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Article ; Online: Cross-Coupling of Benzylic and Aldehydic C-H Bonds via Photocatalytic Tandem Radical-Radical Coupling and Acceptorless Alcohol Dehydrogenation.

Guo, Yunfei / Qi, Jipeng / Guo, Hongyu / Liu, Rongfang / Zhou, Rong

2024 Volume 89, Issue 3, Page(s) 2032–2038

Abstract: The construction of a C-C bond by cross-coupling of two different C-H bonds with the release of hydrogen gas represents an ideal yet challenging bond formation strategy. Herein, we report a photocatalytic metal-free cross-coupling of benzylic and ... ...

Abstract	The construction of a C-C bond by cross-coupling of two different C-H bonds with the release of hydrogen gas represents an ideal yet challenging bond formation strategy. Herein, we report a photocatalytic metal-free cross-coupling of benzylic and aldehydic C-H bonds by synergistic catalysis of organophotocatalyst 4CzIPN and a thiol, which affords the corresponding α-aryl ketones in acceptable yields along with hydrogen evolution. The mechanistic investigation indicates a radical-radical coupling to give an intermediary alcohol, followed by an acceptorless alcohol dehydrogenation.
Language	English
Publishing date	2024-01-16
Publishing country	United States
Document type	Journal Article
ZDB-ID	123490-0
ISSN	1520-6904 ; 0022-3263
ISSN (online)	1520-6904
ISSN	0022-3263
DOI	10.1021/acs.joc.3c02427
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Zs.A 4473: Show issues

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Article ; Online: KIAA1429-mediated RXFP1 attenuates non-small cell lung cancer tumorigenesis via N6-methyladenosine modification.

Zhang, Zhixiang / Guo, Jipeng / Gong, Chongwen / Wu, Sai / Sun, Yanlei

Cancer biomarkers : section A of Disease markers

2024

Abstract: Background: N6-methyladenosine (m6A) modification has been associated with non-small cell lung cancer (NSCLC) tumorigenesis.: Objectives: This study aimed to determine the functions of Vir-like m6A methyltransferase-associated (KIAA1429) and relaxin ... ...

Abstract	Background: N6-methyladenosine (m6A) modification has been associated with non-small cell lung cancer (NSCLC) tumorigenesis. Objectives: This study aimed to determine the functions of Vir-like m6A methyltransferase-associated (KIAA1429) and relaxin family peptide receptor 1 (RXFP1) in NSCLC. Methods: A quantitative real-time polymerase chain reaction was used to analyze the mRNA levels of KIAA1429 and RXFP1 in NSCLC. After silencing KIAA1429 or RXFP1 in NSCLC cells, changes in the malignant phenotypes of NSCLC cells were assessed using cell counting kit-8, colony formation, and transwell assays. Finally, the m6A modification of RXFP1 mediated by KIAA1429 was confirmed using luciferase, methylated RNA immunoprecipitation, and western blot assays. Results: KIAA1429 and RXFP1 were upregulated and downregulated in NSCLC, respectively. Silencing of KIAA1429 attenuated the viability, migration, and invasion of NSCLC cells, whereas silencing of RXFP1 showed the opposite function in NSCLC cells. Moreover, RXFP1 expression was inhibited by KIAA1429 via m6A-modification. Therefore, silencing RXFP1 reversed the inhibitory effect of KIAA1429 knockdown in NSCLC cells. Conclusion: Our findings confirmed that the KIAA1429/RXFP1 axis promotes NSCLC tumorigenesis. This is the first study to reveal the inhibitory function of RXFP1 in NSCLC via KIAA1429-mediated m6A-modification. These findings may help identify new biomarkers for targeted NSCLC therapy.
Language	English
Publishing date	2024-02-07
Publishing country	Netherlands
Document type	Journal Article
ZDB-ID	2203517-5
ISSN	1875-8592 ; 1574-0153 ; 1875-8592
ISSN (online)	1875-8592 ; 1574-0153
ISSN	1875-8592
DOI	10.3233/CBM-230188
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Zs.A 6127: Show issues

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Article ; Online: Designing artificial ion channels with strict K

Li, Jipeng / Du, Linhan / Kong, Xian / Wu, Jianzhong / Lu, Diannan / Jiang, Lei / Guo, Wei

National science review

2023 Volume 10, Issue 12, Page(s) nwad260

Abstract: A biological potassium channel is >1000 times more permeable to ... ...

