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  1. Article ; Online: Assessment of heavy metal contamination in soils at the Kpone landfill site, Ghana: Implication for ecological and health risk assessment.

    Obiri-Nyarko, Franklin / Duah, Anthony A / Karikari, Anthony Y / Agyekum, William A / Manu, Evans / Tagoe, Ralph

    Chemosphere

    2021  Volume 282, Page(s) 131007

    Abstract: Concentrations of lead (Pb), zinc (Zn), copper (Cu), mercury (Hg), and arsenic (As) in soils at the Kpone landfill site (Ghana) were determined using Atomic Absorption Spectrophotometry (AAS). Further analyses allowed establishing the degree of heavy ... ...

    Abstract Concentrations of lead (Pb), zinc (Zn), copper (Cu), mercury (Hg), and arsenic (As) in soils at the Kpone landfill site (Ghana) were determined using Atomic Absorption Spectrophotometry (AAS). Further analyses allowed establishing the degree of heavy metals (HMs) pollution, suitability of the soils for agriculture, sources of the HMs and their ecological and health risks. The site was divided into five zones, A, B, C, D, and E, and in all, seventeen (17) soil samples were collected. Average concentrations of Cu fell within the allowable range for agricultural soils in all the zones while average concentrations of Pb, Zn, Hg, and As exceeded the range in some or all the zones. Concentrations of the HMs generally exceeded their respective background value, with all zones showing very high degree of HMs contamination. The pollution load index (PLI) was 16.48, signifying extreme HMs pollution of the entire site. Multivariate statistical analyses revealed that Cu, Zn, and Pb in the soils originated from the deposited waste materials as well as traffic-related activities (e.g. wear and tear of tyres, brakes, and engines) at the site. Hg also originated from the deposited waste materials as well as cement production and oil and coal combustion activities in the study area, while As derived from industrial discharges and metal smelting activities. All the zones exhibited very high ecological risk. The carcinogenic and non-carcinogenic health risks posed by the HMs were also above acceptable levels, with children being more vulnerable than adults to these health risks.
    MeSH term(s) Adult ; Child ; China ; Environmental Monitoring ; Ghana ; Humans ; Metals, Heavy/analysis ; Risk Assessment ; Soil ; Soil Pollutants/analysis ; Waste Disposal Facilities
    Chemical Substances Metals, Heavy ; Soil ; Soil Pollutants
    Language English
    Publishing date 2021-05-28
    Publishing country England
    Document type Journal Article
    ZDB-ID 120089-6
    ISSN 1879-1298 ; 0045-6535 ; 0366-7111
    ISSN (online) 1879-1298
    ISSN 0045-6535 ; 0366-7111
    DOI 10.1016/j.chemosphere.2021.131007
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Geophysical borehole logging for control of driller’s records: hydrogeological case study from Voltaian sedimentary rocks in northern Ghana

    Agyekum, William / Kurt Klitten / Thomas Armah / Bruce Banoeng-Yakubo / Edmund Okoe Amartey

    Appl Water Sci. 2013 June, v. 3, no. 2

    2013  

    Abstract: The low borehole yielding potential and the high drilling failure rate of the Voltaian sedimentary rocks of Northern Ghana have been of concern to many local hydrogeologists and international donors. Consequently, several donor-supported projects have ... ...

