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Article ; Online: Ligand Steric Interactions Modulate Multidentate Ligand Exchange Pathways: Kinetics of Nickel(II) Ion Capture from N-Substituted IDA Complexes by CDTA.

Boland, Nathan E / Stone, Alan T

2022 Volume 61, Issue 34, Page(s) 13355–13368

Abstract: Exchange reactions between multidentate ligands (also known as chelating agents) contribute to kinetic control of metal ion speciation in aquatic environments. However, the complexity of the stepwise reaction mechanism complicates predictions of kinetic ... ...

Abstract	Exchange reactions between multidentate ligands (also known as chelating agents) contribute to kinetic control of metal ion speciation in aquatic environments. However, the complexity of the stepwise reaction mechanism complicates predictions of kinetic behavior (rates, rate laws, and mechanisms). Clarity is achieved with the adjunctive-semijunctive-disjunctive paradigm, which categorizes multidentate ligand exchange pathways along a continuum according to the decreasing ease of forming intermediate mixed-ligand ternary complexes. In order to better understand how steric interaction between entering and leaving ligands affects reaction pathways and kinetic behavior, we use a capillary electrophoresis method to monitor exchange between
MeSH term(s)	Edetic Acid/analogs & derivatives ; Kinetics ; Ligands ; Metals ; Nickel
Chemical Substances	Ligands ; Metals ; CDTA (482-54-2) ; Nickel (7OV03QG267) ; Edetic Acid (9G34HU7RV0)
Language	English
Publishing date	2022-08-15
Publishing country	United States
Document type	Journal Article
ZDB-ID	1484438-2
ISSN	1520-510X ; 0020-1669
ISSN (online)	1520-510X
ISSN	0020-1669
DOI	10.1021/acs.inorgchem.2c01330
Database	MEDical Literature Analysis and Retrieval System OnLINE

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Article ; Online: ASES and UCLA Are Responsive Patient-Reported Outcome Measures After Rotator Cuff Repair: A Systematic Review and Meta-analysis.

Abed, Varag / Kapp, Sabryn / Nichols, Michael / Brunty, Nathan / Conley, Caitlin E W / Jacobs, Cale A / Robinson, Lauren E / Stone, Austin V

The American journal of sports medicine

2024 , Page(s) 3635465231213870

Abstract: Background: Multiple patient-reported outcome measures (PROMs) have been used to assess shoulder function, but it is unknown which are the most effective.: Purpose/hypothesis: The purpose of this study was to report the multiple PROMs used after ... ...

Abstract	Background: Multiple patient-reported outcome measures (PROMs) have been used to assess shoulder function, but it is unknown which are the most effective. Purpose/hypothesis: The purpose of this study was to report the multiple PROMs used after rotator cuff repair (RCR) and to compare the responsiveness between them. It was hypothesized that the Western Ontario Rotator Cuff PROM would be the most responsive and commonly used in patients undergoing RCR. Study design: Meta-analysis; Level of evidence, 4. Methods: A systematic review was conducted in accordance with PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) and PRISMA-Searching extension guidelines via PubMed/MEDLINE, Embase (Elsevier), and Web of Science (Clarivate). Patient and study characteristics were extracted. From the studies that met inclusion criteria for responsiveness analysis (≥2 PROMs reported, 1-year minimum follow-up, and pre- and postoperative PROM means and standard deviations reported), the authors compared the responsiveness between PROM instruments using effect size and relative efficiency (RE) if a PROM could be compared with another in ≥10 articles. Results: A total of 252 studies met inclusion criteria (32,072 patients; mean age, 59.6 years; mean body mass index, 28.7; mean follow-up time, 27.8 months). Range of motion was reported in 131 (52%) studies and imaging findings were reported in 123 (49%) studies. There were 67 PROM instruments identified; the most commonly used were the American Shoulder and Elbow Surgeon (ASES) (n = 183; 73%), Visual Analog Scale (VAS) (n = 163; 65%), and Constant (n = 118; 47%) scores. The 3 PROMs with the highest effect sizes were the University of California, Los Angeles (UCLA) (2.51), Western Ontario Rotator Cuff (2.42), and ASES (2.00) scores. Overall, UCLA and ASES scores were the most responsive PROMs. The ASES PROM was more responsive than the VAS (RE, 1.70), Constant (RE, 2.76), Simple Shoulder Test (RE, 1.67), and Single Assessment Numeric Evaluation (RE, 2.14) scores. The UCLA PROM was more responsive than the ASES (RE, 1.03), VAS (RE, 3.66), Constant (RE, 1.72), and Simple Shoulder Test (RE, 1.66) scores. Conclusion: ASES and UCLA scores were the most responsive PROMs after RCR. The authors recommend widespread adoption of ASES and UCLA scores for clinical and research standardization; however, the UCLA PROM requires in-person range of motion and strength testing, which is a practical limitation and barrier to long-term follow-up.
Language	English
Publishing date	2024-01-17
Publishing country	United States
Document type	Journal Article
ZDB-ID	197482-8
ISSN	1552-3365 ; 0363-5465
ISSN (online)	1552-3365
ISSN	0363-5465
DOI	10.1177/03635465231213870
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Article ; Online: Enabling Data Discovery with the Astrobiology Resource Metadata Standard.