Abstract	A biological potassium channel is >1000 times more permeable to K
Language	English
Publishing date	2023-10-03
Publishing country	China
Document type	Journal Article
ZDB-ID	2745465-4
ISSN	2053-714X ; 2053-714X
ISSN (online)	2053-714X
ISSN	2053-714X
DOI	10.1093/nsr/nwad260
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Article ; Online: A nomogram for predicting cause-specific mortality among patients with cecal carcinoma: a study based on SEER database.

Zhou, Qianru / Zhan, Yan / Guo, Jipeng

BMC gastroenterology

2023 Volume 23, Issue 1, Page(s) 177

Abstract: Objective: Classical Cox proportional hazard models tend to overestimate the event probability in a competing risk setup. Due to the lack of quantitative evaluation of competitive risk data for colon cancer (CC), the present study aims to evaluate the ... ...

Abstract	Objective: Classical Cox proportional hazard models tend to overestimate the event probability in a competing risk setup. Due to the lack of quantitative evaluation of competitive risk data for colon cancer (CC), the present study aims to evaluate the probability of CC-specific death and construct a nomogram to quantify survival differences among CC patients. Methods: Data on patients diagnosed with CC between 2010 and 2015 were collected from the Surveillance, Epidemiology, and End Results Program (SEER) database. Patients were divided into a training dataset for the establishment of the model and a validation dataset to evaluate the performance the model at a ratio of 7:3. To evaluate the ability of multiple variables to predict cause-specific death in CC patients, univariate and multivariate analyses with Fine-Gray models were performed to screen the predictors of cause-specific death, and a nomogram for predicting cause-specific mortality was constructed. Then, the receiver operating characteristic (ROC) curve and the calibration curve were plotted to evaluate the prognostic performance of the nomogram. Results: The dataset was randomly divided into a training (n = 16,655) dataset and a validation (n = 7,139) dataset at a ratio of 7:3. In the training dataset, variables including pathological subtypes of tumors, pathological grading (degree of differentiation), AJCC staging, T-staging, surgical type, lymph node surgery, chemotherapy, tumor deposits, lymph node metastasis, liver metastasis, and lung metastasis were identified as independent risk factors for cause-specific death of CC patients. Among these factors, the AJCC stage had the strongest predictive ability, and these features were used to construct the final model. In the training dataset, the consistency index (C-index) of the model was 0.848, and the areas under the receiver operating characteristic curve (AUC) at 1, 3, and 5 years was 0.852, 0.861, and 0.856, respectively. In the validation dataset, the C-index of the model was 0.847, and the AUC at 1 year, 3 years, and 5 years was 0.841, 0.862, and 0.852, respectively, indicating that this nomogram had an excellent and robust predictive performance. Conclusion: This study can help clinical doctors make better clinical decisions and provide better support for patients with CC.
MeSH term(s)	Humans ; Nomograms ; Cause of Death ; Colonic Neoplasms ; Databases, Factual ; Carcinoma
Language	English
Publishing date	2023-05-23
Publishing country	England
Document type	Journal Article
ZDB-ID	2041351-8
ISSN	1471-230X ; 1471-230X
ISSN (online)	1471-230X
ISSN	1471-230X
DOI	10.1186/s12876-023-02802-7
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Article ; Online: Extraradical hyphae alleviate nitrogen deposition-induced phosphorus deficiency in ectomycorrhiza-dominated forests.

Zhang, Ziliang / Guo, Wanji / Wang, Jipeng / Lambers, Hans / Yin, Huajun

The New phytologist

2023 Volume 239, Issue 5, Page(s) 1651–1664

Abstract: The continuous imbalance between nitrogen (N) and phosphorus (P) deposition is expected to shift many ecosystems from N- to P limitation. Extraradical hyphae of ectomycorrhizal (ECM) fungi play important roles in plant nutrient acquisition under nutrient ...

