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  1. Article ; Online: Divergent Fe-Mediated C-H Activation Paths Driven by Alkali Cations.

    Wowk, Vincent / Bauer, Alexis K / Radovic, Aleksa / Chamoreau, Lise-Marie / Neidig, Michael L / Lefèvre, Guillaume

    JACS Au

    2024  Volume 4, Issue 2, Page(s) 512–524

    Abstract: The association of the ferrous complex ... ...

    Abstract The association of the ferrous complex Fe
    Language English
    Publishing date 2024-01-19
    Publishing country United States
    Document type Journal Article
    ISSN 2691-3704
    ISSN (online) 2691-3704
    DOI 10.1021/jacsau.3c00649
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Additive and Counterion Effects in Iron-Catalyzed Reactions Relevant to C-C Bond Formation.

    Bakas, Nikki J / Neidig, Michael L

    ACS catalysis

    2021  Volume 11, Issue 14, Page(s) 8493–8503

    Abstract: The use of iron catalysts in carbon-carbon bond forming reactions is of interest as an alternative to precious metal catalysts, offering reduced cost, lower toxicity, and different reactivity. While well-defined ligands such ... ...

    Abstract The use of iron catalysts in carbon-carbon bond forming reactions is of interest as an alternative to precious metal catalysts, offering reduced cost, lower toxicity, and different reactivity. While well-defined ligands such as
    Language English
    Publishing date 2021-06-29
    Publishing country United States
    Document type Journal Article
    ISSN 2155-5435
    ISSN 2155-5435
    DOI 10.1021/acscatal.1c00928
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Forged in iron.

    Neate, Peter G N / Neidig, Michael L

    Nature reviews. Chemistry

    2021  Volume 5, Issue 4, Page(s) 223–224

    Language English
    Publishing date 2021-02-19
    Publishing country England
    Document type Journal Article
    ISSN 2397-3358
    ISSN (online) 2397-3358
    DOI 10.1038/s41570-021-00259-4
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts.

    Bakas, Nikki J / Chourreu, Pablo / Gayon, Eric / Lefèvre, Guillaume / Neidig, Michael L

    Chemical communications (Cambridge, England)

    2023  Volume 59, Issue 10, Page(s) 1317–1320

    Abstract: The molecular-level role of alkoxide salts, used as alternative additive ... ...

    Abstract The molecular-level role of alkoxide salts, used as alternative additive to
    Language English
    Publishing date 2023-01-31
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc06257g
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article: Mechanistic Studies of Iron-PyBOX-Catalyzed Olefin Amino-Oxygenation with Functionalized Hydroxylamines.

    Radović, Aleksa / Wolford, Nikki J / Li, Hongze / Brennessel, William W / Xu, Hao / Neidig, Michael L

    Organometallics

    2023  Volume 42, Issue 14, Page(s) 1810–1817

    Abstract: Iron-catalyzed amino-oxygenation of olefins often uses discrete ligands to increase reactivity and broaden substrate scope. This work is focused on examining ligand effects on reactivity and in situ iron speciation in a system which utilizes a ... ...

    Abstract Iron-catalyzed amino-oxygenation of olefins often uses discrete ligands to increase reactivity and broaden substrate scope. This work is focused on examining ligand effects on reactivity and in situ iron speciation in a system which utilizes a bisoxazoline ligand. Freeze-trapped
    Language English
    Publishing date 2023-04-28
    Publishing country United States
    Document type Journal Article
    ZDB-ID 2006302-7
    ISSN 1520-6041 ; 0276-7333
    ISSN (online) 1520-6041
    ISSN 0276-7333
    DOI 10.1021/acs.organomet.3c00067
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Intermediates and mechanism in iron-catalyzed C-H methylation with trimethylaluminum.

    Bhatia, Shilpa / DeMuth, Joshua C / Neidig, Michael L

    Chemical communications (Cambridge, England)

    2021  Volume 57, Issue 95, Page(s) 12784–12787

    Abstract: A mechanistic study is performed on the reaction method for iron-catalyzed C-H methylation with ... ...

    Abstract A mechanistic study is performed on the reaction method for iron-catalyzed C-H methylation with AlMe
    Language English
    Publishing date 2021-11-30
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d1cc05607g
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Anion-induced disproportionation of Th(III) complexes to form Th(II) and Th(IV) products.