Wolfe, Shawn R / Lafuente, Barbara / Keller, Richard M / Detweiler, Angela M / Bristow, Thomas F / Parenteau, Mary N / Boydstun, Kevin / Dateo, Christopher E / Des Marais, David J / Jahnke, Linda L / Rojo, Sara / Stone, Nathan / Vorobets, Mark

Astrobiology

2024 Volume 24, Issue 2, Page(s) 131–137

Abstract: As scientific investigations increasingly adopt Open Science practices, reuse of data becomes paramount. However, despite decades of progress in internet search tools, finding relevant astrobiology datasets for an envisioned investigation remains ... ...

Abstract	As scientific investigations increasingly adopt Open Science practices, reuse of data becomes paramount. However, despite decades of progress in internet search tools, finding relevant astrobiology datasets for an envisioned investigation remains challenging due to the precise and atypical needs of the astrobiology researcher. In response, we have developed the Astrobiology Resource Metadata Standard (ARMS), a metadata standard designed to uniformly describe astrobiology "resources," that is, virtually any product of astrobiology research. Those resources include datasets, physical samples, software (modeling codes and scripts), publications, websites, images, videos, presentations, and so on. ARMS has been formulated to describe astrobiology resources generated by individual scientists or smaller scientific teams, rather than larger mission teams who may be required to use more complex archival metadata schemes. In the following, we discuss the participatory development process, give an overview of the metadata standard, describe its current use in practice, and close with a discussion of additional possible uses and extensions.
MeSH term(s)	Exobiology ; Metadata ; Software
Language	English
Publishing date	2024-02-22
Publishing country	United States
Document type	Journal Article
ZDB-ID	2047736-3
ISSN	1557-8070 ; 1531-1074
ISSN (online)	1557-8070
ISSN	1531-1074
DOI	10.1089/ast.2023.0067
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Article ; Online: Mutations in EFEMP1 in Patients with Juvenile Open-Angle Glaucoma.

Tejan-Kamara, Aminatta Z / Boese, Erin A / Pouw, Andrew E / Sears, Nathan C / Roos, Ben R / Stone, Edwin M / Scheetz, Todd E / Fingert, John H

Ophthalmology. Glaucoma

2023 Volume 6, Issue 6, Page(s) 668–670

MeSH term(s)	Humans ; Glaucoma, Open-Angle/diagnosis ; Glaucoma, Open-Angle/genetics ; Mutation ; Glaucoma ; Extracellular Matrix Proteins/genetics
Chemical Substances	EFEMP1 protein, human ; Extracellular Matrix Proteins
Language	English
Publishing date	2023-05-22
Publishing country	United States
Document type	Journal Article
ISSN	2589-4196
ISSN (online)	2589-4196
DOI	10.1016/j.ogla.2023.05.006
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Article ; Online: Contamination of surfaces in children's homes with nicotine and the potent carcinogenic tobacco-specific nitrosamine NNK.

Merianos, Ashley L / Matt, Georg E / Stone, Timothy M / Jandarov, Roman A / Hoh, Eunha / Dodder, Nathan G / Quintana, Penelope J E / Lopez-Galvez, Nicolas / Stone, Lara / Mahabee-Gittens, E Melinda

Journal of exposure science & environmental epidemiology

2023

Abstract: Background: Tobacco smoke exposure (TSE) through secondhand and thirdhand smoke is a modifiable risk factor that contributes to childhood morbidity. Limited research has assessed surface TSE pollution in children's environments as a potential source of ... ...