    Abstract The low borehole yielding potential and the high drilling failure rate of the Voltaian sedimentary rocks of Northern Ghana have been of concern to many local hydrogeologists and international donors. Consequently, several donor-supported projects have been instituted within the last few years with the view to study the hydrogeological characteristics of this ‘difficult’ rock system. One such project is the geophysical borehole logging of 13 boreholes drilled into the Voltaian sedimentary rocks of Northern Ghana to enhance detailed hydrogeological assessment. Natural gamma detectors embedded in the five exploratory logging tools employed for the study ensured depth control by comparing their individual gamma log signatures. The combined gamma and formation resistivity/conductivity response logs provided more detailed lithological information than were shown in the driller’s/geologist’s logs. Significant discrepancies between the logging results and the reported drilled depths, construction depths, and screen settings were observed in seven of the thirteen investigated boreholes. Thus, the reliability of driller’s borehole records seems questionable, which will hamper hydrogeological studies and the mapping of groundwater resources. Further, it may be supposed that the productivity of most wells in Ghana is compromised by poor depth control of screen placement.
    Keywords case studies ; detectors ; drilling ; geophysics ; groundwater ; logging ; sedimentary rocks ; wells ; Ghana
    Language English
    Dates of publication 2013-06
    Size p. 491-500.
    Publishing place Springer Berlin Heidelberg
    Document type Article
    ZDB-ID 2594789-8
    ISSN 2190-5495 ; 2190-5487
    ISSN (online) 2190-5495
    ISSN 2190-5487
    DOI 10.1007/s13201-013-0097-y
    Database NAL-Catalogue (AGRICOLA)

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  3. Article ; Online: Multi-trace element levels and arsenic speciation in urine of e-waste recycling workers from Agbogbloshie, Accra in Ghana.

    Asante, Kwadwo Ansong / Agusa, Tetsuro / Biney, Charles Augustus / Agyekum, William Atuobi / Bello, Mohammed / Otsuka, Masanari / Itai, Takaaki / Takahashi, Shin / Tanabe, Shinsuke

    The Science of the total environment

    2012  Volume 424, Page(s) 63–73

    Abstract: To understand human contamination by multi-trace elements (TEs) in electrical and electronic waste (e-waste) recycling site at Agbogbloshie, Accra in Ghana, this study analyzed TEs and As speciation in urine of e-waste recycling workers. Concentrations ... ...

    Abstract To understand human contamination by multi-trace elements (TEs) in electrical and electronic waste (e-waste) recycling site at Agbogbloshie, Accra in Ghana, this study analyzed TEs and As speciation in urine of e-waste recycling workers. Concentrations of Fe, Sb, and Pb in urine of e-waste recycling workers were significantly higher than those of reference sites after consideration of interaction by age, indicating that the recycling workers are exposed to these TEs through the recycling activity. Urinary As concentration was relatively high, although the level in drinking water was quite low. Speciation analysis of As in human urine revealed that arsenobetaine and dimethylarsinic acid were the predominant As species and concentrations of both species were positively correlated with total As concentration as well as between each other. These results suggest that such compounds may be derived from the same source, probably fish and shellfish and greatly influence As exposure levels. To our knowledge, this is the first study on human contamination resulting from the primitive recycling of e-waste in Ghana. This study will contribute to the knowledge about human exposure to trace elements from an e-waste site in a less industrialized region so far scantly covered in the literature.
    MeSH term(s) Adolescent ; Adult ; Aged, 80 and over ; Arsenic/chemistry ; Arsenic/urine ; Arsenicals/chemistry ; Arsenicals/urine ; Chromatography, High Pressure Liquid ; Drinking Water/analysis ; Drinking Water/chemistry ; Electronic Waste/adverse effects ; Environmental Monitoring ; Female ; Ghana ; Humans ; Male ; Mass Spectrometry ; Metals/chemistry ; Metals/urine ; Middle Aged ; Occupational Exposure ; Recycling ; Spectrophotometry, Atomic ; Trace Elements/chemistry ; Trace Elements/urine ; Water Quality
    Chemical Substances Arsenicals ; Drinking Water ; Metals ; Trace Elements ; Arsenic (N712M78A8G)
    Language English
    Publishing date 2012-05-01
    Publishing country Netherlands
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2012.02.072
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Author Correction: Observed controls on resilience of groundwater to climate variability in sub-Saharan Africa.