Abstract	The continuous imbalance between nitrogen (N) and phosphorus (P) deposition is expected to shift many ecosystems from N- to P limitation. Extraradical hyphae of ectomycorrhizal (ECM) fungi play important roles in plant nutrient acquisition under nutrient deficiency. However, whether and how ECM hyphae enhance soil P availability to alleviate N-induced P deficiency remains unclear. We investigated the impacts of ECM hyphae on transformations among different soil P fractions and underlying mechanisms under N deposition in two ECM-dominated forests. Ectomycorrhizal hyphae enhanced soil P availability under N addition by stimulating mineralization of organic P (Po) and desorption and solubilization of secondary mineral P, as indicated by N-induced increase in positive hyphal effect on plant-available P pool and negative hyphal effects on Po and secondary mineral P pools. Moreover, ECM hyphae increased soil phosphatase activity and abundance of microbial genes associated with Po mineralization and inorganic P solubilization, while decreasing concentrations of Fe/Al oxides. Our results suggest that ECM hyphae can alleviate N-induced P deficiency in ECM-dominated forests by regulating interactions between microbial and abiotic factors involved in soil P transformations. This advances our understanding of plant acclimation strategies via mediating plant-mycorrhiza interactions to sustain forest production and functional stability under changing environments.
MeSH term(s)	Phosphorus ; Ecosystem ; Hyphae ; Nitrogen ; Forests ; Mycorrhizae/physiology ; Minerals ; Plants ; Soil ; Soil Microbiology
Chemical Substances	Phosphorus (27YLU75U4W) ; Nitrogen (N762921K75) ; Minerals ; Soil
Language	English
Publishing date	2023-06-15
Publishing country	England
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	208885-x
ISSN	1469-8137 ; 0028-646X
ISSN (online)	1469-8137
ISSN	0028-646X
DOI	10.1111/nph.19078
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Z 868: Show issues

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Article ; Online: Logarithmic Schatten- p Norm Minimization for Tensorial Multi-View Subspace Clustering.

Guo, Jipeng / Sun, Yanfeng / Gao, Junbin / Hu, Yongli / Yin, Baocai

IEEE transactions on pattern analysis and machine intelligence

2023 Volume 45, Issue 3, Page(s) 3396–3410

Abstract: The low-rank tensor could characterize inner structure and explore high-order correlation among multi-view representations, which has been widely used in multi-view clustering. Existing approaches adopt the tensor nuclear norm (TNN) as a convex ... ...

Abstract	The low-rank tensor could characterize inner structure and explore high-order correlation among multi-view representations, which has been widely used in multi-view clustering. Existing approaches adopt the tensor nuclear norm (TNN) as a convex approximation of non-convex tensor rank function. However, TNN treats the different singular values equally and over-penalizes the main rank components, leading to sub-optimal tensor representation. In this paper, we devise a better surrogate of tensor rank, namely the tensor logarithmic Schatten- p norm ([Formula: see text]N), which fully considers the physical difference between singular values by the non-convex and non-linear penalty function. Further, a tensor logarithmic Schatten- p norm minimization ([Formula: see text]NM)-based multi-view subspace clustering ([Formula: see text]NM-MSC) model is proposed. Specially, the proposed [Formula: see text]NM can not only protect the larger singular values encoded with useful structural information, but also remove the smaller ones encoded with redundant information. Thus, the learned tensor representation with compact low-rank structure will well explore the complementary information and accurately characterize the high-order correlation among multi-views. The alternating direction method of multipliers (ADMM) is used to solve the non-convex multi-block [Formula: see text]NM-MSC model where the challenging [Formula: see text]NM problem is carefully handled. Importantly, the algorithm convergence analysis is mathematically established by showing that the sequence generated by the algorithm is of Cauchy and converges to a Karush-Kuhn-Tucker (KKT) point. Experimental results on nine benchmark databases reveal the superiority of the [Formula: see text]NM-MSC model.
Language	English
Publishing date	2023-02-03
Publishing country	United States
Document type	Journal Article
ISSN	1939-3539
ISSN (online)	1939-3539
DOI	10.1109/TPAMI.2022.3179556
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Article ; Online: Millimeter-scale ultrathin suspended metasurface integrated high-finesse optomechanical cavity.

Xu, Jipeng / Liu, Ken / Sang, You / Tan, Zhongqi / Guo, Chucai / Zhu, Zhihong

Optics letters

2023 Volume 47, Issue 21, Page(s) 5481–5484

Abstract: A typical optomechanical system is a cavity with one movable mirror and one fixed mirror. However, this configuration has been considered incapable of integrating sensitive mechanical elements while maintaining high cavity finesse. Although the membrane- ... ...

Abstract	A typical optomechanical system is a cavity with one movable mirror and one fixed mirror. However, this configuration has been considered incapable of integrating sensitive mechanical elements while maintaining high cavity finesse. Although the membrane-in-the-middle solution seems to be able to overcome this contradiction, it introduces additional components that will lead to unexpected insertion loss, resulting in reduced cavity quality. Here we propose a Fabry-Perot optomechanical cavity composed of an ultrathin suspended Si
Language	English
Publishing date	2023-05-23
Publishing country	United States
Document type	Journal Article
ISSN	1539-4794
ISSN (online)	1539-4794
DOI	10.1364/OL.465567
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Article ; Online: Nanocapsule of MnS Nanopolyhedron Core@CoS Nanoparticle/Carbon Shell@Pure Carbon Shell as Anode Material for High-Performance Lithium Storage.