Abstract	Background: Tobacco smoke exposure (TSE) through secondhand and thirdhand smoke is a modifiable risk factor that contributes to childhood morbidity. Limited research has assessed surface TSE pollution in children's environments as a potential source of thirdhand smoke exposure, and none have examined levels of the tobacco-specific nitrosamine 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK) on surfaces. Objective: This study measured surface NNK and nicotine in children's homes and associations with sociodemographics and parent-reported TSE behaviors. We assessed correlations of surface NNK and nicotine with dust NNK, dust nicotine, and child cotinine. Methods: Home surface wipe NNK and nicotine data from 84 children who lived with smokers were analyzed. Tobit and simple linear regression analyses were conducted to assess associations of surface NNK and nicotine with child characteristics. Spearman's (ρ) correlations assessed the strength of associations between environmental markers and child cotinine. Results: Nearly half (48.8%) of children's home surfaces had detectable NNK and 100% had detectable nicotine. The respective geometric means (GMs) of surface NNK and nicotine loadings were 14.0 ng/m Impact: Although nicotine on surfaces is an established marker of thirdhand smoke pollution, other thirdhand smoke contaminants have not been measured on surfaces in the homes of children living with smokers. We provide evidence that the potent carcinogenic tobacco-specific nitrosamine NNK was detectable on surfaces in nearly half of children's homes, and nicotine was detectable on all surfaces. Surface NNK was positively correlated with surface nicotine and dust NNK. Detectable surface NNK levels were found in homes with indoor smoking bans, indicating the role of NNK as a persistent thirdhand smoke pollutant accumulating on surfaces as well as in dust.
Language	English
Publishing date	2023-12-16
Publishing country	United States
Document type	Journal Article
ZDB-ID	2218551-3
ISSN	1559-064X ; 1559-0631
ISSN (online)	1559-064X
ISSN	1559-0631
DOI	10.1038/s41370-023-00629-8
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Article: DNA Capture and Enrichment: A Culture-Independent Approach for Characterizing the Genomic Diversity of Pathogenic

Stone, Nathan E / McDonough, Ryelan F / Hamond, Camila / LeCount, Karen / Busch, Joseph D / Dirsmith, Katherine L / Rivera-Garcia, Sarai / Soltero, Fred / Arnold, Laura M / Weiner, Zachary / Galloway, Renee L / Schlater, Linda K / Nally, Jarlath E / Sahl, Jason W / Wagner, David M

Microorganisms

2023 Volume 11, Issue 5

Abstract: Because they are difficult to culture, obtaining genomic information ... ...

Abstract	Because they are difficult to culture, obtaining genomic information from
Language	English
Publishing date	2023-05-14
Publishing country	Switzerland
Document type	Journal Article
ZDB-ID	2720891-6
ISSN	2076-2607
ISSN	2076-2607
DOI	10.3390/microorganisms11051282
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Article ; Online: Complete Genome Sequence of Peptacetobacter (Clostridium) hiranonis Strain DGF055142, Isolated from Dog Feces from Flagstaff, Arizona, USA, 2019.

Stone, Nathan E / Nunnally, Amalee E / Roe, Chandler C / Hornstra, Heidie M / Wagner, David M / Sahl, Jason W

Microbiology resource announcements

2021 Volume 10, Issue 9

Abstract: A single-chromosome closed genome ... ...

Abstract	A single-chromosome closed genome of
Language	English
Publishing date	2021-03-04
Publishing country	United States
Document type	Journal Article
ISSN	2576-098X
ISSN (online)	2576-098X
DOI	10.1128/MRA.00067-21
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Article ; Online: A local-scale One Health genomic surveillance of

Williamson, Charles H D / Roe, Chandler C / Terriquez, Joel / Hornstra, Heidie / Lucero, Samantha / Nunnally, Amalee E / Vazquez, Adam J / Vinocur, Jacob / Plude, Carmel / Nienstadt, Linus / Stone, Nathan E / Celona, Kimberly R / Wagner, David M / Keim, Paul / Sahl, Jason W

Microbial genomics

2023 Volume 9, Issue 6

Abstract: Although infections caused ... ...