    Wedal, Justin C / Cajiao, Nathalia / Neidig, Michael L / Evans, William J

    Chemical communications (Cambridge, England)

    2022  Volume 58, Issue 34, Page(s) 5289–5291

    Abstract: A new synthesis of Th(II) complexes has been identified involving addition of simple MX salts (M = Li, Na, K; X = H, Cl, Me, ... ...

    Abstract A new synthesis of Th(II) complexes has been identified involving addition of simple MX salts (M = Li, Na, K; X = H, Cl, Me, N
    Language English
    Publishing date 2022-04-26
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc01272c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: A TMEDA-Iron Adduct Reaction Manifold in Iron-Catalyzed C(sp

    Bakas, Nikki J / Sears, Jeffrey D / Brennessel, William W / Neidig, Michael L

    Angewandte Chemie (International ed. in English)

    2022  Volume 61, Issue 15, Page(s) e202114986

    Abstract: Herein, we expand the current molecular-level understanding of one of the most important and effective additives in iron-catalyzed cross-coupling reactions, N,N,N',N'-tetramethylethylenediamine (TMEDA). Focusing on relevant phenyl and ethyl Grignard ... ...

    Abstract Herein, we expand the current molecular-level understanding of one of the most important and effective additives in iron-catalyzed cross-coupling reactions, N,N,N',N'-tetramethylethylenediamine (TMEDA). Focusing on relevant phenyl and ethyl Grignard reagents and slow nucleophile addition protocols commonly used in effective catalytic systems, TMEDA-iron(II)-aryl intermediates are identified via in situ spectroscopy, X-ray crystallography, and detailed reaction studies to be a part of an iron(II)/(III)/(I) reaction cycle where radical recombination with FePhBr(TMEDA) (2
    Language English
    Publishing date 2022-02-18
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.202114986
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: C-Term magnetic circular dichroism (MCD) spectroscopy in paramagnetic transition metal and f-element organometallic chemistry.

    Wolford, Nikki J / Radovic, Aleksa / Neidig, Michael L

    Dalton transactions (Cambridge, England : 2003)

    2020  Volume 50, Issue 2, Page(s) 416–428

    Abstract: Magnetic circular dichroism (MCD) spectroscopy is a powerful experiment used to probe the electronic structure and bonding in paramagnetic metal-based complexes. While C-term MCD spectroscopy has been utilized in many areas of chemistry, it has been ... ...

    Abstract Magnetic circular dichroism (MCD) spectroscopy is a powerful experiment used to probe the electronic structure and bonding in paramagnetic metal-based complexes. While C-term MCD spectroscopy has been utilized in many areas of chemistry, it has been underutilized in studying paramagnetic organometallic transition metal and f-element complexes. From the analysis of isolated organometallic complexes to the study of in situ generated species, MCD can provide information regarding ligand interactions, oxidation and spin state, and geometry and coordination environment of paramagnetic species. The pratical aspects of this technique, such as air-free sample preparation and cryogenic experimental temperatures, allow for the study of highly unstable species, something that is often difficult with other spectroscopic techniques. This perspective highlights MCD studies of both transition metal and f-element organometallic complexes, including in situ generated reactive intermediates, to demonstrate the utility of this technique in probing electronic structure, bonding and mechanism in paramagnetic organometallic chemistry.
    Language English
    Publishing date 2020-12-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d0dt03730c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Academia or Industry: Lessons on Choosing Career Paths─There May Be More Than One Fork in the Road Ahead.

    Blackmond, Donna G / Emmert, Marion / Huryn, Donna M / Neidig, Michael L / Schaub, Thomas / Topczewski, Joseph J / Bravo-Altamirano, Karla / Buchan, Zachary / Cabrera, Pablo J

    Organic letters

    2024  Volume 26, Issue 14, Page(s) 2682–2685

    MeSH term(s) Academia ; Industry
    Language English
    Publishing date 2024-03-04
    Publishing country United States
    Document type Editorial
    ISSN 1523-7052
    ISSN (online) 1523-7052
    DOI 10.1021/acs.orglett.4c01099
    Database MEDical Literature Analysis and Retrieval System OnLINE

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