Article: Regioselective catalytic carbonylation and borylation of alkynes with aryldiazonium salts toward α-unsubstituted β-boryl ketones.
2022 Volume 13, Issue 41, Page(s) 12122–12126
Abstract: A new Pd/Cu-catalyzed carbonylation and borylation of alkynes with aryldiazonium salts toward α-unsubstituted β-boryl ketones with complete regioselectivity has been developed. This transformation shows broad substrate scope and excellent functional- ... ...
Abstract | A new Pd/Cu-catalyzed carbonylation and borylation of alkynes with aryldiazonium salts toward α-unsubstituted β-boryl ketones with complete regioselectivity has been developed. This transformation shows broad substrate scope and excellent functional-group tolerance. Moreover, the obtained 1,2-carbonylboration products provide substantial opportunities for further transformations which cannot be obtained by known carbonylation procedures. Preliminary mechanistic studies indicate that the three hydrogen atoms of the products originated from ethyl acetate. |
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Language | English |
Publishing date | 2022-09-30 |
Publishing country | England |
Document type | Journal Article |
ZDB-ID | 2559110-1 |
ISSN | 2041-6539 ; 2041-6520 |
ISSN (online) | 2041-6539 |
ISSN | 2041-6520 |
DOI | 10.1039/d2sc04867a |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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