    Cuthbert, Mark O / Taylor, Richard G / Favreau, Guillaume / Todd, Martin C / Shamsudduha, Mohammad / Villholth, Karen G / MacDonald, Alan M / Scanlon, Bridget R / Kotchoni, D O Valerie / Vouillamoz, Jean-Michel / Lawson, Fabrice M A / Adjomayi, Philippe Armand / Kashaigili, Japhet / Seddon, David / Sorensen, James P R / Ebrahim, Girma Yimer / Owor, Michael / Nyenje, Philip M / Nazoumou, Yahaya /
    Goni, Ibrahim / Ousmane, Boukari Issoufou / Sibanda, Tenant / Ascott, Matthew J / Macdonald, David M J / Agyekum, William / Koussoubé, Youssouf / Wanke, Heike / Kim, Hyungjun / Wada, Yoshihide / Lo, Min-Hui / Oki, Taikan / Kukuric, Neno

    Nature

    2020  Volume 588, Issue 7838, Page(s) E25

    Language English
    Publishing date 2020-12-02
    Publishing country England
    Document type Published Erratum
    ZDB-ID 120714-3
    ISSN 1476-4687 ; 0028-0836
    ISSN (online) 1476-4687
    ISSN 0028-0836
    DOI 10.1038/s41586-020-2985-2
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article: Multi-trace element levels and arsenic speciation in urine of e-waste recycling workers from Agbogbloshie, Accra in Ghana

    Asante, Kwadwo Ansong / Agusa, Tetsuro / Biney, Charles Augustus / Agyekum, William Atuobi / Bello, Mohammed / Otsuka, Masanari / Itai, Takaaki / Takahashi, Shin / Tanabe, Shinsuke

    science of the total environment. 2012 May 1, v. 424

    2012  

    Abstract: To understand human contamination by multi-trace elements (TEs) in electrical and electronic waste (e-waste) recycling site at Agbogbloshie, Accra in Ghana, this study analyzed TEs and As speciation in urine of e-waste recycling workers. Concentrations ... ...

    Abstract To understand human contamination by multi-trace elements (TEs) in electrical and electronic waste (e-waste) recycling site at Agbogbloshie, Accra in Ghana, this study analyzed TEs and As speciation in urine of e-waste recycling workers. Concentrations of Fe, Sb, and Pb in urine of e-waste recycling workers were significantly higher than those of reference sites after consideration of interaction by age, indicating that the recycling workers are exposed to these TEs through the recycling activity. Urinary As concentration was relatively high, although the level in drinking water was quite low. Speciation analysis of As in human urine revealed that arsenobetaine and dimethylarsinic acid were the predominant As species and concentrations of both species were positively correlated with total As concentration as well as between each other. These results suggest that such compounds may be derived from the same source, probably fish and shellfish and greatly influence As exposure levels. To our knowledge, this is the first study on human contamination resulting from the primitive recycling of e-waste in Ghana. This study will contribute to the knowledge about human exposure to trace elements from an e-waste site in a less industrialized region so far scantly covered in the literature.
    Keywords arsenic ; cacodylic acid ; drinking water ; fish ; labor ; recycling ; shellfish ; speciation ; urinalysis ; urine ; wastes ; Ghana
    Language English
    Dates of publication 2012-0501
    Size p. 63-73.
    Publishing place Elsevier B.V.
    Document type Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2012.02.072
    Database NAL-Catalogue (AGRICOLA)

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  6. Article ; Online: Observed controls on resilience of groundwater to climate variability in sub-Saharan Africa.

    Cuthbert, Mark O / Taylor, Richard G / Favreau, Guillaume / Todd, Martin C / Shamsudduha, Mohammad / Villholth, Karen G / MacDonald, Alan M / Scanlon, Bridget R / Kotchoni, D O Valerie / Vouillamoz, Jean-Michel / Lawson, Fabrice M A / Adjomayi, Philippe Armand / Kashaigili, Japhet / Seddon, David / Sorensen, James P R / Ebrahim, Girma Yimer / Owor, Michael / Nyenje, Philip M / Nazoumou, Yahaya /
    Goni, Ibrahim / Ousmane, Boukari Issoufou / Sibanda, Tenant / Ascott, Matthew J / Macdonald, David M J / Agyekum, William / Koussoubé, Youssouf / Wanke, Heike / Kim, Hyungjun / Wada, Yoshihide / Lo, Min-Hui / Oki, Taikan / Kukuric, Neno

    Nature

    2019  Volume 572, Issue 7768, Page(s) 230–234

    Abstract: Groundwater in sub-Saharan Africa supports livelihoods and poverty ... ...

