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Article ; Online: Effects of vitamin K

Xu, Wencheng / Wu, Hongguang / Tahara, Koichiro / Chen, Shuhe / Wang, Xiaoqin / Tanaka, Sachiko / Sugiyama, Kentaro / Sawada, Tetsuji / Hirano, Toshihiko

Fundamental & clinical pharmacology

2021 Volume 35, Issue 5, Page(s) 832–842

Abstract: ... rheumatoid arthritis (RA). Vitamin K: Objectives: Immunosuppressive pharmacodynamics of vitamin K ... immunosuppressive pharmacodynamics of drugs in vitro.: Results: Vitamin K: Conclusion: The above information ... may partially elucidate the potentiation effects of vitamin K ...

Abstract	Background: Methotrexate (MTX) is used as anchor drug for patients with early and established rheumatoid arthritis (RA). Vitamin K Objectives: Immunosuppressive pharmacodynamics of vitamin K Methods: Mitogen-activated peripheral blood mononuclear cells (PBMCs) were used to evaluate immunosuppressive pharmacodynamics of drugs in vitro. Results: Vitamin K Conclusion: The above information may partially elucidate the potentiation effects of vitamin K
MeSH term(s)	Adult ; Aged ; Aged, 80 and over ; Antirheumatic Agents/administration & dosage ; Antirheumatic Agents/pharmacology ; Antirheumatic Agents/therapeutic use ; Arthritis, Rheumatoid/drug therapy ; Arthritis, Rheumatoid/metabolism ; Drug Therapy, Combination ; Female ; Healthy Volunteers ; Humans ; Inhibitory Concentration 50 ; Leukocytes, Mononuclear/drug effects ; Male ; Methotrexate/administration & dosage ; Methotrexate/pharmacology ; Methotrexate/therapeutic use ; Middle Aged ; Vitamin K 2/administration & dosage ; Vitamin K 2/pharmacology ; Vitamin K 2/therapeutic use ; Young Adult
Chemical Substances	Antirheumatic Agents ; Vitamin K 2 (11032-49-8) ; Methotrexate (YL5FZ2Y5U1)
Language	English
Publishing date	2021-04-11
Publishing country	England
Document type	Journal Article
ZDB-ID	639134-5
ISSN	1472-8206 ; 0767-3981
ISSN (online)	1472-8206
ISSN	0767-3981
DOI	10.1111/fcp.12676
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Article ; Online: Vitamin K

Xu, Wencheng / Meng, Kehan / Wu, Hongguang / Miura, Taro / Suzuki, Shunsuke / Chiyotanda, Masako / Tanaka, Sachiko / Sugiyama, Kentaro / Kawashima, Hisashi / Hirano, Toshihiko

Pediatrics international : official journal of the Japan Pediatric Society

2019 Volume 61, Issue 12, Page(s) 1188–1195

Abstract: ... The purpose of this study was to explore whether vitamin K: Methods: The immunosuppressive efficacy ... of vitamin K: Results: The mean (SD) IC: Conclusion: Vitamin K ...

Abstract	Background: Over 20 kinds of steroids, tacrolimus ointments, and cyclosporine capsules are usually recommended for the treatment of atopic dermatitis (AD), depending on the symptoms of patients. However, several side effects sometimes occur with the extensive use of these agents for the treatment of pediatric AD patients. The purpose of this study was to explore whether vitamin K Methods: The immunosuppressive efficacy of vitamin K Results: The mean (SD) IC Conclusion: Vitamin K
MeSH term(s)	Adult ; Cell Proliferation/drug effects ; Cells, Cultured ; Child ; Child, Preschool ; Cyclosporine/pharmacology ; Dermatitis, Atopic/drug therapy ; Female ; Healthy Volunteers ; Humans ; Immunosuppressive Agents/administration & dosage ; Immunosuppressive Agents/pharmacology ; Leukocytes, Mononuclear/drug effects ; Male ; Methylprednisolone/pharmacology ; Tacrolimus/pharmacology ; Vitamin K 2/administration & dosage ; Vitamin K 2/pharmacology ; Vitamin K 2/therapeutic use
Chemical Substances	Immunosuppressive Agents ; Vitamin K 2 (11032-49-8) ; Cyclosporine (83HN0GTJ6D) ; Tacrolimus (WM0HAQ4WNM) ; Methylprednisolone (X4W7ZR7023)
Language	English
Publishing date	2019-12-13
Publishing country	Australia
Document type	Journal Article
ZDB-ID	1470376-2
ISSN	1442-200X ; 1328-8067
ISSN (online)	1442-200X
ISSN	1328-8067
DOI	10.1111/ped.14014
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Article ; Online: Nutritional Therapy with Vitamin K

