Article ; Online: Synthesis of the precursors of iminosugars with 7-membered ring.
2022 Volume 518, Page(s) 108584
Abstract: d-Glucose was converted into the orthogonally protected open-chain derivative having different blocks at both terminal positions: C1 and C6. Selective deprotection of the C1-position opened a route to intermediate with the D-gluco-configuration, while ... ...
| Abstract | d-Glucose was converted into the orthogonally protected open-chain derivative having different blocks at both terminal positions: C1 and C6. Selective deprotection of the C1-position opened a route to intermediate with the D-gluco-configuration, while deprotection at the C6-position gave the L-gulo isomer. In both derivatives, the oxime functionality was installed at the proper terminal position, which produced the corresponding precursors of a family of 7-membered ring iminosugars. One of these oximes was converted into the direct precursor: 6,1-bromonitrile. |
|---|---|
| MeSH term(s) | Glucose ; Isomerism ; Oximes |
| Chemical Substances | Oximes ; Glucose (IY9XDZ35W2) |
| Language | English |
| Publishing date | 2022-05-18 |
| Publishing country | Netherlands |
| Document type | Journal Article |
| ZDB-ID | 1435-7 |
| ISSN | 1873-426X ; 0008-6215 |
| ISSN (online) | 1873-426X |
| ISSN | 0008-6215 |
| DOI | 10.1016/j.carres.2022.108584 |
| Database | MEDical Literature Analysis and Retrieval System OnLINE |
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