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  1. Article ; Online: Resonance Raman Spectra of [M(6)X(8)Y(6)](2)(-) Cluster Complexes (M = Mo, W; X, Y = Cl, Br, I).

    Schoonover, Jon R. / Zietlow, Thomas C. / Clark, David L. / Heppert, Joseph A. / Chisholm, Malcolm H. / Gray, Harry B. / Sattelberger, Alfred P. / Woodruff, William H.

    Inorganic chemistry

    1996  Volume 35, Issue 22, Page(s) 6606–6613

    Abstract: ... 2)(-) (M = Mo or W; X, Y = Cl, Br, or I) are reported. The three totally symmetric fundamental ... Resonance Raman spectra of the cubic metal-halide complexes having the general formula [M(6)X(8)Y(6 ...

    Abstract Resonance Raman spectra of the cubic metal-halide complexes having the general formula [M(6)X(8)Y(6)](2)(-) (M = Mo or W; X, Y = Cl, Br, or I) are reported. The three totally symmetric fundamental vibrations of these complexes are identified. The extensive mixing of the symmetry coordinates that compose the symmetric normal modes expected in these systems is not observed. Instead the "group-frequency" approximation is valid. Furthermore, the force constants of both the apical and face-bridging metal-halide bonds are insensitive to the identity of either the metal or the halide. Raman spectra of related complexes with methoxy and benzenethiol groups as ligands are reported along with the structural data for [Mo(6)Cl(8)(SPh)(6)][NBu(4)](2). Crystal data for [Mo(6)Cl(8)(SPh)(6)][NBu(4)](2) at -156 degrees C: monoclinic space group P2(1)/c; a = 12.588(3), b = 17.471(5), c = 20.646(2) Å; beta = 118.53(1) degrees, V = 3223.4 Å(3); d(calcd) = 1.664 g cm(-)(3); Z = 2.
    Language English
    Publishing date 1996-10-23
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/ic960184b
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  2. Article ; Online: Making narrative feedback meaningful.

    Hall, Alan M / Gray, Adam / Ragsdale, John W

    The clinical teacher

    2024  , Page(s) e13766

    Abstract: Background: Narrative written feedback given to students by faculty often fails to identify areas for improvement and recommended actions to lead to this improvement. When these elements are missing, it is challenging for students to improve and for ... ...

    Abstract Background: Narrative written feedback given to students by faculty often fails to identify areas for improvement and recommended actions to lead to this improvement. When these elements are missing, it is challenging for students to improve and for medical schools to use narrative feedback in promotion decisions, to guide coaching plans and to pass on meaningful information to residency programs. Large-group faculty development has improved narrative written feedback, but less is known about individualised faculty development to supplement large-group sessions. To fill this gap, we built a curriculum with general and individualised faculty development to improve narrative written feedback from Internal Medicine faculty to clerkship students.
    Approach: We used Kern's steps to build a curriculum with general and individualised one-on-one faculty development to improve the problem of inadequate narrative written feedback. We used a novel narrative feedback rubric for pre and post-intervention faculty scores.
    Results/findings/evaluation: Through general and individualised one-on-one faculty development with peer comparison scores, we were able to improve narrative written feedback from 3.7/6 to 4.6/6, for an increase of 23%.
    Implications: We found our faculty development program effective in improving feedback and was easy to implement. Our rubric was easy to use, and faculty were receptive to feedback in one-on-one meetings. We plan to extend this work locally to other divisions/departments and into graduate medical education; it should also be easily extended to other medical disciplines or health professions.
    Language English
    Publishing date 2024-04-23
    Publishing country England
    Document type Journal Article
    ZDB-ID 2151518-9
    ISSN 1743-498X ; 1743-4971
    ISSN (online) 1743-498X
    ISSN 1743-4971
    DOI 10.1111/tct.13766
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  3. Article ; Online: Broken silicone earplugs: removal success using a small camera in a deployed environment.

    Hammond, William Todd / Gray, M W

    BMJ military health

    2022  

    Language English
    Publishing date 2022-11-25
    Publishing country England
    Document type Journal Article
    ZDB-ID 3011686-7
    ISSN 2633-3775 ; 2633-3767
    ISSN (online) 2633-3775
    ISSN 2633-3767
    DOI 10.1136/military-2022-002251
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  4. Book ; Online: Food and agribusiness in 2030