    Abstract Groundwater in sub-Saharan Africa supports livelihoods and poverty alleviation
    MeSH term(s) Africa South of the Sahara ; Desert Climate ; Droughts/statistics & numerical data ; Groundwater/analysis ; Rain
    Language English
    Publishing date 2019-08-07
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 120714-3
    ISSN 1476-4687 ; 0028-0836
    ISSN (online) 1476-4687
    ISSN 0028-0836
    DOI 10.1038/s41586-019-1441-7
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Observed controls on resilience of groundwater to climate variability in sub-Saharan Africa

    Cuthbert, Mark O. / Taylor, Richard G. / Favreau, Guillaume / Todd, Martin C. / Shamsudduha, Mohammad / Villholth, Karen G. / MacDonald, Alan M. / Scanlon, Bridget R. / Kotchoni, D.O. Valerie / Vouillamoz, Jean-Michel / Lawson, Fabrice M.A. / Adjomayi, Philippe Armand / Kashaigili, Japhet J. / Seddon, David / Sorensen, James P. R. / Ebrahim, Girma Yimer / Owor, Michael / Nyenje, Philip M. / Nazoumou, Yahaya /
    Goni, Ibrahim / Ousmane, Boukari Issoufou / Sibanda, Tenant / Ascott, Matthew J. / Macdonald, David M.J. / Agyekum, William / Koussoubé, Youssouf / Wanke, Heike / Kim, Hyungjun / Wada, Yoshihide / Lo, Min-Hui / Oki, Taikan / Kukuric, Neno

    Nature

    2019  

    Abstract: Groundwater in sub-Saharan Africa supports livelihoods and poverty alleviation1,2, maintains vital ecosystems, and strongly influences terrestrial water and energy budgets3. Yet the hydrological processes that govern groundwater recharge and ... ...

    Abstract Groundwater in sub-Saharan Africa supports livelihoods and poverty alleviation1,2, maintains vital ecosystems, and strongly influences terrestrial water and energy budgets3. Yet the hydrological processes that govern groundwater recharge and sustainability—and their sensitivity to climatic variability—are poorly constrained4,5. Given the absence of firm observational constraints, it remains to be seen whether model-based projections of decreased water resources in dry parts of the region4 are justified. Here we show, through analysis of multidecadal groundwater hydrographs across sub-Saharan Africa, that levels of aridity dictate the predominant recharge processes, whereas local hydrogeology influences the type and sensitivity of precipitation–recharge relationships. Recharge in some humid locations varies by as little as five per cent (by coefficient of variation) across a wide range of annual precipitation values. Other regions, by contrast, show roughly linear precipitation–recharge relationships, with precipitation thresholds (of roughly ten millimetres or less per day) governing the initiation of recharge. These thresholds tend to rise as aridity increases, and recharge in drylands is more episodic and increasingly dominated by focused recharge through losses from ephemeral overland flows. Extreme annual recharge is commonly associated with intense rainfall and flooding events, themselves often driven by large-scale climate controls. Intense precipitation, even during years of lower overall precipitation, produces some of the largest years of recharge in some dry subtropical locations. Our results therefore challenge the ‘high certainty’ consensus regarding decreasing water resources4 in such regions of sub-Saharan Africa. The potential resilience of groundwater to climate variability in many areas that is revealed by these precipitation–recharge relationships is essential for informing reliable predictions of climate-change impacts and adaptation strategies.
    Language English
    Publishing date 2019-08-16T13:22:19Z
    Publisher Springer
    Publishing country fr
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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