Article ; Online: Unexplored reactivity of (S
Chemical communications (Cambridge, England)
2019 Volume 55, Issue 44, Page(s) 6189–6192
Abstract: ... provided that the elemental metal can retrocede electron(s) to empty antibonding sulfur σ* levels. ...
Abstract | We demonstrate here the low temperature topochemical insertion of transition elements (Fe, Ni, and Cu) in precursors containing pre-formed (Sn)2- (n = 2 and 3) oligomers. Indeed, this soft chemistry route opens the door to the easy, orientated synthesis of low dimensional transition metal compounds provided that the elemental metal can retrocede electron(s) to empty antibonding sulfur σ* levels. |
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Language | English |
Publishing date | 2019-05-02 |
Publishing country | England |
Document type | Journal Article |
ZDB-ID | 1472881-3 |
ISSN | 1364-548X ; 1359-7345 ; 0009-241X |
ISSN (online) | 1364-548X |
ISSN | 1359-7345 ; 0009-241X |
DOI | 10.1039/c9cc01338e |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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