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Article ; Online: Structural isomerism in (p-XC6H4)SeCl3 and (p-XC6H4)SeBr3 (X = F, Cl) compounds. Co-crystallisation of cis- and trans-dimeric forms of (p-ClC6H4)SeCl2(μ-Cl)2(p-ClC6H4)SeCl2. A new structural modification for the "PhSeBr" reagent, Ph2Se2Br2, containing an elongated Se-Se bond.

Barnes, Nicholas A / Godfrey, Stephen M / Ollerenshaw, Ruth T A / Khan, Rana Z / Pritchard, Robin G

Dalton transactions (Cambridge, England : 2003)

2012 Volume 41, Issue 48, Page(s) 14583–14593

Abstract: A series of di(para-halophenyl)diselenides, (p-XC(6)H(4))(2)Se(2) (X = F, Cl) have been reacted ... The structures of (p-FC(6)H(4))SeX(3) (X = Cl, Br) have been determined, and both exhibit a dimeric RSeX(2)(μ-X ... 2)RSeX(2) structure consisting of two "saw-horse" (p-FC(6)H(4))SeX(3) units linked by two halide ...

Abstract	A series of di(para-halophenyl)diselenides, (p-XC(6)H(4))(2)Se(2) (X = F, Cl) have been reacted with three equivalents of SO(2)Cl(2) or Br(2), leading to the formation of selenium(iv) RSeX(3) compounds. The structures of (p-FC(6)H(4))SeX(3) (X = Cl, Br) have been determined, and both exhibit a dimeric RSeX(2)(μ-X)(2)RSeX(2) structure consisting of two "saw-horse" (p-FC(6)H(4))SeX(3) units linked by two halide bridges, with an overall square pyramidal geometry at selenium. In both structures all the selenium and halogen atoms are planar, with both aryl rings located on the same side of the Se(2)X(6) plane (cis-isomer). The structure of (p-ClC(6)H(4))SeCl(3) also adopts a planar dimeric structure, however both cis- and trans-dimeric molecules are co-crystallised in the unit cell. In contrast, the structure of (p-ClC(6)H(4))SeBr(3) adopts a folded cis-dimeric structure due to steric constraints. Secondary Se···X interactions to the "vacant" sixth coordination site at selenium are a feature of most of these structures, but are most prominent in the folded structure of (p-ClC(6)H(4))SeBr(3). A re-examination of the PhSeBr/PhSeBr(3) system resulted in the isolation of crystals of a second structural form of "PhSeBr". The structure of Ph(2)Se(2)Br(2) consists of two PhSeBr units linked by an elongated Se-Se bond of 2.832(4) Å, and longer secondary Se···Br interactions of 3.333(4) Å to form a chain structure. Further weak Se···Br and Br···Br interactions are present, which form loosely linked rippled sheets of selenium and bromine atoms, similar to the sheets observed for the tetrameric form, Ph(4)Se(4)Br(4).
Language	English
Publishing date	2012-12-28
Publishing country	England
Document type	Journal Article
ZDB-ID	1472887-4
ISSN	1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
ISSN (online)	1477-9234 ; 1364-5447
ISSN	0300-9246 ; 1477-9226
DOI	10.1039/c2dt31539d
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Article: Spetial and temporal distribution of house dust mite (Astigmata:Pyroglyphidae) allergens Der p 1 and Der f 1 in Barbadian homes.

Barnes, K C / Fernández-Caldas, E / Trudeau, W L / Milne, D E / Brenner, R J

Journal of medical entomology

1997 Volume 34, Issue 2, Page(s) 212–218

Abstract: ... disease. Allergen (Der p 1 and Der f 1) levels were measured at 4 sites (mattress, bedroom floor, living ... concrete and wood houses. Der f 1(9 of 17 homes) levels were lower than Der p 1 by 1/1,000 (both seasons ... room floor, and furniture) in 17 houses in Barbados during dry and rainy seasons. Der p 1(17 of 17 ...