Kuwabara, Akiko / Nagae, Akiko / Kitagawa, Mari / Tozawa, Kunihiko / Kumode, Masao / Tanaka, Kiyoshi

Journal of nutritional science and vitaminology

2020 Volume 66, Issue 3, Page(s) 278–284

Abstract: ... have a high prevalence of vitamin K deficiency both in the liver and bone. Thus, vitamin K therapy ... of nutritional therapy with vitamin K ...

Abstract	We have previously reported that patients with severe motor and intellectual disabilities (SMID) have a high prevalence of vitamin K deficiency both in the liver and bone. Thus, vitamin K therapy for SMID patients should be considered. In the present study, we have studied the efficacy of nutritional therapy with vitamin K
MeSH term(s)	Adult ; Alkaline Phosphatase/blood ; Biomarkers/blood ; Bone Remodeling ; Bone and Bones/metabolism ; Disabled Persons ; Female ; Humans ; Intellectual Disability/blood ; Intellectual Disability/complications ; Middle Aged ; Motor Disorders/blood ; Motor Disorders/complications ; Nutrition Therapy ; Nutritional Requirements ; Nutritional Status ; Osteocalcin/blood ; Protein Precursors/blood ; Prothrombin ; Severity of Illness Index ; Tartrate-Resistant Acid Phosphatase/blood ; Treatment Outcome ; Vitamin K 1/blood ; Vitamin K 1/therapeutic use ; Vitamin K Deficiency/blood ; Vitamin K Deficiency/drug therapy ; Vitamin K Deficiency/etiology ; Young Adult
Chemical Substances	Biomarkers ; Protein Precursors ; Osteocalcin (104982-03-8) ; acarboxyprothrombin (53230-14-1) ; Vitamin K 1 (84-80-0) ; Prothrombin (9001-26-7) ; Alkaline Phosphatase (EC 3.1.3.1) ; ACP5 protein, human (EC 3.1.3.2) ; Tartrate-Resistant Acid Phosphatase (EC 3.1.3.2)
Language	English
Publishing date	2020-06-24
Publishing country	Japan
Document type	Clinical Trial ; Journal Article
ZDB-ID	191366-9
ISSN	1881-7742 ; 0301-4800
ISSN (online)	1881-7742
ISSN	0301-4800
DOI	10.3177/jnsv.66.278
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Article ; Online: Ppp6c deficiency accelerates K-ras

Cancer medicine

2021 Volume 10, Issue 13, Page(s) 4451–4464

Abstract: ... deficiency on tongue tumor development in K (K-rasG12D)- and KP (K-rasG12D + Trp53-deficient)-inducible mice ... Results: Mice of K and KP genotypes developed squamous cell carcinoma in situ in the tongue approximately ... that in the presence of K-rasG12D, Ppp6c deletion enhanced the activation of the ERK-ELK1-FOS, AKT-4EBP1, and AKT-FOXO ...

