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  1. Article: Weak inter-actions in crystals: old concepts, new developments.

    Batsanov, Andrei S

    Acta crystallographica. Section E, Crystallographic communications

    2018  Volume 74, Issue Pt 5, Page(s) 570–574

    Abstract: Andrei Batsanov presents a general review of weak interactions in crystals, which highlights ...

    Abstract Andrei Batsanov presents a general review of weak interactions in crystals, which highlights the history, state-of-the art and future developments of this field.
    Language English
    Publishing date 2018-04-17
    Publishing country England
    Document type Journal Article
    ZDB-ID 2041947-8
    ISSN 2056-9890 ; 1600-5368
    ISSN 2056-9890 ; 1600-5368
    DOI 10.1107/S2056989018005339
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Transparent Colloids of Detonation Nanodiamond: Physical, Chemical and Biological Properties.

    Batsanov, Stepan S / Gavrilkin, Sergey M / Dan'kin, Dmitry A / Batsanov, Andrei S / Kurakov, Alexander V / Shatalova, Tatiana B / Kulikova, Inna M

    Materials (Basel, Switzerland)

    2023  Volume 16, Issue 18

    Abstract: Aqueous suspensions (colloids) containing detonation nano-diamond (DND) feature in most applications of DND and are an indispensable stage of its production; therefore, the interaction of DND with water is actively studied. However, insufficient ... ...

    Abstract Aqueous suspensions (colloids) containing detonation nano-diamond (DND) feature in most applications of DND and are an indispensable stage of its production; therefore, the interaction of DND with water is actively studied. However, insufficient attention has been paid to the unique physico-chemical and biological properties of transparent colloids with
    Language English
    Publishing date 2023-09-15
    Publishing country Switzerland
    Document type Journal Article ; Review
    ZDB-ID 2487261-1
    ISSN 1996-1944
    ISSN 1996-1944
    DOI 10.3390/ma16186227
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Editorial on "Genesis on diamonds II: contact with diamond enhances human sperm performance by 300%".

    Batsanov, Stepan S / Batsanov, Andrei S

    Annals of translational medicine

    2017  Volume 5, Issue 20, Page(s) 407

    Language English
    Publishing date 2017-06-30
    Publishing country China
    Document type Editorial ; Comment
    ZDB-ID 2893931-1
    ISSN 2305-5847 ; 2305-5839
    ISSN (online) 2305-5847
    ISSN 2305-5839
    DOI 10.21037/atm.2017.07.15
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  4. Article ; Online: Oxidation State Tuning of Room Temperature Phosphorescence and Delayed Fluorescence in Phenothiazine and Phenothiazine-5,5-dioxide Dimers.

    Wright, Iain A / Etherington, Marc K / Batsanov, Andrei S / Monkman, Andrew P / Bryce, Martin R

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2023  Volume 29, Issue 30, Page(s) e202300428

    Abstract: Heterocyclic dimers consisting of combinations of butterfly-shaped phenothiazine (PTZ) and its chemically oxidized form phenothiazine-5,5-dioxide (PTZ( ... ...

    Abstract Heterocyclic dimers consisting of combinations of butterfly-shaped phenothiazine (PTZ) and its chemically oxidized form phenothiazine-5,5-dioxide (PTZ(SO
    Language English
    Publishing date 2023-04-19
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1478547-X
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.202300428
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  5. Article ; Online: Weak interactions in crystals

    Andrei S. Batsanov

    Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 5, Pp 570-

    old concepts, new developments

    2018  Volume 574

    Keywords crystallography ; weak interactions ; editorial ; Chemistry ; QD1-999
    Language English
    Publishing date 2018-05-01T00:00:00Z
    Publisher International Union of Crystallography
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  6. Article ; Online: Nitrogen Fixation and Biological Behavior of Nanodiamond Colloidal Solutions.

    Kurakov, Alexander V / Batsanov, Andrei S / Gavrilkin, Sergei M / Batsanov, Stepan S

    ChemPlusChem

    2020  Volume 85, Issue 8, Page(s) 1905–1911

    Abstract: Detonation-produced nanodiamond, both as a powder (with adsorbed water) and especially when suspended in an aqueous colloid, can support the growth (both aerobic and anaerobic) of bacteria and fungi. These were isolated and identified by microbiological ... ...

    Abstract Detonation-produced nanodiamond, both as a powder (with adsorbed water) and especially when suspended in an aqueous colloid, can support the growth (both aerobic and anaerobic) of bacteria and fungi. These were isolated and identified by microbiological methods, optical and electron microscopy, as species of Penicillium, Purpureocillium, Beaveria, Trichoderma and Aspergillus genera. The C : N molar ratio of the developing fibers (comprising fungal mycelia with attached bacteria and entrapped nanodiamond) decreased from 25 to 11 between the 1
    MeSH term(s) Adsorption ; Bacteria/ultrastructure ; Colloids/chemistry ; Fungi/ultrastructure ; Microscopy, Electron, Scanning ; Nanodiamonds/chemistry ; Nitrogen Fixation ; Solutions ; Surface Properties
    Chemical Substances Colloids ; Nanodiamonds ; Solutions
    Language English
    Publishing date 2020-08-26
    Publishing country Germany
    Document type Journal Article
    ISSN 2192-6506
    ISSN (online) 2192-6506
    DOI 10.1002/cplu.202000437
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  7. Article: Phospho-rescent mono- and diiridium(III) complexes cyclo-metalated by fluorenyl- or phenyl-pyridino ligands with bulky substituents, as prospective OLED dopants.

    M'hamedi, Ahmed / Batsanov, Andrei S

    Acta crystallographica. Section E, Crystallographic communications

    2020  Volume 76, Issue Pt 3, Page(s) 392–399

    Abstract: The crystal structures of tris-[9,9-dihexyl-2-(5-meth-oxy-pyridin-2-yl- ... ...

