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  1. Book ; Online ; E-Book: Biopolymer-based metal nanoparticle chemistry for sustainable applications / Volume 1,

    Nasrollahzadeh, Mahmoud

    2021  

    Author's details Mahmoud Nasrollahzadeh
    Keywords Biopolymers ; Nanoparticles ; Metallography
    Subject code 572.33
    Language English
    Size 1 online resource (500 pages)
    Publisher Elsevier
    Publishing place Amsterdam, Netherlands
    Document type Book ; Online ; E-Book
    Remark Zugriff für angemeldete ZB MED-Nutzerinnen und -Nutzer
    ISBN 0-12-822123-2 ; 0-12-822108-9 ; 978-0-12-822123-5 ; 978-0-12-822108-2
    Database ZB MED Catalogue: Medicine, Health, Nutrition, Environment, Agriculture

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  2. Article ; Online: Iran's agricultural waste.

    Akbari, Reza / Nasrollahzadeh, Mahmoud

    Science (New York, N.Y.)

    2022  Volume 375, Issue 6584, Page(s) 984–985

    Language English
    Publishing date 2022-03-03
    Publishing country United States
    Document type Letter
    ZDB-ID 128410-1
    ISSN 1095-9203 ; 0036-8075
    ISSN (online) 1095-9203
    ISSN 0036-8075
    DOI 10.1126/science.abn9765
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions.

    Nasrollahzadeh, Mahmoud

    Molecules (Basel, Switzerland)

    2018  Volume 23, Issue 10

    Abstract: Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically ... ...

    Abstract Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and C
    MeSH term(s) Carbon/chemistry ; Catalysis ; Chemistry Techniques, Synthetic ; Coordination Complexes/chemistry ; Dendrimers/chemistry ; Magnetite Nanoparticles/chemistry ; Molecular Structure ; Palladium/chemistry
    Chemical Substances Coordination Complexes ; Dendrimers ; Magnetite Nanoparticles ; Palladium (5TWQ1V240M) ; Carbon (7440-44-0)
    Language English
    Publishing date 2018-10-04
    Publishing country Switzerland
    Document type Journal Article ; Review
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules23102532
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Starch-based hydrogels for environmental applications: A review.

    Dong, Yahao / Ghasemzadeh, Mohadeseh / Khorsandi, Zahra / Sheibani, Reza / Nasrollahzadeh, Mahmoud

    International journal of biological macromolecules

    2024  , Page(s) 131956

    Abstract: Water sources have become extremely scarce and contaminated by organic and inorganic industrial and agricultural pollutants as well as household wastes. Poisoning water resources by dyes and metals is a problem because contaminated water can leak into ... ...

    Abstract Water sources have become extremely scarce and contaminated by organic and inorganic industrial and agricultural pollutants as well as household wastes. Poisoning water resources by dyes and metals is a problem because contaminated water can leak into subsurface and surface sources, causing serious contamination and health problems. Therefore, developing wastewater treatment technologies is valuable. Today, hydrogels have attracted considerable attention owing to their broad applications. Hydrogels are polymeric network compositions with significant water-imbibing capacity. Hydrogels have potential applications in diverse fields such as biomedical, personal care products, pharmaceuticals, cosmetics, and biosensors. They can be prepared by using natural (biopolymers) and synthetic polymers. Synthetic polymer-based hydrogels obtained from petrochemicals are not environmentally benign; thus, abundant plant-based polysaccharides are found as more suitable compounds for making biodegradable hydrogels. Polysaccharides with many advantages such as non-toxicity, biodegradability, availability, inexpensiveness, etc. are widely employed for the preparation of environmentally friendly hydrogels. Polysaccharides-based hydrogels containing chitin, chitosan, gum, starch (St), etc. are employed to remove pollutants, metals, and dyes. Among these, St has attracted a lot of attention. St can be mixed with other compounds to make hydrogels, which remove dyes and metal ions to variable degrees of efficiency. Although St has numerous advantages, it suffers from drawbacks such as low stability, low water solubility, and fast degradability in water which limit its application as an environmental adsorbent. As an effective way to overcome these weaknesses, various modification approaches to form starch-based hydrogels (SBHs) employing different compounds have been reported. The preparation methods and applications of SBH adsorbents in organic dyes, hazardous materials, and toxic ions elimination from water resources have been comprehensively discussed in this review.
    Language English
    Publishing date 2024-04-29
    Publishing country Netherlands
    Document type Journal Article ; Review
    ZDB-ID 282732-3
    ISSN 1879-0003 ; 0141-8130
    ISSN (online) 1879-0003
    ISSN 0141-8130
    DOI 10.1016/j.ijbiomac.2024.131956
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Synthesis of palladium nanoparticles stabilized on Schiff base-modified ZnO particles as a nanoscale catalyst for the phosphine-free Heck coupling reaction and 4-nitrophenol reduction.