Abstract	Background: Effective treatments for cancer harboring mutant RAS are lacking. In Drosophila, it was reported that PP6 suppresses tumorigenicity of mutant RAS. However, the information how PP6 regulates oncogenic RAS in mammals is limited. Methods: We examined the effects of PP6 gene (Ppp6c) deficiency on tongue tumor development in K (K-rasG12D)- and KP (K-rasG12D + Trp53-deficient)-inducible mice. Results: Mice of K and KP genotypes developed squamous cell carcinoma in situ in the tongue approximately 2 weeks after the induction of Ppp6c deficiency and was euthanized due to 20% loss of body weight. Transcriptome analysis revealed significantly different gene expressions between tissues of Ppp6c-deficient tongues and those of Ppp6c wild type, while Trp53 deficiency had a relatively smaller effect. We then analyzed genes commonly altered by Ppp6c deficiency, with or without Trp53 deficiency, and identified a group concentrated in KEGG database pathways defined as 'Pathways in Cancer' and 'Cytokine-cytokine receptor interaction'. We then evaluated signals downstream of oncogenic RAS and those regulated by PP6 substrates and found that in the presence of K-rasG12D, Ppp6c deletion enhanced the activation of the ERK-ELK1-FOS, AKT-4EBP1, and AKT-FOXO-CyclinD1 axes. Ppp6c deletion combined with K-rasG12D also enhanced DNA double-strand break (DSB) accumulation and activated NFκB signaling, upregulating IL-1β, COX2, and TNF.
MeSH term(s)	Animals ; Carcinoma in Situ/genetics ; Carcinoma, Squamous Cell/genetics ; DNA Breaks, Double-Stranded ; Gene Deletion ; Genes, ras ; Genotype ; Mice ; Mutation ; Phosphoprotein Phosphatases/deficiency ; Phosphoprotein Phosphatases/genetics ; Tongue Neoplasms/genetics ; Transcriptome ; Tumor Suppressor Protein p53/deficiency ; Tumor Suppressor Protein p53/genetics
Chemical Substances	Trp53 protein, mouse ; Tumor Suppressor Protein p53 ; Phosphoprotein Phosphatases (EC 3.1.3.16) ; protein phosphatase 6 (EC 3.1.3.16)
Language	English
Publishing date	2021-06-18
Publishing country	United States
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	2659751-2
ISSN	2045-7634 ; 2045-7634
ISSN (online)	2045-7634
ISSN	2045-7634
DOI	10.1002/cam4.3962
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Article ; Online: The investigation of activated carbon by K

Khuong, Duy Anh / Trinh, Kieu Trang / Nakaoka, Yu / Tsubota, Toshiki / Tashima, Daisuke / Nguyen, Hong Nam / Tanaka, Daisaku

Chemosphere

2022 Volume 299, Page(s) 134365

Abstract: In this study, the K ...

Abstract	In this study, the K
MeSH term(s)	Adsorption ; Carbon Dioxide/chemistry ; Charcoal/chemistry ; Porosity ; Water Purification
Chemical Substances	Carbon Dioxide (142M471B3J) ; Charcoal (16291-96-6)
Language	English
Publishing date	2022-03-21
Publishing country	England
Document type	Journal Article
ZDB-ID	120089-6
ISSN	1879-1298 ; 0045-6535 ; 0366-7111
ISSN (online)	1879-1298
ISSN	0045-6535 ; 0366-7111
DOI	10.1016/j.chemosphere.2022.134365
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Article ; Online: Detailed analysis of distorted retinal and its interaction with surrounding residues in the K intermediate of bacteriorhodopsin.

Taguchi, Shoun / Niwa, Satomi / Dao, Hoang-Anh / Tanaka, Yoshihiro / Takeda, Ryota / Fukai, Shuya / Hasegawa, Kazuya / Takeda, Kazuki

Communications biology

2023 Volume 6, Issue 1, Page(s) 190

Abstract: The K intermediate of proton pumping bacteriorhodopsin is the first intermediate generated after ... isomerization of retinal to the 13-cis form. Although various structures have been reported for the K ... analysis of the K structure. The polyene chain of 13-cis retinal is observed to be S-shaped. The side chain ...

