Article: Über Komplexe des Typs {(PhC=C)3P}3M(CO)3 (M = Cr, Mo, W) / On Complexes of the Type {(PhC=C)3P}3M(CO)3 (M = Cr, Mo, W)
Zeitschrift für Naturforschung. 2014 June 2, v. 56, no. 1
2014
Abstract: The tris(alkinyl)phosphine complexes {(PhC=C)₃P}₃M(CO)₃, M = Cr (3a), Mo (3b), W (3c), are obtained ... from P(C=CPh)₃ and (C₆H₁₅N₃)M(CO)₃ (C₆H₁₅N₃ = 1,3,5-trimethyl-1,3,5-triazacyclohexane) as stable yellow ...
| Abstract | The tris(alkinyl)phosphine complexes {(PhC=C)₃P}₃M(CO)₃, M = Cr (3a), Mo (3b), W (3c), are obtained from P(C=CPh)₃ and (C₆H₁₅N₃)M(CO)₃ (C₆H₁₅N₃ = 1,3,5-trimethyl-1,3,5-triazacyclohexane) as stable yellow solids in good yields. While IR data indicate significant acceptor properties of the phosphane ligands, the X-ray structure analysis of 3c also allows the discussion of weak donor interactions. |
|---|---|
| Keywords | X-radiation ; chromium ; ligands ; molybdenum ; phosphine |
| Language | English |
| Dates of publication | 2014-0602 |
| Size | p. 95-99. |
| Publishing place | Verlag der Zeitschrift für Naturforschung |
| Document type | Article |
| ZDB-ID | 124635-5 |
| ISSN | 0340-5087 ; 0044-3174 ; 0932-0776 ; 0341-0447 ; 0341-0420 |
| ISSN | 0340-5087 ; 0044-3174 ; 0932-0776 ; 0341-0447 ; 0341-0420 |
| DOI | 10.1515/znb-2001-0116 |
| Database | NAL-Catalogue (AGRICOLA) |
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