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Article ; Online: Low expression levels of miRNA-155 and miRNA-499a are associated with obesity in Type 2 diabetes.

Latini, Andrea / Benedittis, Giada De / Ciccacci, Cinzia / Novelli, Giuseppe / Spallone, Vincenza / Borgiani, Paola

2024 Volume 16, Issue 2, Page(s) 85–91

Abstract: Background & aims: ...

Abstract	Background & aims:
MeSH term(s)	Humans ; Circulating MicroRNA ; Diabetes Mellitus, Type 2/complications ; Diabetes Mellitus, Type 2/genetics ; MicroRNAs/genetics ; Obesity/complications ; Obesity/genetics ; Obesity, Abdominal/complications
Chemical Substances	Circulating MicroRNA ; MicroRNAs ; MIRN155 microRNA, human ; MIRN499 microRNA, human
Language	English
Publishing date	2024-01-15
Publishing country	England
Document type	Journal Article
ZDB-ID	2537199-X
ISSN	1750-192X ; 1750-1911
ISSN (online)	1750-192X
ISSN	1750-1911
DOI	10.2217/epi-2023-0320
Database	MEDical Literature Analysis and Retrieval System OnLINE

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Article ; Online: 4,4′-([2,2′-Bithiophene]-5,5′-diylbis(ethyne-2,1-diyl))bis(1-methylpyridin-1-ium) Iodide

Lorenza Romagnoli / Andrea D’Annibale / Alessandro Latini

Molbank, Vol 2023, Iss 4, p M

2023 Volume 1733

Abstract: Viologens are a highly advantageous class of compounds for the synthesis of functional materials. Owing to their versatile structure, they can embed additional conjugated moieties, thus representing a convenient platform, for example for organic ... ...

Abstract	Viologens are a highly advantageous class of compounds for the synthesis of functional materials. Owing to their versatile structure, they can embed additional conjugated moieties, thus representing a convenient platform, for example for organic semiconductors and other energy-related uses. A straightforward synthesis of an extended viologen containing a bithiophene is described here, together with its UV-visible absorption and fluorescence spectroscopy, showing multiple absorption and emission bands. Thanks to its ease of synthesis and optical properties, this organic salt appears to be of potential interest for various optoelectronic applications.
Keywords	viologen ; fluorescent probe ; Sonogashira reaction ; Inorganic chemistry ; QD146-197
Language	English
Publishing date	2023-10-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
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Article ; Online: 4,4′,4″-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(1-methylpyridin-1-ium) Iodide

Lorenza Romagnoli / Andrea D’Annibale / Alessandro Latini

Molbank, Vol 2023, Iss 4, p M

2023 Volume 1742

Abstract: Despite having been known for a long time, quaternary 4,4′-bipyridinium salts, or viologens, are still a highly inspiring class of compounds, thanks to their peculiar redox and charge transfer properties. However, more complex structures containing ... ...

Abstract	Despite having been known for a long time, quaternary 4,4′-bipyridinium salts, or viologens, are still a highly inspiring class of compounds, thanks to their peculiar redox and charge transfer properties. However, more complex structures containing multiple pyridinium rings, also interspaced by conjugated moieties, allow an even wider synthetic variability and tunability of their characteristics. The compound described herein is a star-shaped, fully conjugated molecule with three methylated pyridinium rings connected by a triple bond spacer to a central benzene core, which was synthesized from readily available building blocks, representing a quite simple model of multi-pyridyl extended viologen; its UV–visible absorption and fluorescence spectra have also been investigated.
Keywords	viologen ; fluorescent probe ; Sonogashira reaction ; Inorganic chemistry ; QD146-197
Language	English
Publishing date	2023-11-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
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Article: The Role of Large Language Models (LLMs) in Providing Triage for Maxillofacial Trauma Cases: A Preliminary Study.

Frosolini, Andrea / Catarzi, Lisa / Benedetti, Simone / Latini, Linda / Chisci, Glauco / Franz, Leonardo / Gennaro, Paolo / Gabriele, Guido

Diagnostics (Basel, Switzerland)

2024 Volume 14, Issue 8

Abstract: Background: In the evolving field of maxillofacial surgery, integrating advanced technologies like Large Language Models (LLMs) into medical practices, especially for trauma triage, presents a promising yet largely unexplored potential. This study aimed ...