Abstract	The K intermediate of proton pumping bacteriorhodopsin is the first intermediate generated after isomerization of retinal to the 13-cis form. Although various structures have been reported for the K intermediate until now, these differ from each other, especially in terms of the conformation of the retinal chromophore and its interaction with surrounding residues. We report here an accurate X-ray crystallographic analysis of the K structure. The polyene chain of 13-cis retinal is observed to be S-shaped. The side chain of Lys216, which is covalently bound to retinal via the Schiff-base linkage, interacts with residues, Asp85 and Thr89. In addition, the Nζ-H of the protonated Schiff-base linkage interacts with a residue, Asp212 and a water molecule, W402. Based on quantum chemical calculations for this K structure, we examine the stabilizing factors of distorted conformation of retinal and propose a relaxation manner to the next L intermediate.
MeSH term(s)	Bacteriorhodopsins/chemistry ; Models, Molecular ; Proton Pumps/chemistry ; Molecular Conformation ; Ion Transport
Chemical Substances	Bacteriorhodopsins (53026-44-1) ; Proton Pumps
Language	English
Publishing date	2023-02-17
Publishing country	England
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ISSN	2399-3642
ISSN (online)	2399-3642
DOI	10.1038/s42003-023-04554-2
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Book ; Online: Optimizing $k$ in $k$NN Graphs with Graph Learning Perspective

Tamaru, Asuka / Hara, Junya / Higashi, Hiroshi / Tanaka, Yuichi / Ortega, Antonio

2024

Abstract: In this paper, we propose a method, based on graph signal processing, to optimize the choice of $k$ ... in $k$-nearest neighbor graphs ($k$NNGs). $k$NN is one of the most popular approaches and is widely used ... in machine learning and signal processing. The parameter $k$ represents the number of neighbors that are connected ...

Abstract	In this paper, we propose a method, based on graph signal processing, to optimize the choice of $k$ in $k$-nearest neighbor graphs ($k$NNGs). $k$NN is one of the most popular approaches and is widely used in machine learning and signal processing. The parameter $k$ represents the number of neighbors that are connected to the target node; however, its appropriate selection is still a challenging problem. Therefore, most $k$NNGs use ad hoc selection methods for $k$. In the proposed method, we assume that a different $k$ can be chosen for each node. We formulate a discrete optimization problem to seek the best $k$ with a constraint on the sum of distances of the connected nodes. The optimal $k$ values are efficiently obtained without solving a complex optimization. Furthermore, we reveal that the proposed method is closely related to existing graph learning methods. In experiments on real datasets, we demonstrate that the $k$NNGs obtained with our method are sparse and can determine an appropriate variable number of edges per node. We validate the effectiveness of the proposed method for point cloud denoising, comparing our denoising performance with achievable graph construction methods that can be scaled to typical point cloud sizes (e.g., thousands of nodes).
Keywords	Computer Science - Machine Learning ; Electrical Engineering and Systems Science - Signal Processing
Subject code	006
Publishing date	2024-01-16
Publishing country	us
Document type	Book ; Online
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Article: Vitamin K intake and health, consideration from the epidemiological studies.

Kuwabara, Akiko / Uenishi, Kazuhiro / Tanaka, Kiyoshi

Journal of clinical biochemistry and nutrition

2021 Volume 69, Issue 2, Page(s) 111–121

Abstract: The most fundamental function of vitamin K is to activate the blood coagulation factors ... Intakes for vitamin K is based on the amount necessary for maintaining the normal blood coagulation ... in many countries. To define the Dietary Reference Intake for vitamin K, appropriate biomarkers well-reflecting ...

