∼200 wt% of the peptide inhibitors from solution via simple agitation at pH 7, and release them after cell uptake. Delivery of Hsp70 inhibitors to HCT116 cancer cells produced a clear Hsp70 inhibition phenotype: downregulation of client proteins glucocorticoid receptor (GR), immunophilins (FKBP51 and FKBP52), the protein kinase Akt-1, as well as the co-chaperone CHIP, and they induce cancer cell death. These results showcase the advantages of using versatile nanogels for delivery of hydrophilic cargo such as peptides and demonstrate the viability of these peptide inhibitors for targeting the Hsp70-HOP interaction in a cellular system.
MeSH term(s)	HCT116 Cells ; HSP70 Heat-Shock Proteins/metabolism ; HSP90 Heat-Shock Proteins/metabolism ; Heat-Shock Proteins/metabolism ; Humans ; Neoplasms ; Peptides/pharmacology ; Protein Binding
Chemical Substances	HSP70 Heat-Shock Proteins ; HSP90 Heat-Shock Proteins ; Heat-Shock Proteins ; Peptides
Language	English
Publishing date	2022-03-01
Publishing country	United States
Document type	Journal Article
ZDB-ID	120080-x
ISSN	1090-2120 ; 0045-2068
ISSN (online)	1090-2120
ISSN	0045-2068
DOI	10.1016/j.bioorg.2022.105713
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Article ; Online: Ultrafast Triggering of Insulator-Metal Transition in Two-Dimensional VSe

Biswas, Deepnarayan / Jones, Alfred J H / Majchrzak, Paulina / Choi, Byoung Ki / Lee, Tsung-Han / Volckaert, Klara / Feng, Jiagui / Marković, Igor / Andreatta, Federico / Kang, Chang-Jong / Kim, Hyuk Jin / Lee, In Hak / Jozwiak, Chris / Rotenberg, Eli / Bostwick, Aaron / Sanders, Charlotte E / Zhang, Yu / Karras, Gabriel / Chapman, Richard T /

Wyatt, Adam S / Springate, Emma / Miwa, Jill A / Hofmann, Philip / King, Phil D C / Chang, Young Jun / Lanatà, Nicola / Ulstrup, Søren

Nano letters

2021 Volume 21, Issue 5, Page(s) 1968–1975

Abstract: The transition-metal dichalcogenide ... ...

Abstract	The transition-metal dichalcogenide VSe
Language	English
Publishing date	2021-02-18
Publishing country	United States
Document type	Journal Article
ISSN	1530-6992
ISSN (online)	1530-6992
DOI	10.1021/acs.nanolett.0c04409
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