Abstract	Background: In the evolving field of maxillofacial surgery, integrating advanced technologies like Large Language Models (LLMs) into medical practices, especially for trauma triage, presents a promising yet largely unexplored potential. This study aimed to evaluate the feasibility of using LLMs for triaging complex maxillofacial trauma cases by comparing their performance against the expertise of a tertiary referral center. Methods: Utilizing a comprehensive review of patient records in a tertiary referral center over a year-long period, standardized prompts detailing patient demographics, injury characteristics, and medical histories were created. These prompts were used to assess the triage suggestions of ChatGPT 4.0 and Google GEMINI against the center's recommendations, supplemented by evaluating the AI's performance using the QAMAI and AIPI questionnaires. Results: The results in 10 cases of major maxillofacial trauma indicated moderate agreement rates between LLM recommendations and the referral center, with some variances in the suggestion of appropriate examinations (70% ChatGPT and 50% GEMINI) and treatment plans (60% ChatGPT and 45% GEMINI). Notably, the study found no statistically significant differences in several areas of the questionnaires, except in the diagnosis accuracy (GEMINI: 3.30, ChatGPT: 2.30; Conclusions: This exploratory investigation underscores the potential of LLMs in enhancing clinical decision making for maxillofacial trauma cases, indicating a need for further research to refine their application in healthcare settings.
Language	English
Publishing date	2024-04-18
Publishing country	Switzerland
Document type	Journal Article
ZDB-ID	2662336-5
ISSN	2075-4418
ISSN	2075-4418
DOI	10.3390/diagnostics14080839
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Article ; Online: ATG5 gene expression analysis supports the involvement of autophagy in microangiopathic complications of type 2 diabetes.

De Benedittis, Giada / Latini, Andrea / Spallone, Vincenza / Novelli, Giuseppe / Borgiani, Paola / Ciccacci, Cinzia

Nutrition, metabolism, and cardiovascular diseases : NMCD

2023 Volume 33, Issue 9, Page(s) 1797–1799

Abstract: Background and aims: Type 2 diabetes (T2D) hyperglycaemia alters basal autophagy. Since autophagy is an essential cellular process, our aim was to investigate the ATG5 (autophagy-related 5) gene expression level and genetic variants in a cohort of ... ...

Abstract	Background and aims: Type 2 diabetes (T2D) hyperglycaemia alters basal autophagy. Since autophagy is an essential cellular process, our aim was to investigate the ATG5 (autophagy-related 5) gene expression level and genetic variants in a cohort of diabetic patients, characterized for the presence of microangiopathic complications. Methods and results: the expression levels of ATG5 were evaluated in PBMCs from 48 T2D patients with an extensive evaluation for microangiopathic complications. Our analyses revealed a significant lower expression of ATG5 in T2D patients with retinopathy compared to those without retinopathy. We also highlighted a significant lower expression of ATG5 in T2D patients with early-cardiovascular autonomic neuropathy compared to those without it, after correction for sex, age, body mass index and levels of hemoglobin A1c. Conclusion: our results highlight that dysregulation in the autophagy process could be involved in the development of severe microangiopathic complications.
MeSH term(s)	Humans ; Diabetes Mellitus, Type 2/complications ; Diabetes Mellitus, Type 2/diagnosis ; Diabetes Mellitus, Type 2/genetics ; Vascular Diseases ; Glycated Hemoglobin ; Autophagy/genetics ; Retinal Diseases ; Autophagy-Related Protein 5/genetics
Chemical Substances	Glycated Hemoglobin ; ATG5 protein, human ; Autophagy-Related Protein 5
Language	English
Publishing date	2023-06-24
Publishing country	Netherlands
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	1067704-5
ISSN	1590-3729 ; 0939-4753
ISSN (online)	1590-3729
ISSN	0939-4753
DOI	10.1016/j.numecd.2023.06.018
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Article ; Online: Interposition Arthroplasty versus Dual Cup Mobility Prosthesis in Treatment of Trapeziometacarpal Joint Osteoarthritis: A Prospective Randomized Study.

Guzzini, Matteo / Arioli, Leopoldo / Annibaldi, Alessandro / Pecchia, Stefano / Latini, Francesca / Ferretti, Andrea

Hand (New York, N.Y.)

2023 , Page(s) 15589447231185584

Abstract: Background: Osteoarthritis (OA) of the trapeziometacarpal (TMC) joint is a common cause of pain and functional disability of the hand and is the second most frequent site in the hand of OA. This prospective randomized study analyses and compares the ... ...

Abstract	Background: Osteoarthritis (OA) of the trapeziometacarpal (TMC) joint is a common cause of pain and functional disability of the hand and is the second most frequent site in the hand of OA. This prospective randomized study analyses and compares the outcomes and global assessment of 2 different surgical techniques for rhizarthrosis treatment: trapeziectomy with tendon interposition arthroplasty and total joint replacement with Touch® (KeriMedical; Geneva, Switzerland) TMC prosthesis. Methods: The enrolled patients were randomly divided into 2 groups: group A included 71 patients (75 hands) treated with tendon interposition arthroplasty, while group B included 65 patients (72 hands) treated with total joint replacement. Clinical and radiological outcomes were collected before surgery and at 1, 3, 6, 12, and 24 months of follow-up. Results: Although the values of all clinical tests performed during follow-up demonstrated statistically significant improvement over preoperative ones in both groups, patients treated with prosthesis showed faster improvement, especially in tests of strength and range of motion, which showed better results than patients treated with trapeziectomy and tendon interposition arthroplasty throughout the follow-up. Conclusions: Our study suggests that joint replacement should be preferred to interposition arthroplasty as the treatment of rhizarthrosis, choosing the latter in case of prosthetic replacement complications or scaphoid-trapezium-trapezoid OA.
Language	English
Publishing date	2023-07-23
Publishing country	United States
Document type	Journal Article
ZDB-ID	2277325-3
ISSN	1558-9455 ; 1558-9447
ISSN (online)	1558-9455
ISSN	1558-9447
DOI	10.1177/15589447231185584
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Article ; Online: Thermodynamics and the Intrinsic Stability of Lead Halide Perovskites CH

Ciccioli, Andrea / Latini, Alessandro

The journal of physical chemistry letters

2018 Volume 9, Issue 13, Page(s) 3756–3765

Abstract: The role of thermodynamics in assessing the intrinsic instability of the ... ...