Abstract	The most fundamental function of vitamin K is to activate the blood coagulation factors in the liver. Despite the recent recognition of its extra-hepatic actions, the current Dietary Reference Intakes for vitamin K is based on the amount necessary for maintaining the normal blood coagulation in many countries. To define the Dietary Reference Intake for vitamin K, appropriate biomarkers well-reflecting the vitamin K status are essential. Unfortunately, however, no markers are currently available with properties enabling us to properly define the vitamin K status; i.g., no interference by other factors and the presence of widely approved cut-off values. Thus, Adequate Intake is determined, which is an index based on the representative dietary intake data from healthy individuals. Recently, epidemiological studies have been reported regarding the relationship between vitamin K and noncommunicable diseases including osteoporotic fracture. Furthermore, studies focusing on the relationship between vitamin K intake and metabolic syndrome, physical function, depression, cognition, and all-cause mortality have become available, although limited in number. This review summarizes the recent findings in favor of the novel functions of vitamin K. More epidemiological studies are needed to define the appropriate vitamin K intake value based on the prevention of various disorders.
Language	English
Publishing date	2021-03-25
Publishing country	Japan
Document type	Journal Article
ZDB-ID	632945-7
ISSN	1880-5086 ; 0912-0009
ISSN (online)	1880-5086
ISSN	0912-0009
DOI	10.3164/jcbn.20-64
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Article ; Online: Measurement of CP Violation in B^{0}→K_{S}^{0}π^{0} Decays at Belle II.

Adachi, I / Adamczyk, K / Aggarwal, L / Ahmed, H / Aihara, H / Akopov, N / Aloisio, A / Anh Ky, N / Asner, D M / Atmacan, H / Aushev, T / Aushev, V / Aversano, M / Babu, V / Bae, H / Bahinipati, S / Bambade, P / Banerjee, Sw / Barrett, M /