Abstract	House features contribute to house dust mite abundance and, therefore, exposure to mite allergens. Our study assessed the hypothesis that modernization of the domestic environment in a tropical setting may lead to a level of allergen from the house dust mites Dermatophagoides pteronyssinus (Trouessart) and D. farinae Hughes that previously has been defined clinically as at risk for people who suffer from allergic disease. Allergen (Der p 1 and Der f 1) levels were measured at 4 sites (mattress, bedroom floor, living room floor, and furniture) in 17 houses in Barbados during dry and rainy seasons. Der p 1(17 of 17 homes) at all 4 sites did not vary significantly from the dry to rainy season. Allergen levels varied according to site, and were highest in living room furniture in both seasons (geometric mean 40.37 and 64.17 micrograms/g, respectively). Concentration of Der p 1 allergens were higher in concrete than in wood or mixed concrete and wood houses. Der f 1(9 of 17 homes) levels were lower than Der p 1 by 1/1,000 (both seasons). Results indicate that season is less important in regard to levels of Der p 1 than house construction and confirm other studies that implicate D. pteronyssinus as a more abundant source of allergen than D. farinae in this tropical setting.
MeSH term(s)	Allergens/analysis ; Animals ; Antigens, Dermatophagoides ; Glycoproteins/analysis ; Humans ; Mites
Chemical Substances	Allergens ; Antigens, Dermatophagoides ; Glycoproteins
Language	English
Publishing date	1997-03
Publishing country	England
Document type	Journal Article ; Research Support, U.S. Gov't, Non-P.H.S.
ZDB-ID	410635-0
ISSN	0022-2585
ISSN	0022-2585
DOI	10.1093/jmedent/34.2.212
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Article: Foreword: The Role of a Team Physician and an Athletic Trainer.

Warren, Russell F / Barnes, Ronnie P

HSS journal : the musculoskeletal journal of Hospital for Special Surgery

2023 Volume 19, Issue 3, Page(s) 266–268

Language	English
Publishing date	2023-05-25
Publishing country	United States
Document type	Journal Article
ZDB-ID	2250601-9
ISSN	1556-3324 ; 1556-3316
ISSN (online)	1556-3324
ISSN	1556-3316
DOI	10.1177/15563316231173678
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Zs.A 6398: Show issues

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Article: Spatial and temporal distribution of house dust mite (Astigmata: Pyroglyphidae) allergens Der p 1 and Der f 1 in Barbadian homes

Barnes, K.C / Fernandez-Caldas, E / Trudeau, W.L / Milne, D.E / Brenner, R.J

Journal of medical entomology. Mar 1997. v. 34 (2)

1997

Abstract: ... disease. Allergen (Der p 1 and Der f 1) levels were measured at 4 sites (mattress, bedroom floor, living ... concrete and wood houses. Der f 1 (9 of 17 homes) levels were lower than Der p 1 by 1/1,000 (both seasons ... room floor, and furniture) in 17 houses in Barbados during dry and rainy seasons. Der p 1 (17 of 17 ...

Abstract	House features contribute to house dust mite abundance and, therefore, exposure to mite allergens. Our study assessed the hypothesis that modernization of the domestic environment in a tropical setting may lead to a level of allergen from the house dust mites Dermatophagoides pteronyssinus (Trouessart) and D. farinae Hughes that previously has been defined clinically as at risk for people who suffer from allergic disease. Allergen (Der p 1 and Der f 1) levels were measured at 4 sites (mattress, bedroom floor, living room floor, and furniture) in 17 houses in Barbados during dry and rainy seasons. Der p 1 (17 of 17 homes) at all 4 sites did not vary significantly from the dry to rainy season. Allergen levels varied according to site, and were highest in living room furniture in both seasons (geometric mean 40.37 and 64.17 micrograms/g, respectively). Concentration of Der p 1 allergens were higher in concrete than in wood or mixed concrete and wood houses. Der f 1 (9 of 17 homes) levels were lower than Der p 1 by 1/1,000 (both seasons). Results indicate that season is less important in regard to levels of Der p 1 than house construction and confirm other studies that implicate D. pteronyssinus as a more abundant source of allergen than D. farinae in this tropical setting.
Keywords	Dermatophagoides pteronyssinus ; Dermatophagoides farinae ; dust mites ; allergens ; spatial distribution ; seasonal variation ; dry season ; wet season ; building construction ; wood ; concrete ; Barbados
Language	English
Dates of publication	1997-03
Size	p. 212-218.
Document type	Article
ZDB-ID	410635-0
ISSN	0022-2585
ISSN	0022-2585
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Racial and Ethnic Disparities in Coexisting Cancer and COVID-19 Mortality.

Barnes, Justin M / Chino, Junzo P / Chino, Fumiko

Journal of general internal medicine

2023 Volume 38, Issue 5, Page(s) 1344–1347

MeSH term(s)	Humans ; United States/epidemiology ; COVID-19 ; Neoplasms/epidemiology ; Racial Groups ; Health Status Disparities ; Healthcare Disparities
Language	English
Publishing date	2023-02-07
Publishing country	United States
Document type	Research Support, N.I.H., Extramural ; Journal Article
ZDB-ID	639008-0
ISSN	1525-1497 ; 0884-8734
ISSN (online)	1525-1497
ISSN	0884-8734
DOI	10.1007/s11606-023-08069-8
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Article ; Online: Expression of RAS and RAB interactor 1 (RIN1) in head and neck tumors at selected hospital in Ghana.

Osei Saahene, Roland / Barnes, Precious / Yeboah, F A / Agbo, Elvis / Asante, Du-Bois / Arhin, Samuel Kofi

PloS one

2024 Volume 19, Issue 4, Page(s) e0301295

Abstract: ... tumors of p-value 0.02. There was a significant difference with p-values of 0.001 when poor and well ...