Yang, Peng / Yuan, Yongfeng / Zhang, Dong / Yang, Qiuhe / Guo, Shaoyi / Cheng, Jipeng

Molecules (Basel, Switzerland)

2023 Volume 28, Issue 2

Abstract: MnS has been explored as an anode material for lithium-ion batteries due to its high theoretical capacity, but low electronic conductivity and severe volume change induce low reversible capacity and poor cycling performance. In this work, the nanocapsule ...

Abstract	MnS has been explored as an anode material for lithium-ion batteries due to its high theoretical capacity, but low electronic conductivity and severe volume change induce low reversible capacity and poor cycling performance. In this work, the nanocapsule consisting of MnS nanopolyhedrons confined in independent, closed and conductive hollow polyhedral nanospheres is prepared by embedding MnCO
MeSH term(s)	Nanocapsules ; Lithium ; Nanospheres ; Carbon ; Electrodes
Chemical Substances	Nanocapsules ; Lithium (9FN79X2M3F) ; Carbon (7440-44-0)
Language	English
Publishing date	2023-01-16
Publishing country	Switzerland
Document type	Journal Article
ZDB-ID	1413402-0
ISSN	1420-3049 ; 1431-5165 ; 1420-3049
ISSN (online)	1420-3049
ISSN	1431-5165 ; 1420-3049
DOI	10.3390/molecules28020898
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Zs.MO 81: Show issues

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Article: Metabolomic analysis revealed the edible and extended-application potential of specific

Xu, Yudi / Liu, Xianju / Gao, Yingying / Liu, Yan / Chen, Sha / Chen, Chang / Cheng, Jintang / Guo, Cong / Xu, Qingxia / Di, Jipeng / Zhang, Jun / Liu, An / Jiang, Jinzhu

Heliyon

2024 Volume 10, Issue 4, Page(s) e25990

Abstract: The diverse applications of various tissues ... ...

Abstract	The diverse applications of various tissues of
Language	English
Publishing date	2024-02-15
Publishing country	England
Document type	Journal Article
ZDB-ID	2835763-2
ISSN	2405-8440
ISSN	2405-8440
DOI	10.1016/j.heliyon.2024.e25990
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Article ; Online: Reconstruction of Large Periorbital Defect With a Pre-expanded Retrograde Postauricular Island Flap: Our 13-Year Experiences.

Fan, Jincai / Yang, Jifan / Han, Bing / Huang, Rong / Guo, Rui / Zhang, Tiran / Song, Jipeng

The Journal of craniofacial surgery

2023

Abstract: The clinical application of the retrograde postauricular island flap has been widely restricted because of its limited size and high morbidity of venous congestion. Thus, in this article, we introduced a pre-expanded retrograde postauricular island flap ... ...

Abstract	The clinical application of the retrograde postauricular island flap has been widely restricted because of its limited size and high morbidity of venous congestion. Thus, in this article, we introduced a pre-expanded retrograde postauricular island flap to reconstruct the large periorbital defect. A total of 13 patients with periorbital lesions who had undergone the treatment of our flap were enrolled in the study. The whole series of operations was divided into 3 parts, including expander implantation in the postauricular region, a series of expander inflations, and flap transferring, and special incisions were also designed in the procedure. In the end, all the flaps survived without serious complications. The mean size of the harvested flaps was 2.65 times larger than that of our nonexpanded cases. The reconstructed periorbital region showed a functional and aesthetic repair outcome after a follow-up of 3 to 30 months. To conclude, the pre-expanded retrograde postauricular island flap was a safe way to reconstruct a larger periorbital defect.
Language	English
Publishing date	2023-11-20
Publishing country	United States
Document type	Journal Article
ZDB-ID	1159501-2
ISSN	1536-3732 ; 1049-2275
ISSN (online)	1536-3732
ISSN	1049-2275
DOI	10.1097/SCS.0000000000009909
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Zs.A 3761: Show issues			Location: Je nach Verfügbarkeit (siehe Angabe bei Bestand) bis Jg. 1994: Bestellungen von Artikeln über das Online-Bestellformular Jg. 1995 - 2021: Lesesall (2.OG) ab Jg. 2022: Lesesaal (EG)
Zs.MO 175: Show issues

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