Article: Ionized o-, m-, and p-difluorobenzene dissociate through ring-opened intermediates: a TPEPICO investigation.
Journal of the American Society for Mass Spectrometry
2009 Volume 20, Issue 1, Page(s) 20–24
Abstract: Threshold photoelectron photoion coincidence (TPEPICO) experiments have shown that o-, m-, and p ... for the initial isomerization of 4.48 +/- 0.05, 4.55 +/- 0.05, and 4.68 +/- 0.05 eV for o-, m-, and p ... difluorobenzene ions dissociate via a common, ring-opened intermediate and not via ionized p-difluorobenzene. Rice ...
Abstract | Threshold photoelectron photoion coincidence (TPEPICO) experiments have shown that o-, m-, and p-difluorobenzene ions dissociate via a common, ring-opened intermediate and not via ionized p-difluorobenzene. Rice-Ramsperger-Kassel-Marcus (RRKM) modeling of the experimental breakdown curves yields activation energies for the initial isomerization of 4.48 +/- 0.05, 4.55 +/- 0.05, and 4.68 +/- 0.05 eV for o-, m-, and p-difluorobenzene, respectively. These values place each ion at a similar absolute energy and thus similar transition states. A large positive DeltaS(double dagger) for each ion (ca 100 J K(-1) mol(-1)) suggests a ring-opened structure for these transition states. |
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Language | English |
Publishing date | 2009-01 |
Publishing country | United States |
Document type | Journal Article |
ZDB-ID | 1073671-2 |
ISSN | 1044-0305 |
ISSN | 1044-0305 |
DOI | 10.1016/j.jasms.2008.09.020 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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