Abstract	Background: Head and neck tumors (HNT) are tumors of the paranasal sinuses, the salivary glands and the upper aerodigestive tract. RIN1 is a Ras effector protein regulating epithelial cell properties and has been implicated in a number of cancers. Method: The aim of this study was to investigate the expression of RIN1 in head and neck tumors. RIN1 expression was assessed using quantitative real-time PCR (qRT-PCR) and immunohistochemical staining on archival head and neck tissue samples between 2014 and 2020. Results: RIN1 expression was low in tissue samples as compared with the normal head and neck tissues. High and low RIN1 levels were compared with ages ≤40, >40 in the head and neck tumors of p-value 0.02. There was a significant difference with p-values of 0.001 when poor and well-moderate malignant tumors were compared. Conclusion: Our data suggests that RIN1may play an important role in head and neck tumor progression and that its expression may provide baseline data to facilitate identification of new molecular targeted therapeutics.
MeSH term(s)	Humans ; Intracellular Signaling Peptides and Proteins/genetics ; Ghana ; Epithelial Cells ; Real-Time Polymerase Chain Reaction ; Head and Neck Neoplasms/genetics
Chemical Substances	Intracellular Signaling Peptides and Proteins ; RIN1 protein, human
Language	English
Publishing date	2024-04-18
Publishing country	United States
Document type	Journal Article
ZDB-ID	2267670-3
ISSN	1932-6203 ; 1932-6203
ISSN (online)	1932-6203
ISSN	1932-6203
DOI	10.1371/journal.pone.0301295
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Article ; Online: Potential for a minor pine bark beetle pest, Dendroctonus terebrans (Coleoptera: Curculionidae: Scolytinae), to mediate host location by a major pine killer, Dendroctonus frontalis.

Sullivan, Brian T / Munro, Holly L / Barnes, Brittany F / McNichol, Bailey H / Shepherd, William P / Gandhi, Kamal J K

Journal of economic entomology

2024

Abstract: The southern pine beetle, Dendroctonus frontalis Zimmermann is an important mortality agent of Pinus in the eastern United States of America where it commonly shares hosts with the black turpentine beetle, Dendroctonus terebrans (Olivier), which ... ...

Abstract	The southern pine beetle, Dendroctonus frontalis Zimmermann is an important mortality agent of Pinus in the eastern United States of America where it commonly shares hosts with the black turpentine beetle, Dendroctonus terebrans (Olivier), which infrequently kills trees. Unlike D. frontalis, which must kill its hosts to become established in the bark and reproduce, D. terebrans can occupy living hosts as a parasite. Olfactory mechanisms whereby D. frontalis initially locates hosts have not been demonstrated, whereas D. terebrans responds strongly to host odors. Because D. terebrans produces frontalin, the primary aggregation pheromone component for D. frontalis, and commonly arrives on hosts prior to D. frontalis, it has been hypothesized that D. terebrans pheromone components can mediate D. frontalis location of suitable, living trees. We assessed this possibility with studies of the semiochemical interactions between D. frontalis and D. terebrans. Coupled gas chromatography-electroantennographic detection analyses indicated that D. terebrans produces nine different olfactory stimulants for D. frontalis, nearly all of them known semiochemicals for D. frontalis. A trapping experiment designed to address the potentially confounding influence of lure contamination confirmed that the D. terebrans pheromone component exo-brevicomin enhances attraction of D. frontalis and thus could be an attractive kairomone. In ambulatory bioassays, male D. frontalis were strongly attracted to odors of frass of solitary female and paired D. terebrans, indicating their attraction to the naturally occurring semiochemicals of D. terebrans. Cues from D. terebrans may influence host and mate-finding success of D. frontalis and, thereby, the latter's virulence.
Language	English
Publishing date	2024-03-31
Publishing country	England
Document type	Journal Article
ZDB-ID	3031-4
ISSN	1938-291X ; 0022-0493
ISSN (online)	1938-291X
ISSN	0022-0493
DOI	10.1093/jee/toae054
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Article ; Online: Interpretable Performance Models for Energetic Materials using Parsimonious Neural Networks.

Appleton, Robert J / Salek, Peter / Casey, Alex D / Barnes, Brian C / Son, Steven F / Strachan, Alejandro

The journal of physical chemistry. A

2024 Volume 128, Issue 6, Page(s) 1142–1153

Abstract: Predictive models for the performance of explosives and propellants are important for their design, optimization, and safety. Thermochemical codes can predict some of these properties from fundamental quantities such as density and formation energies ... ...