Baudot, J / Bauer, M / Baur, A / Beaubien, A / Becker, J / Behera, P K / Bennett, J V / Bertacchi, V / Bertemes, M / Bertholet, E / Bessner, M / Bettarini, S / Bhuyan, B / Bianchi, F / Bilka, T / Biswas, D / Bodrov, D / Bondar, A / Borah, J / Bozek, A / Bračko, M / Branchini, P / Briere, R A / Browder, T E / Budano, A / Bussino, S / Campajola, M / Cao, L / Casarosa, G / Cecchi, C / Cerasoli, J / Chang, P / Cheaib, R / Cheema, P / Chekelian, V / Chen, C / Cheon, B G / Chilikin, K / Chirapatpimol, K / Cho, H-E / Cho, K / Cho, S-J / Choi, S-K / Choudhury, S / Cochran, J / Corona, L / Cremaldi, L M / Das, S / Dattola, F / De La Cruz-Burelo, E / De La Motte, S A / de Marino, G / De Nuccio, M / De Pietro, G / de Sangro, R / Destefanis, M / De Yta-Hernandez, A / Dhamija, R / Di Canto, A / Di Capua, F / Dingfelder, J / Doležal, Z / Domínguez Jiménez, I / Dong, T V / Dorigo, M / Dort, K / Dreyer, S / Dubey, S / Dujany, G / Ecker, P / Eliachevitch, M / Feichtinger, P / Ferber, T / Ferlewicz, D / Fillinger, T / Finck, C / Finocchiaro, G / Fodor, A / Forti, F / Fulsom, B G / Gabrielli, A / Ganiev, E / Garcia-Hernandez, M / Garg, R / Garmash, A / Gaudino, G / Gaur, V / Gaz, A / Gellrich, A / Ghosh, D / Giakoustidis, G / Giordano, R / Giri, A / Glazov, A / Gobbo, B / Godang, R / Goldenzweig, P / Gradl, W / Grammatico, T / Granderath, S / Graziani, E / Greenwald, D / Gruberová, Z / Gu, T / Guan, Y / Gudkova, K / Halder, S / Han, Y / Hara, K / Hara, T / Hayasaka, K / Hayashii, H / Hazra, S / Hearty, C / Hedges, M T / Heredia de la Cruz, I / Hernández Villanueva, M / Hershenhorn, A / Higuchi, T / Hill, E C / Hoek, M / Hohmann, M / Hsu, C-L / Humair, T / Iijima, T / Inami, K / Ipsita, N / Ishikawa, A / Ito, S / Itoh, R / Iwasaki, M / Jackson, P / Jacobs, W W / Jang, E-J / Ji, Q P / Jia, S / Jin, Y / Johnson, A / Joo, K K / Junkerkalefeld, H / Kaleta, M / Kaliyar, A B / Kandra, J / Kang, K H / Kang, S / Kar, S / Karyan, G / Kawasaki, T / Keil, F / Ketter, C / Kiesling, C / Kim, C-H / Kim, D Y / Kim, K-H / Kim, Y-K / Kindo, H / Kodyš, P / Koga, T / Kohani, S / Kojima, K / Korobov, A / Korpar, S / Kovalenko, E / Kowalewski, R / Kraetzschmar, T M G / Križan, P / Krokovny, P / Kuhr, T / Kumar, J / Kumar, M / Kumara, K / Kunigo, T / Kuzmin, A / Kwon, Y-J / Lacaprara, S / Lai, Y-T / Lam, T / Lange, J S / Laurenza, M / Leboucher, R / Le Diberder, F R / Leitl, P / Levit, D / Li, C / Li, L K / Libby, J / Liu, Q Y / Liu, Z Q / Liventsev, D / Longo, S / Lueck, T / Luo, T / Lyu, C / Ma, Y / Maggiora, M / Maharana, S P / Maiti, R / Maity, S / Mancinelli, G / Manfredi, R / Manoni, E / Mantovano, M / Marcantonio, D / Marcello, S / Marinas, C / Martel, L / Martellini, C / Martinov, T / Massaccesi, L / Masuda, M / Matsuda, T / Matsuoka, K / Matvienko, D / Maurya, S K / McKenna, J A / Mehta, R / Meier, F / Merola, M / Metzner, F / Milesi, M / Miller, C / Mirra, M / Miyabayashi, K / Mizuk, R / Mohanty, G B / Molina-Gonzalez, N / Mondal, S / Moneta, S / Moser, H-G / Mrvar, M / Mussa, R / Nakamura, I / Nakazawa, Y / Narimani Charan, A / Naruki, M / Natochii, A / Nayak, L / Nayak, M / Nazaryan, G / Nisar, N K / Nishida, S / Ono, H / Onuki, Y / Oskin, P / Pakhlov, P / Pakhlova, G / Paladino, A / Paoloni, E / Pardi, S / Parham, K / Park, H / Park, S-H / Passeri, A / Patra, S / Paul, S / Pedlar, T K / Peschke, R / Pestotnik, R / Pham, F / Piccolo, M / Piilonen, L E / Podesta-Lerma, P L M / Podobnik, T / Pokharel, S / Praz, C / Prell, S / Prencipe, E / Prim, M T / Purwar, H / Rad, N / Rados, P / Raeuber, G / Raiz, S / Reif, M / Reiter, S / Remnev, M / Ripp-Baudot, I / Rizzo, G / Robertson, S H / Roehrken, M / Roney, J M / Rostomyan, A / Rout, N / Russo, G / Sahoo, D / Sandilya, S / Sangal, A / Santelj, L / Sato, Y / Savinov, V / Scavino, B / Schmitt, C / Schwanda, C / Schwartz, A J / Seino, Y / Selce, A / Senyo, K / Serrano, J / Sevior, M E / Sfienti, C / Shan, W / Sharma, C / Shi, X D / Shillington, T / Shiu, J-G / Shtol, D / Sibidanov, A / Simon, F / Singh, J B / Skorupa, J / Sobie, R J / Sobotzik, M / Soffer, A / Sokolov, A / Solovieva, E / Spataro, S / Spruck, B / Starič, M / Stavroulakis, P / Stefkova, S / Stottler, Z S / Stroili, R / Sumihama, M / Sumisawa, K / Sutcliffe, W / Svidras, H / Takahashi, M / Takizawa, M / Tamponi, U / Tanaka, S / Tanida, K / Tenchini, F / Thaller, A / Tittel, O / Tiwary, R / Tonelli, D / Torassa, E / Trabelsi, K / Tsaklidis, I / Uchida, M / Ueda, I / Uglov, T / Unger, K / Unno, Y / Uno, K / Uno, S / Urquijo, P / Ushiroda, Y / Vahsen, S E / van Tonder, R / Varner, G S / Varvell, K E / Vinokurova, A / Vismaya, V S / Vitale, L / Wach, B / Wakai, M / Wakeling, H M / Wallner, S / Wang, E / Wang, M-Z / Wang, Z / Warburton, A / Watanabe, M / Watanuki, S / Welsch, M / Wessel, C / Won, E / Xu, X P / Yabsley, B D / Yamada, S / Yan, W / Yang, S B / Yin, J H / Yoshihara, K / Yuan, C Z / Yusa, Y / Zani, L / Zhang, Y / Zhilich, V / Zhou, Q D / Zhukova, V I