Abstract	Although infections caused by
MeSH term(s)	Humans ; Animals ; Dogs ; Clostridioides difficile ; Bacterial Toxins/genetics ; Clostridioides ; One Health ; Clostridium Infections/epidemiology ; Clostridium Infections/veterinary ; Genomics
Chemical Substances	trimethylaminocarboxyldihydroboran ; Bacterial Toxins
Language	English
Publishing date	2023-06-22
Publishing country	England
Document type	Journal Article
ZDB-ID	2835258-0
ISSN	2057-5858 ; 2057-5858
ISSN (online)	2057-5858
ISSN	2057-5858
DOI	10.1099/mgen.0.001046
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Article: Bovine Leptospirosis Due to Persistent Renal Carriage of

Hamond, Camila / LeCount, Karen / Putz, Ellie J / Bayles, Darrell O / Camp, Patrick / Goris, Marga G A / van der Linden, Hans / Stone, Nathan E / Schlater, Linda K / Sahl, Jason W / Wagner, David M / Nally, Jarlath E

Frontiers in veterinary science

2022 Volume 9, Page(s) 848664

Abstract: Leptospirosis is a global zoonotic disease that causes significant morbidity and mortality in human and animal populations. ...

Abstract	Leptospirosis is a global zoonotic disease that causes significant morbidity and mortality in human and animal populations.
Language	English
Publishing date	2022-04-05
Publishing country	Switzerland
Document type	Journal Article
ZDB-ID	2834243-4
ISSN	2297-1769
ISSN	2297-1769
DOI	10.3389/fvets.2022.848664
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Article ; Online: Changes and stability of hand nicotine levels in children of smokers: Associations with urinary biomarkers, reported child tobacco smoke exposure, and home smoking bans.

Matt, Georg E / Merianos, Ashley L / Stone, Lara / Wullenweber, Chase / Quintana, Penelope J E / Hoh, Eunha / Dodder, Nathan G / Lopez Galvez, Nicolas / Mahabee-Gittens, E Melinda

Environment international

2023 Volume 181, Page(s) 108239

Abstract: Background: Exposure to thirdhand smoke (THS) residue takes place through inhalation, ingestion, and dermal transfer. Hand nicotine levels have been proposed to measure THS pollution in the environment of children, but little is known about its ... ...

Abstract	Background: Exposure to thirdhand smoke (THS) residue takes place through inhalation, ingestion, and dermal transfer. Hand nicotine levels have been proposed to measure THS pollution in the environment of children, but little is known about its variability and stability over time and correlates of change. Objectives: The goal was to determine the stability of hand nicotine in comparison to urinary biomarkers and to explore factors that influence changes in hand nicotine. Methods: Data were collected from 0 to 11-year-old children (Mean age = 5.9) who lived with ≥1 tobacco smokers (N = 129). At a 6-week interval, we collected repeated measures of hand nicotine, four urinary biomarkers (cotinine, trans-3'-hydroxycotinine, nicotelline N-oxides, and 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol), and parent-reported child tobacco smoke exposure (TSE). Dependent sample t-tests, correlations, and multivariable regression analyses were conducted to examine the changes in child TSE. Results: Hand nicotine levels (r = 0.63, p < 0.001) showed similar correlations between repeated measures to urinary biomarkers (r = 0.58-0.71; p < 0.001). Different from urinary biomarkers, mean hand nicotine levels increased over time (t(113) = 3.37, p < 0.001) being significantly higher in children from homes without smoking bans at Time 2 (p = 0.016) compared to Time 1 (p = 0.003). Changes in hand nicotine correlated with changes in cotinine and trans-3'-hydroxycotinine (r = 0.30 and r = 0.19, respectively, p < 0.05). Children with home smoking bans at Time 1 and 2 showed significantly lower hand nicotine levels compared to children without home smoking bans. Discussion: Findings indicate that hand nicotine levels provide additional insights into children's exposure to tobacco smoke pollutants than reported child TSE and urinary biomarkers. Changes in hand nicotine levels show that consistent home smoking bans in homes of children of smokers can lower THS exposure. Hand nicotine levels may be influenced by the environmental settings in which they are collected.
MeSH term(s)	Humans ; Child ; Child, Preschool ; Infant, Newborn ; Infant ; Nicotine/analysis ; Cotinine/analysis ; Tobacco Smoke Pollution/adverse effects ; Tobacco Smoke Pollution/analysis ; Smokers ; Smoke-Free Policy ; Biomarkers
Chemical Substances	Nicotine (6M3C89ZY6R) ; Cotinine (K5161X06LL) ; Tobacco Smoke Pollution ; Biomarkers
Language	English
Publishing date	2023-09-27
Publishing country	Netherlands
Document type	Journal Article
ZDB-ID	554791-x
ISSN	1873-6750 ; 0160-4120
ISSN (online)	1873-6750
ISSN	0160-4120
DOI	10.1016/j.envint.2023.108239
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