    Gray, Allan W. / Rodrigues, Jonny Mateus / Kalaki, Rafael Bordonal / Neves, Marcos Fava

    a roadmap

    2020  

    Author's details Marcos Fava Neves (coordinator) ; Allan W. Gray, Falvio Runkhe Valerio, Leticia Franco Martinez, Jonny Mateus Rodrigues, Rafael Bordonal Kalaki, Vitor Nardini Marques, Vinícius Cambaúva
    Language English
    Size 1 Online-Ressource (124 Seiten)
    Publisher Wageningen Academic Publishers
    Publishing place Wageningen
    Publishing country Netherlands
    Document type Book ; Online
    HBZ-ID HT020668850
    ISBN 978-90-8686-907-7 ; 9789086863549 ; 90-8686-907-6 ; 908686354X
    Database ZB MED Catalogue: Medicine, Health, Nutrition, Environment, Agriculture

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  5. Article ; Online: Discovery of Carbohydrate Sulfotransferase Inhibitors from a Kinase-Directed Library We thank Sharon Long and Dave Keating for providing both the NodH sulfotransferase and APS Kinase during our preliminary experiments and Jack Kirsch for numerous helpful conversations. J.I.A. and K.G.B were supported by NIH Molecular Biophysics Training Grant (No. T32GM0895). This research was funded by grants to C.R.B. from the Pew Scholars Program, the W. M. Keck Foundation and the American Cancer Society (Grant No. RPG9700501BE).

    Armstrong / Portley / Chang / Nierengarten / Cook / Bowman / Bishop / Gray / Shokat / Schultz / Bertozzi

    Angewandte Chemie (International ed. in English)

    2000  Volume 39, Issue 7, Page(s) 1303–1306

    Language English
    Publishing date 2000-04
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/(sici)1521-3773(20000403)39:7<1303::aid-anie1303>3.0.co;2-0
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  6. Article ; Online: Factors associated with conversion from day-case to in-patient elective inguinal hernia repair surgery across England: an observational study using administrative data.

    Joyner, J / Ayyaz, F M / Cheetham, M / Briggs, T W R / Gray, W K

    Hernia : the journal of hernias and abdominal wall surgery

    2024  Volume 28, Issue 2, Page(s) 555–565

    Abstract: Purpose: Elective primary inguinal hernia repair surgery is increasingly being conducted as a day-case procedure. However, some patients planned for day-case surgery have to stay in hospital for at least one night. The aim of this study was to identify ... ...

    Abstract Purpose: Elective primary inguinal hernia repair surgery is increasingly being conducted as a day-case procedure. However, some patients planned for day-case surgery have to stay in hospital for at least one night. The aim of this study was to identify the factors associated with conversion from day-case to in-patient management for elective inguinal hernia repair surgery.
    Methods: This was an exploratory retrospective analysis of observational data from the Hospital Episode Statistics dataset for England. All patients aged ≥ 17 years undergoing a first elective inguinal hernia repair between 1st April 2014 and 31st March 2022 that was planned as day-case surgery were identified. The exposure of interest was discharged on the day of admission (day-case) or requiring overnight stay. The primary outcome of interest was 30-day emergency readmission with an overnight stay. For reporting, providers were aggregated to an Integrated Care Board (ICB) level.
    Results: A total of 351,528 planned day-case elective primary inguinal hernia repairs were identified over the eight-year study period. Of these, 45,305 (12.9%) stayed in hospital for at least one night and were classed as day-case to in-patient stay conversions. Patients who converted to in-patient stay were older, had more comorbidities, and were more likely to have bilateral surgery and be operated on by a low-annual volume surgeon. Post-procedural complications were strongly associated with conversion. Across the 42 ICBs in England, model-adjusted conversion rates varied from 3.3% to 21.3%.
    Conclusions: There was considerable variation in conversion to in-patient stay rates for inguinal hernia repair across ICBs in England. Our findings should help surgical teams to better identify patients suitable for day-case inguinal hernia repair and plan discharge services more effectively. This should help to reduce the variation in conversion rates.
    MeSH term(s) Humans ; Hernia, Inguinal/surgery ; Retrospective Studies ; Herniorrhaphy/methods ; Elective Surgical Procedures ; England
    Language English
    Publishing date 2024-02-12
    Publishing country France
    Document type Observational Study ; Journal Article
    ZDB-ID 1388125-5
    ISSN 1248-9204 ; 1265-4906
    ISSN (online) 1248-9204
    ISSN 1265-4906
    DOI 10.1007/s10029-023-02949-y
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    Zs.A 5390: Show issues Location:
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  7. Article ; Online: Association of day-case rates with post COVID-19 recovery of elective laparoscopic cholecystectomy activity across England.

    Ayyaz, F M / Joyner, J / Cheetham, M / Briggs, Twr / Gray, W K

    Annals of the Royal College of Surgeons of England

    2024  

    Abstract: Introduction: The aim of this study was to investigate the safety of day-case laparoscopic cholecystectomy, and the association between day-case rates and, post the COVID-19 pandemic, recovery of activity to prepandemic levels for integrated care boards ...