Physical review letters

2023 Volume 131, Issue 11, Page(s) 111803

Abstract: We report a measurement of the CP-violating parameters C and S in B^{0}→K_{S}^{0}π^{0} decays ...

Abstract	We report a measurement of the CP-violating parameters C and S in B^{0}→K_{S}^{0}π^{0} decays at Belle II using a sample of 387×10^{6} BB[over ¯] events recorded in e^{+}e^{-} collisions at a center-of-mass energy corresponding to the ϒ(4S) resonance. These parameters are determined by fitting the proper decay-time distribution of a sample of 415 signal events. We obtain C=-0.04_{-0.15}^{+0.14}±0.05 and S=0.75_{-0.23}^{+0.20}±0.04, where the first uncertainties are statistical and the second are systematic.
Language	English
Publishing date	2023-09-29
Publishing country	United States
Document type	Journal Article
ZDB-ID	208853-8
ISSN	1079-7114 ; 0031-9007
ISSN (online)	1079-7114
ISSN	0031-9007
DOI	10.1103/PhysRevLett.131.111803
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Article ; Online: Two States of Water Converge to One State below 215 K.

Oka, Kouki / Shibue, Toshimichi / Sugimura, Natsuhiko / Watabe, Yuki / Tanaka, Midori / Winther-Jensen, Bjorn / Nishide, Hiroyuki

The journal of physical chemistry letters

2021 Volume 12, Issue 24, Page(s) 5802–5806

Abstract: ... one state upon supercooling. However, water crystallizes completely below 235 K ("no man's land ... land". We found the singularity temperature (215 K) at ambient pressure. Water exists in one state ... below 215 K. Above 215 K, the two states of water are supercritical states of the liquid-liquid critical ...

Abstract	Anomalies of water have been explained by the two-state water model. In the model, water becomes one state upon supercooling. However, water crystallizes completely below 235 K ("no man's land"). The structural origin of the anomalous of the water is hidden in the "no man's land". To understand the properties of water, the spectroscopic experiment in "Norman's land" is inevitable. Hence, we proposed a new soft-confinement method for standard nuclear magnetic resonance spectroscopy to explore the "no man's land". We found the singularity temperature (215 K) at ambient pressure. Water exists in one state below 215 K. Above 215 K, the two states of water are supercritical states of the liquid-liquid critical point. The current study provides a perspective to determine the liquid-liquid critical point of water existing in a high-pressure condition.
Language	English
Publishing date	2021-06-17
Publishing country	United States
Document type	Journal Article
ISSN	1948-7185
ISSN (online)	1948-7185
DOI	10.1021/acs.jpclett.1c01132
Database	MEDical Literature Analysis and Retrieval System OnLINE

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