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  1. Article ; Online: MIC: Microwave Imaging Curtain for Dynamic and Automatic Detection of Weapons and Explosive Belts.

    Baqué, Rémi / Vignaud, Luc / Wasik, Valentine / Castet, Nicolas / Herschel, Reinhold / Cetinkaya, Harun / Brandes, Thomas

    Sensors (Basel, Switzerland)

    2023  Volume 23, Issue 23

    Abstract: DEXTER (detection of explosives and firearms to counter terrorism) is a project funded by NATO's Science for Peace and Security (SPS) program with the goal of developing an integrated system capable of remotely and accurately detecting explosives and ... ...

    Abstract DEXTER (detection of explosives and firearms to counter terrorism) is a project funded by NATO's Science for Peace and Security (SPS) program with the goal of developing an integrated system capable of remotely and accurately detecting explosives and firearms in public places without impeding the flow of pedestrians. While body scanner systems in secure areas of public places are becoming more and more efficient, the attack at Brussels airport on 22 March 2016, upstream of these systems, in the middle of the crowd of passengers, demonstrated the lack of discreet and real-time security against threats of mass terrorism. The NATO-SPS international and multi-year DEXTER project aims to provide new technical and strategic solutions to fill this gap. This project is based on multi-sensor coordination and fusion, from hyperspectral remote laser to smart glasses, artificial algorithms, and suspect identification and tracking. One of these sensors is dedicated to threat detection (large weapon or explosive belt) using the clothing of pedestrians by means of an active microwave component. This project is referred to as MIC (Microwave Imaging Curtain), also supported by the French SGDSN (General Secretariat of Defense and National Security), and utilizes a radar system capable of generating 3D images in real-time to address non-checkpoint detection of explosives and firearms. The project, led by ONERA (France), is based on a radar imaging system developed by the Fraunhofer FHR institute, using a MIMO architecture with an Ultra-Wide Band waveform. Although high-resolution 3D microwave imaging is already being used in expensive body scanners to detect firearms concealed under clothing, MIC's innovative approach lies in utilizing a high-resolution 3D imaging device that can detect larger dangerous objects carried by moving individuals at a longer range, in addition to providing discrete detection in pedestrian flow. Automatic detection and classification of these dangerous objects is carried out on 3D radar images using a deep-learning network. This paper will outline the project's objectives and constraints, as well as the design, architecture, and performance of the final system. Additionally, it will present real-time imaging results obtained during a live demonstration in a relevant environment.
    Language English
    Publishing date 2023-11-30
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2052857-7
    ISSN 1424-8220 ; 1424-8220
    ISSN (online) 1424-8220
    ISSN 1424-8220
    DOI 10.3390/s23239531
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Porous materials applied to biomarker sensing in exhaled breath for monitoring and detecting non-invasive pathologies.

    André, Laurie / Desbois, Nicolas / Gros, Claude P / Brandès, Stéphane

    Dalton transactions (Cambridge, England : 2003)

    2020  Volume 49, Issue 43, Page(s) 15161–15170

    Abstract: The quantification of specific gases among thousands of VOCs (Volatile Organic Compounds) present in the human breath at the ppm/ppb level can be used to evidence the presence of diseases in the human body. The detection of these biomarkers in human ... ...

    Abstract The quantification of specific gases among thousands of VOCs (Volatile Organic Compounds) present in the human breath at the ppm/ppb level can be used to evidence the presence of diseases in the human body. The detection of these biomarkers in human exhaled breath through a noninvasive approach is an important field of research that is still attracting significant attention to this day. A portable device working at room temperature and usable directly on exhaled breath samples is still a challenge requiring a sensing material with high performances. The rich composition of the human breath implies that the sensing material must be highly selective and sensitive (ppm/ppb) in high relative humidity (RH) conditions and preferably at room temperature. The present work intends to provide a review on recent works in this application field through the use of porous materials and discuss the importance of Metal Organic Frameworks (MOFs) for such application. MOFs are highly porous crystalline materials often used for gas detection and capture, thus raising questions about their potential for detection in exhaled breath.
    MeSH term(s) Biomarkers/analysis ; Breath Tests/methods ; Exhalation ; Humans ; Limit of Detection ; Porosity
    Chemical Substances Biomarkers
    Language English
    Publishing date 2020-10-16
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d0dt02511a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Cobalt tris(4-vinylphenyl)corrole: out of the frying pan into the polymer.