    Abstract The crystal structures of tris-[9,9-dihexyl-2-(5-meth-oxy-pyridin-2-yl-κ
    Language English
    Publishing date 2020-02-18
    Publishing country England
    Document type Journal Article
    ZDB-ID 2041947-8
    ISSN 2056-9890 ; 1600-5368
    ISSN 2056-9890 ; 1600-5368
    DOI 10.1107/S2056989020001784
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Development of a Continuous Photochemical Benzyne-Forming Process

    Cormac Bracken / Andrei S. Batsanov / Marcus Baumann

    SynOpen, Vol 05, Iss 01, Pp 29-

    2021  Volume 35

    Abstract: A continuous-flow process is presented that enables the safe generation and derivatization of benzyne under photochemical conditions. This is facilitated by a new high-power LED lamp emitting light at 365 nm. The resulting flow process effectively ... ...

    Abstract A continuous-flow process is presented that enables the safe generation and derivatization of benzyne under photochemical conditions. This is facilitated by a new high-power LED lamp emitting light at 365 nm. The resulting flow process effectively controls the release of gaseous by-products based on an adjustable backpressure regulator and delivers a series of heterocyclic products in a short residence time of 3 minutes. The robustness of this methodology is demonstrated for the rapid generation of benzotriazoles, 2H-indazoles and various furan-derived adducts, facilitating the preparation of these important heterocyclic scaffolds via a simple and readily scalable flow protocol.
    Keywords flow chemistry ; photochemistry ; benzyne ; cycloadditions ; high-energy intermediates ; reaction development ; heterocycles ; Chemistry ; QD1-999
    Language English
    Publishing date 2021-01-01T00:00:00Z
    Publisher Georg Thieme Verlag KG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  9. Article ; Online: Intramolecular Hydrogen Bonding in Thermally Activated Delayed Fluorescence Emitters: Is There Evidence Beyond Reasonable Doubt?

    Hempe, Matthias / Kukhta, Nadzeya A / Danos, Andrew / Batsanov, Andrei S / Monkman, Andrew P / Bryce, Martin R

    The journal of physical chemistry letters

    2022  Volume 13, Issue 35, Page(s) 8221–8227

    Abstract: Intramolecular hydrogen bonding between donor and acceptor segments in thermally activated delayed fluorescence (TADF) materials is now frequently employed to─purportedly─rigidify the structure and improve the emission performance of these materials. ... ...

    Abstract Intramolecular hydrogen bonding between donor and acceptor segments in thermally activated delayed fluorescence (TADF) materials is now frequently employed to─purportedly─rigidify the structure and improve the emission performance of these materials. However, direct evidence for these intramolecular interactions is often lacking or ambiguous, leading to assertions that are largely speculative. Here we investigate a series of TADF-active materials incorporating pyridine, which bestows the potential ability to form intramolecular H-bonding interactions. Despite possible indications of H-bonding from an X-ray analysis, an array of other experimental investigations proved largely inconclusive. Instead, after examining computational potential energy surfaces of the donor-acceptor torsion angle we conclude that the pyridine group primarily alleviates steric congestion in our case, rather than enabling an H-bond interaction as elsewhere assumed. We suggest that many previously reported "H-bonding" TADF materials featuring similar chemical motifs may instead operate similarly and that investigation of potential energy surfaces should become a key feature of future studies.
    Language English
    Publishing date 2022-08-25
    Publishing country United States
    Document type Journal Article
    ISSN 1948-7185
    ISSN (online) 1948-7185
    DOI 10.1021/acs.jpclett.2c00907
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  10. Article ; Online: Exploring the Impact of the HOMO-LUMO Gap on Molecular Thermoelectric Properties: A Comparative Study of Conjugated Aromatic, Quinoidal, and Donor-Acceptor Core Systems.

    Blankevoort, Nickel / Bastante, Pablo / Davidson, Ross J / Salthouse, Rebecca J / Daaoub, Abdalghani H S / Cea, Pilar / Solans, Santiago Martin / Batsanov, Andrei S / Sangtarash, Sara / Bryce, Martin R / Agrait, Nicolas / Sadeghi, Hatef

    ACS omega

    2024  Volume 9, Issue 7, Page(s) 8471–8477

    Abstract: Thermoelectric materials have garnered significant interest for their potential to efficiently convert waste heat into electrical energy at room temperature without moving parts or harmful emissions. This study investigated the impact of the HOMO-LUMO (H- ...

    Abstract Thermoelectric materials have garnered significant interest for their potential to efficiently convert waste heat into electrical energy at room temperature without moving parts or harmful emissions. This study investigated the impact of the HOMO-LUMO (H-L) gap on the thermoelectric properties of three distinct classes of organic compounds: conjugated aromatics (isoindigos (IIGs)), quinoidal molecules (benzodipyrrolidones (BDPs)), and donor-acceptor systems (bis(pyrrol-2-yl)squaraines (BPSs)). These compounds were chosen for their structural simplicity and linear π-conjugated conductance paths, which promote high electrical conductance and minimize complications from quantum interference. Single-molecule thermoelectric measurements revealed that despite their low H-L gaps, the Seebeck coefficients of these compounds remain low. The alignment of the frontier orbitals relative to the Fermi energy was found to play a crucial role in determining the Seebeck coefficients, as exemplified by the BDP compounds. Theoretical calculations support these findings and suggest that anchor group selection could further enhance the thermoelectric behavior of these types of molecules.
    Language English
    Publishing date 2024-02-05
    Publishing country United States
    Document type Journal Article
    ISSN 2470-1343
    ISSN (online) 2470-1343
    DOI 10.1021/acsomega.3c09760
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