Abstract	The role of thermodynamics in assessing the intrinsic instability of the CH
Language	English
Publishing date	2018-07-05
Publishing country	United States
Document type	Journal Article
ISSN	1948-7185
ISSN (online)	1948-7185
DOI	10.1021/acs.jpclett.8b00463
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Article ; Online: Thermodynamic Study of Formamidinium Lead Iodide (CH

Ciccioli, Andrea / Latini, Alessandro / Luongo, Alessio / Smirnova, Natalia N / Markin, Alexey V / Vecchio Ciprioti, Stefano

Entropy (Basel, Switzerland)

2022 Volume 24, Issue 2

Abstract: In the present study, the molar heat capacity of solid formamidinium lead iodide ( ... ...

Abstract	In the present study, the molar heat capacity of solid formamidinium lead iodide (CH
Language	English
Publishing date	2022-01-18
Publishing country	Switzerland
Document type	Journal Article
ZDB-ID	2014734-X
ISSN	1099-4300 ; 1099-4300
ISSN (online)	1099-4300
ISSN	1099-4300
DOI	10.3390/e24020145
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Article ; Online: PCSK3

Latini, Andrea / De Benedittis, Giada / Colafrancesco, Serena / Perricone, Carlo / Novelli, Giuseppe / Novelli, Lucia / Priori, Roberta / Ciccacci, Cinzia / Borgiani, Paola

Genes

2023 Volume 14, Issue 5

Abstract: Background: The : Methods: We investigated the : Results: We observed, by RT-qPCR, that the : Conclusions: Our data suggest that Furin could play a role in SS development, also promoting IFN-γ secretion. ...

Abstract	Background: The Methods: We investigated the Results: We observed, by RT-qPCR, that the Conclusions: Our data suggest that Furin could play a role in SS development, also promoting IFN-γ secretion.
MeSH term(s)	Humans ; Furin/genetics ; Gene Expression ; Interferon-gamma/genetics ; Interferon-gamma/metabolism ; Leukocytes, Mononuclear/metabolism ; Promoter Regions, Genetic ; Sjogren's Syndrome
Chemical Substances	Furin (EC 3.4.21.75) ; Interferon-gamma (82115-62-6) ; FURIN protein, human (EC 3.4.21.75)
Language	English
Publishing date	2023-04-26
Publishing country	Switzerland
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	2527218-4
ISSN	2073-4425 ; 2073-4425
ISSN (online)	2073-4425
ISSN	2073-4425
DOI	10.3390/genes14050981
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Article ; Online: Stable Cycling of Sodium Metal Anodes Enabled by a Sodium/Silica‐Gel Host

Angelica Petrongari / Mariarosaria Tuccillo / Dr. Andrea Ciccioli / Prof. Alessandro Latini / Prof. Sergio Brutti

ChemElectroChem, Vol 10, Iss 5, Pp n/a-n/a (2023)

2023

Abstract: Abstract Sodium metal batteries (SMBs) are innovative and promising energy storage systems. SMBs are a competitive technological paradigm compared to the state‐of‐the‐art lithium‐ion batteries thanks to the high specific capacity of sodium metal, i. e., ... ...

Abstract	Abstract Sodium metal batteries (SMBs) are innovative and promising energy storage systems. SMBs are a competitive technological paradigm compared to the state‐of‐the‐art lithium‐ion batteries thanks to the high specific capacity of sodium metal, i. e., 1166 mAh g−1, and the Na+/Na0 low redox potential of −2.71 V vs. standard hydrogen electrode. Unstable solid electrolyte interface (SEI), uncontrolled overpotentials and dendrite growth of sodium are the main drawbacks that hinder the development of SMBs. Herein, we propose a functionalized silica gel material with extended porosity (NaSGII) as an active host material in order to obtain stable cycling of sodium metal anodes. NaSGII was incorporated in composite electrodes using a conductive carbon additive and polymeric binders and the functional properties in SMBs cells demonstrated by galvanostatic tests. A Butler‐Volmer analysis demonstrated an improvement of electrokinetic parameters induced by NaSGII.
Keywords	aprotic batteries ; charge transfer ; electrochemistry ; secondary batteries ; sodium batteries ; Industrial electrochemistry ; TP250-261 ; Chemistry ; QD1-999
Language	English
Publishing date	2023-03-01T00:00:00Z
Publisher	Wiley-VCH
Document type	Article ; Online
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