Abstract	Predictive models for the performance of explosives and propellants are important for their design, optimization, and safety. Thermochemical codes can predict some of these properties from fundamental quantities such as density and formation energies that can be obtained from first principles. Models that are simpler to evaluate are desirable for efficient, rapid screening of material screening. In addition, interpretable models can provide insight into the physics and chemistry of these materials that could be useful to direct new synthesis. Current state-of-the-art performance models are based on either the parametrization of physics-based expressions or data-driven approaches with minimal interpretability. We use parsimonious neural networks (PNNs) to discover interpretable models for the specific impulse of propellants and detonation velocity and pressure for explosives using data collected from the open literature. A combination of evolutionary optimization with custom neural networks explores and trains models with objective functions that balance accuracy and complexity. For all three properties of interest, we find interpretable models that are Pareto optimal in the accuracy and simplicity space.
Language	English
Publishing date	2024-01-31
Publishing country	United States
Document type	Journal Article
ISSN	1520-5215
ISSN (online)	1520-5215
DOI	10.1021/acs.jpca.3c06159
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Article ; Online: Brief opportunistic interventions by general practitioners to promote smoking cessation: A conversation analytic study.

Wheat, H / Barnes, R K / Aveyard, P / Stevenson, F / Begh, R

Social science & medicine (1982)

2022 Volume 314, Page(s) 115463

Abstract: Very brief opportunistic interventions for smoking cessation are effective, cost-saving for health systems, and universally recommended in guidelines. However, evidence suggests that clinicians are reluctant to intervene, citing interactional ... ...

Abstract	Very brief opportunistic interventions for smoking cessation are effective, cost-saving for health systems, and universally recommended in guidelines. However, evidence suggests that clinicians are reluctant to intervene, citing interactional difficulties. Only one UK study has specifically examined smoking discussions, within naturally occurring primary care consultations. However smoking cessation treatment was not available at the time. We examined existing datasets amounting to 519 video-recordings of GP consultations in England for instances of talk about smoking. We used conversation analytic methods to assess patients' responses to doctors asking about smoking, giving advice on smoking, and offering cessation treatment. In 31 recordings it was apparent that the patient smoked, and, in 25/31 consultations, doctors initiated the topic of smoking. They did so by asking about smoking status, commonly during the history-taking phase of the consultation. In many instances, these questions led to active resistance from patients against being placed in a discreditable category, for example by minimising their smoking. This was more pronounced when GPs pursued efforts to quantify the amount smoked. Thereafter, where doctors returned to the topic of smoking, they did so typically by linking smoking to the patient's medical condition, which likewise led to resistance. Guidance recommends that GPs advise on how best to quit smoking where patients are interested in doing so, but this was only evident in a minority of consultations. Where GPs offered support for cessation, they did so using interactional practices that minimised the need for the patient to respond and thereby accept. Interactional difficulties were found to be common in consultations between GPs and people who smoke when GPs actions aligned with some VBA guidelines. Future research should examine when and how advice on how best to quit, and offers of support, should be delivered within primary care consultations.
MeSH term(s)	Humans ; General Practitioners ; Smoking Cessation ; Communication ; Referral and Consultation ; Medical Assistance
Language	English
Publishing date	2022-10-29
Publishing country	England
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	4766-1
ISSN	1873-5347 ; 0037-7856 ; 0277-9536
ISSN (online)	1873-5347
ISSN	0037-7856 ; 0277-9536
DOI	10.1016/j.socscimed.2022.115463
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Article ; Online: Spectroscopic and Microscopic Characterization of Microbial Biofouling on Aircraft Fuel Tanks.

Gómez-Bolívar, Jaime / Warburton, Martin P / Mumford, Adam D / Mujica-Alarcón, Juan F / Anguilano, Lorna / Onwukwe, Uchechukwu / Barnes, James / Chronopoulou, Myrsini / Ju-Nam, Yon / Thornton, Steven F / Rolfe, Stephen A / Ojeda, Jesús J

Langmuir : the ACS journal of surfaces and colloids

2024

Abstract: Avoiding microbial contamination and biofilm formation on the surfaces of aircraft fuel tanks is a major challenge in the aviation industry. The inevitable presence of water in fuel systems and nutrients provided by the fuel makes an ideal environment ... ...

Abstract	Avoiding microbial contamination and biofilm formation on the surfaces of aircraft fuel tanks is a major challenge in the aviation industry. The inevitable presence of water in fuel systems and nutrients provided by the fuel makes an ideal environment for bacteria, fungi, and yeast to grow. Understanding how microbes grow on different fuel tank materials is the first step to control biofilm formation in aviation fuel systems. In this study, biofilms of
Language	English
Publishing date	2024-02-06
Publishing country	United States
Document type	Journal Article
ZDB-ID	2005937-1
ISSN	1520-5827 ; 0743-7463
ISSN (online)	1520-5827
ISSN	0743-7463
DOI	10.1021/acs.langmuir.3c02803
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