    Baran, Nuray Yılmaz / Baran, Talat / Nasrollahzadeh, Mahmoud

    Scientific reports

    2023  Volume 13, Issue 1, Page(s) 12008

    Abstract: Recently, the development of heterogeneous nanocatalytic systems using solid supports has been gaining importance due to some advantages such as easy handling, high thermal stability, high efficiency, reusability, and so on. Therefore, the design of ... ...

    Abstract Recently, the development of heterogeneous nanocatalytic systems using solid supports has been gaining importance due to some advantages such as easy handling, high thermal stability, high efficiency, reusability, and so on. Therefore, the design of catalyst supports for the preparation of stable heterogeneous catalytic systems is of great importance. In this work, Schiff base-modified ZnO particles have been developed (ZnO-Scb) as a novel support. A heterogeneous nanocatalyst system has then been prepared by immobilizing palladium nanoparticles (Pd NPs) on the ZnO-Scb surface as the support. The resulting palladium nanocatalyst (Pd-ZnO-Scb) structure has been characterized by different analytical techniques (FT-IR, XRD, TEM, FE-SEM, elemental mapping and EDS) and used to catalyze the Heck coupling reactions and 4-nitrophenol (4-NP) reduction. Test results revealed that Pd-ZnO-Scb could effectively couple various aryl halides with styrene in yields of up to 98% in short reaction times. Pd-ZnO-Scb was also efficiently used in the complete 4-NP reduction within 135 s at room temperature. Additionally, it was found that Pd-ZnO-Scb was more effective than other reported catalysts in the Heck coupling reaction. Moreover, the recycling tests indicated that Pd-ZnO-Scb could be easily isolated from the reaction medium and reused in seven consecutive catalytic runs while retaining its nanostructure.
    Language English
    Publishing date 2023-07-25
    Publishing country England
    Document type Journal Article
    ZDB-ID 2615211-3
    ISSN 2045-2322 ; 2045-2322
    ISSN (online) 2045-2322
    ISSN 2045-2322
    DOI 10.1038/s41598-023-38898-w
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Better preparation for Iran's forest fires.

    Tavakoli Hafshejani, Mahmood / Nasrollahzadeh, Mahmoud / Mirkhani, Valiollah

    Science (New York, N.Y.)

    2022  Volume 377, Issue 6604, Page(s) 379

    MeSH term(s) Iran ; Wildfires/economics ; Wildfires/prevention & control
    Language English
    Publishing date 2022-07-21
    Publishing country United States
    Document type Letter
    ZDB-ID 128410-1
    ISSN 1095-9203 ; 0036-8075
    ISSN (online) 1095-9203
    ISSN 0036-8075
    DOI 10.1126/science.add5194
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions

    Mahmoud Nasrollahzadeh

    Molecules, Vol 23, Iss 10, p

    2018  Volume 2532

    Abstract: Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically ... ...

    Abstract Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed.
    Keywords magnetic nanoparticles ; palladium complexes ; coupling reactions ; Organic chemistry ; QD241-441
    Subject code 540
    Language English
    Publishing date 2018-10-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  8. Article ; Online: Fermentation of Rubus dolichocarpus juice using Lactobacillus gasseri and Lacticaseibacillus casei and protecting phenolic compounds by Stevia extract during cold storage.

    Karimkhani, Mohammad Mahdi / Jamshidi, Abdollah / Nasrollahzadeh, Mahmoud / Armin, Mohammad / Jafari, Seid Mahdi / Zeinali, Tayebeh

    Scientific reports

    2024  Volume 14, Issue 1, Page(s) 5711

    Abstract: This study aimed to investigate the biological activities of Lactobacillus gasseri SM 05 (L. gasseri) and Lacticaseibacillus casei subsp. casei PTCC 1608 (L. casei) in the black raspberry (Rubus dolichocarpus) juice (BRJ) environment, and also the anti- ... ...

    Abstract This study aimed to investigate the biological activities of Lactobacillus gasseri SM 05 (L. gasseri) and Lacticaseibacillus casei subsp. casei PTCC 1608 (L. casei) in the black raspberry (Rubus dolichocarpus) juice (BRJ) environment, and also the anti-adhesion activity against Salmonella typhimurium (S. typhimurium) in fermented black raspberry juice (FBRJ). Results showed significant anti-adhesion activity in Caco-2 epithelial cells. In the anti-adhesion process, lactic acid bacteria (LAB) improve intestinal health by preventing the adhesion of pathogens. Adding LAB to BRJ produces metabolites with bacteriocin properties. Major findings of this research include improved intestinal health, improved antidiabetic properties, inhibition of degradation of amino acids, and increase in the nutritional value of foods that have been subjected to heat processing by preventing Maillard inhibition, and inhibition of oxidation of foodstuff by increased antioxidant activity of BRJ. Both species of Lactobacillus effectively controlled the growth of S. typhimurium during BRJ fermentation. Moreover, in all tests, as well as Maillard's and α-amylase inhibition, L. gasseri was more effective than L. casei. The phenolic and flavonoid compounds increased significantly after fermentation by both LAB (p < 0.05). Adding Stevia extract to FBRJ and performing the HHP process showed convenient protection of phenolic compounds compared to heat processing.
    MeSH term(s) Humans ; Lacticaseibacillus casei ; Fermentation ; Rubus ; Lactobacillus gasseri ; Stevia ; Caco-2 Cells ; Plant Extracts/pharmacology ; Probiotics
    Chemical Substances Plant Extracts
    Language English
    Publishing date 2024-03-08
    Publishing country England
    Document type Journal Article
    ZDB-ID 2615211-3
    ISSN 2045-2322 ; 2045-2322
    ISSN (online) 2045-2322
    ISSN 2045-2322
    DOI 10.1038/s41598-024-56235-7
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Lignosulfonate valorization into a Cu-containing magnetically recyclable photocatalyst for treating wastewater pollutants in aqueous media.