    Desbois, Nicolas / Osterloh, W Ryan / Sabat, Dimitri / Monot, Camille / Brandès, Stéphane / Meyer, Michel / Chaar, Capucine / Hespel, Louise / Lebrun, Laurent / Baati, Rachid / Estour, François / Gros, Claude P

    Chemical communications (Cambridge, England)

    2023  Volume 59, Issue 15, Page(s) 2098–2101

    Abstract: A novel cobalt corrole bearing 4-vinylphenyl groups at the 5,10,15- ...

    Abstract A novel cobalt corrole bearing 4-vinylphenyl groups at the 5,10,15-
    Language English
    Publishing date 2023-02-16
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc06872a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Porous organic polymers based on cobalt corroles for carbon monoxide binding.

    Brandès, Stéphane / Quesneau, Valentin / Fonquernie, Osian / Desbois, Nicolas / Blondeau-Patissier, Virginie / Gros, Claude P

    Dalton transactions (Cambridge, England : 2003)

    2019  Volume 48, Issue 31, Page(s) 11651–11662

    Abstract: Porous organic polymers (POPs), known for their high surface area and porosity, were prepared starting from tetraphenyl tetrahedral-shaped building blocks and corrole macrocyclic linkers either as free bases or cobalt complexes. This synthetic method ... ...

    Abstract Porous organic polymers (POPs), known for their high surface area and porosity, were prepared starting from tetraphenyl tetrahedral-shaped building blocks and corrole macrocyclic linkers either as free bases or cobalt complexes. This synthetic method allowed us to construct new porous frameworks with high carbon monoxide adsorption properties. Two synthetic strategies were developed for incorporating cobalt corroles into the porous matrix. The first method is based on the copper-free Sonogashira cross-coupling reaction between a free base diodo-corrole with a tetrahedral shaped derivative followed by cobalt complexation of the resulting material, leading to POP-CorCo-1. The second strategy consists of preparing POP-CorCo-2 by directly using in the coupling reaction the metalated cobalt corrole temporarily protected by two ammine ligands at the axial position. The design principles as well as the relationship between the structure and the selective CO adsorption performance are presented. The adsorption capacities and selectivities of CO were calculated from a multisite Langmuir isotherm model and using IAST theory. Spectroscopic studies (NMR, FTIR, UV-visible), kinetic sorption measurements and microscopic analyses made possible to provide a fairly complete description of the structure of the POPs, their porosity and the nature of solid-gas interactions. The POPs prepared by both methods show a high permanent porosity and outstanding CO sorption properties with a high selectivity over N2, O2 and CO2, up to 15 700, 4000 and 1800, respectively. The two POP-CorCo therefore offer confined molecular spaces for ascertaining a high accessibility of the metallocorrole active sites for gas binding on the cobalt atom, thus featuring high potential for applications in selective capture or sensing of CO versus N2, O2 and CO2.
    Language English
    Publishing date 2019-07-23
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c9dt01599j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Book ; Online ; Thesis: Oxidative thiol modifications in pro- and eukaryotic organisms

    Brandes, Nicolas [Verfasser]

    2010  

    Author's details vorgelegt von Nicolas Brandes
    Keywords Biowissenschaften, Biologie ; Life Science, Biology
    Subject code sg570
    Language English
    Document type Book ; Online ; Thesis
    Database Digital theses on the web

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  6. Article ; Online: Ligand Noninnocence in Cobalt Dipyrrin-Bisphenols: Spectroscopic, Electrochemical, and Theoretical Insights Indicating an Emerging Analogy with Corroles.

    Shan, Wenqian / Desbois, Nicolas / Pacquelet, Sandrine / Stéphane Brandès / Rousselin, Yoann / Conradie, Jeanet / Ghosh, Abhik / Gros, Claude P / Kadish, Karl M

    Inorganic chemistry

    2019  Volume 58, Issue 12, Page(s) 7677–7689

    Abstract: Three cobalt dipyrrin-bisphenol (DPPCo) complexes with different meso-aryl groups (pentafluorophenyl, phenyl, and mesityl) were synthesized and characterized based on their electrochemistry and spectroscopic properties in nonaqueous media. Each DPPCo ... ...