    Abstract Introduction: The aim of this study was to investigate the safety of day-case laparoscopic cholecystectomy, and the association between day-case rates and, post the COVID-19 pandemic, recovery of activity to prepandemic levels for integrated care boards (ICBs) in England.
    Methods: This was a retrospective observational study of the Hospital Episodes Statistics (HES) data set. Elective laparoscopic cholecystectomies for the period 1 January 2019 to 31 December 2022 were identified. Activity levels for 2022 were compared with those for the whole of 2019 (baseline). Day-case activity was identified where the length of stay recorded in the HES was zero days.
    Results: Data were available for 184,252 patients across the 42 ICBs in England, of which 120,408 (65.3%) were day-case procedures. By December 2022, activity levels for the whole of England had returned to 88.2% of prepandemic levels. The South West region stood out as having recovered activity levels to the greatest extent, with activity at 97.3% of prepandemic levels during 2022. The South West also had the highest postpandemic day-case rate at 74.9% of all patients seen as a day-case during 2022; this compares with an England average of 65.3%. At an ICB level, there was a significant correlation between day-case rates and postpandemic activity levels (
    Conclusions: Recovery of elective laparoscopic cholecystectomy activity has been better in South West England than in other regions. Increasing day-case rates may be important if ICBs in other regions are to increase activity levels up to and beyond prepandemic levels.
    Language English
    Publishing date 2024-04-02
    Publishing country England
    Document type Journal Article
    ZDB-ID 80044-2
    ISSN 1478-7083 ; 0035-8843
    ISSN (online) 1478-7083
    ISSN 0035-8843
    DOI 10.1308/rcsann.2023.0111
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  8. Article ; Online: Emergency Department Use Disparities Among Transgender and Cisgender Medicare Beneficiaries, 2011-2020.

    Babbs, Gray / Hughto, Jaclyn M W / Shireman, Theresa I / Meyers, David J

    JAMA internal medicine

    2024  Volume 184, Issue 4, Page(s) 443–445

    MeSH term(s) Aged ; Humans ; United States ; Transgender Persons ; Medicare ; Emergency Service, Hospital ; Emergency Medical Services
    Language English
    Publishing date 2024-02-12
    Publishing country United States
    Document type Journal Article ; Comment
    ZDB-ID 2699338-7
    ISSN 2168-6114 ; 2168-6106
    ISSN (online) 2168-6114
    ISSN 2168-6106
    DOI 10.1001/jamainternmed.2023.8209
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  9. Article: Recommended practices for virtual nutrition education interventions for adolescents with autism spectrum disorder: A reflection from two pilot interventions during the COVID-19 pandemic.

    Buro, Acadia W / Shurack, Riley H / Garcia, Jeanette M / Gray, Heewon L

    Nutrition and health

    2023  Volume 30, Issue 1, Page(s) 15–19

    Abstract: Youth with autism spectrum disorder (ASD) demonstrate unhealthy eating behaviors and dietary patterns compared to their neurotypical counterparts. Given the increased risk of unhealthy weight gain and the onset of the COVID-19 pandemic, modified ... ...

    Abstract Youth with autism spectrum disorder (ASD) demonstrate unhealthy eating behaviors and dietary patterns compared to their neurotypical counterparts. Given the increased risk of unhealthy weight gain and the onset of the COVID-19 pandemic, modified nutrition programs in this population are warranted. The authors independently conducted two virtual pilot interventions during COVID-19 that offered feasible and acceptable alternatives to in-person delivery, providing unique opportunities for participant engagement and family involvement. Future virtual nutrition education programs for adolescents with ASD may include visual and verbal aids through Zoom, more parent/family integration, and accommodations for those with varying ASD severity levels.
    MeSH term(s) Humans ; Adolescent ; Autism Spectrum Disorder/therapy ; Pilot Projects ; Pandemics/prevention & control ; COVID-19 ; Parents
    Language English
    Publishing date 2023-01-24
    Publishing country England
    Document type Journal Article
    ZDB-ID 603215-1
    ISSN 2047-945X ; 0260-1060
    ISSN (online) 2047-945X
    ISSN 0260-1060
    DOI 10.1177/02601060231151985
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  10. Article: Vaccine Treatment in Surgery.

    Gray, H M W

    Transactions. Medico-Chirurgical Society of Edinburgh

    2018  Volume 25, Page(s) 182–199

    Language English
    Publishing date 2018-03-19
    Publishing country Scotland
    Document type Journal Article
    ISSN 0267-2790
    ISSN 0267-2790
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