    Orooji, Yasin / Pakzad, Khatereh / Nasrollahzadeh, Mahmoud

    Chemosphere

    2022  Volume 305, Page(s) 135180

    Abstract: This study presents an eco-friendly and economical process for preparing a magnetic copper complex conjugated to modified calcium lignosulfonate (LS) through a diamine ( ... ...

    Abstract This study presents an eco-friendly and economical process for preparing a magnetic copper complex conjugated to modified calcium lignosulfonate (LS) through a diamine (Fe
    MeSH term(s) Coloring Agents/chemistry ; Copper/chemistry ; Diamines ; Environmental Pollutants ; Lignin/analogs & derivatives ; Spectroscopy, Fourier Transform Infrared ; Waste Water ; Water
    Chemical Substances Coloring Agents ; Diamines ; Environmental Pollutants ; Waste Water ; Water (059QF0KO0R) ; Copper (789U1901C5) ; lignosulfuric acid (8062-15-5) ; Lignin (9005-53-2)
    Language English
    Publishing date 2022-05-31
    Publishing country England
    Document type Journal Article
    ZDB-ID 120089-6
    ISSN 1879-1298 ; 0045-6535 ; 0366-7111
    ISSN (online) 1879-1298
    ISSN 0045-6535 ; 0366-7111
    DOI 10.1016/j.chemosphere.2022.135180
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Magnetic chitosan stabilized Cu(II)-tetrazole complex: an effective nanocatalyst for the synthesis of 3-imino-2-phenylisoindolin-1-one derivatives under ultrasound irradiation.

    Nasrollahzadeh, Mahmoud / Shafiei, Nasrin / Orooji, Yasin

    Scientific reports

    2022  Volume 12, Issue 1, Page(s) 6724

    Abstract: In the present research, a recyclable catalyst has been prepared via a simple approach using chitosan as a linear polysaccharide. This paper reports the synthesis of novel copper(II) complex of 5-phenyl-1H-tetrazole immobilized on magnetic chitosan (MCS@ ... ...

    Abstract In the present research, a recyclable catalyst has been prepared via a simple approach using chitosan as a linear polysaccharide. This paper reports the synthesis of novel copper(II) complex of 5-phenyl-1H-tetrazole immobilized on magnetic chitosan (MCS@PhTet@Cu(II)) as an effective catalyst. Transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), vibrating sample magnetometer (VSM), Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), and inductively coupled plasma mass spectrometry (ICP-MS) techniques were applied for the characterization of the catalyst. The catalytic activity of MCS@PhTet@Cu(II) was evaluated in the ultrasound-assisted synthesis of 3-imino-2-phenylisoindolin-1-one derivatives via the reaction between benzoyl chloride and arylcyanamides in ethanol at ambient temperature. Utilizing a wide variety of arylcyanamides under mild conditions, no use of toxic organic solvents, moderate reaction time, high yields along with catalyst excellent reusability and easy separation of the products without any tedious separation techniques, made this method a novel and simple process. The resulting heterogeneous catalyst showed valuable advantages such as easier work-up, better stability, and greater separation ability using an external magnet. The catalyst showed high efficacy and recyclability even after five cycles with no significant loss of its efficacy. The present methodology provides a path for the preparation of structurally diverse heterocyclic compounds, which may exhibit important biological activity.
    MeSH term(s) Chitosan/chemistry ; Magnetic Phenomena ; Spectroscopy, Fourier Transform Infrared ; Tetrazoles
    Chemical Substances Tetrazoles ; 1H-tetrazole (288-94-8) ; Chitosan (9012-76-4)
    Language English
    Publishing date 2022-04-25
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2615211-3
    ISSN 2045-2322 ; 2045-2322
    ISSN (online) 2045-2322
    ISSN 2045-2322
    DOI 10.1038/s41598-022-10591-4
    Database MEDical Literature Analysis and Retrieval System OnLINE

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