    Abstract Three cobalt dipyrrin-bisphenol (DPPCo) complexes with different meso-aryl groups (pentafluorophenyl, phenyl, and mesityl) were synthesized and characterized based on their electrochemistry and spectroscopic properties in nonaqueous media. Each DPPCo undergoes multiple oxidations and reductions with the potentials, reversibility, and number of processes depending on the specific solution conditions, the specific macrocyclic substituents, and the type and number of axially coordinated ligands on the central cobalt ion. Theoretical calculations of the compounds with different coordination numbers are given in the current study in order to elucidate the cobalt-ion oxidation state and the innocence or noninnocence of the macrocyclic ligand as a function of the changes in the solvent properties and degree of axial coordination. Electron paramagnetic resonance spectra of the compounds are obtained to experimentally assess the electron spin state. An X-ray structure of the six-coordinate complex is also presented. The investigated chemical properties of DPPCo compounds under different solution conditions are compared to those of cobalt corroles, where the macrocycle and metal ion also possess formal 3- and 3+ oxidation states in their air-stable forms.
    Language English
    Publishing date 2019-01-17
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.8b03006
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Old Dog, New Tricks: Innocent, Five-coordinate Cyanocobalt Corroles.

    Osterloh, W Ryan / Desbois, Nicolas / Quesneau, Valentin / Brandès, Stéphane / Fleurat-Lessard, Paul / Fang, Yuanyuan / Blondeau-Patissier, Virginie / Paolesse, Roberto / Gros, Claude P / Kadish, Karl M

    Inorganic chemistry

    2020  Volume 59, Issue 12, Page(s) 8562–8579

    Abstract: Three mono-CN ligated anionic cobalt ... ...

    Abstract Three mono-CN ligated anionic cobalt A
    Language English
    Publishing date 2020-05-26
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.0c01037
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Synthesis and the Effect of Anions on the Spectroscopy and Electrochemistry of Mono(dimethyl sulfoxide)-Ligated Cobalt Corroles.

    Osterloh, W Ryan / Quesneau, Valentin / Desbois, Nicolas / Brandès, Stéphane / Shan, Wenqian / Blondeau-Patissier, Virginie / Paolesse, Roberto / Gros, Claude P / Kadish, Karl M

    Inorganic chemistry

    2019  Volume 59, Issue 1, Page(s) 595–611

    Abstract: A new series of cobalt ... ...

    Abstract A new series of cobalt A
    Language English
    Publishing date 2019-12-11
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.9b02855
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Diamondoid Nanostructures as sp

    Moncea, Oana / Casanova-Chafer, Juan / Poinsot, Didier / Ochmann, Lukas / Mboyi, Clève D / Nasrallah, Houssein O / Llobet, Eduard / Makni, Imen / El Atrous, Molka / Brandès, Stéphane / Rousselin, Yoann / Domenichini, Bruno / Nuns, Nicolas / Fokin, Andrey A / Schreiner, Peter R / Hierso, Jean-Cyrille

    Angewandte Chemie (International ed. in English)

    2019  Volume 58, Issue 29, Page(s) 9933–9938

    Abstract: Diamondoids, ... ...

    Abstract Diamondoids, sp
    Language English
    Publishing date 2019-06-11
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.201903089
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Electrochemistry of Bis(pyridine)cobalt (Nitrophenyl)corroles in Nonaqueous Media.

    Jiang, Xiaoqin / Naitana, Mario L / Desbois, Nicolas / Quesneau, Valentin / Brandès, Stéphane / Rousselin, Yoann / Shan, Wenqian / Osterloh, W Ryan / Blondeau-Patissier, Virginie / Gros, Claude P / Kadish, Karl M

    Inorganic chemistry

    2018  Volume 57, Issue 3, Page(s) 1226–1241

    Abstract: A series of bis(pyridine)cobalt corroles with one or three nitrophenyl groups on the meso positions of the corrole macrocycle were synthesized and characterized as to their electrochemical and spectroscopic properties in dichloromethane, benzonitrile, ... ...

    Abstract A series of bis(pyridine)cobalt corroles with one or three nitrophenyl groups on the meso positions of the corrole macrocycle were synthesized and characterized as to their electrochemical and spectroscopic properties in dichloromethane, benzonitrile, and pyridine. The potentials for each electrode reaction were measured by cyclic voltammetry and the electron-transfer mechanisms evaluated by analysis of the electrochemical data combined with UV-visible spectra of the neutral, electroreduced, and electroxidized forms of the corroles. The proposed electronic configurations of the initial compounds and the prevailing redox reactions involving the electroactive central cobalt ion, the electroactive conjugated macrocycle, and the electroactive meso-nitrophenyl groups are all discussed in terms of solvent binding and the number of the nitrophenyl groups and other substituents on the meso-nitrophenyl rings of the compounds.
    Language English
    Publishing date 2018-02-05
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.7b02655
    Database MEDical Literature Analysis and Retrieval System OnLINE

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