Article: Darstellung und Charakterisierung von Spezies der Zusammensetzung η5-C5H5Cr(NO)2SR (R = C6H5, C6F5, t–C4H9) und [η5-C5H5CrNO]2(ER)2 (E = O, S, Se, Te, R = Alkyl, Aryl); Röntgenstrukturanalysen von [η5-C5H5(NO)Cr(μ-SeC6H5)2Cr(NO)-η5-C5H5] und [η5-C5H5(NO)Cr(μ-Se-n-C4H9)(μ-OH)Cr(NO)-η5-C5H5] / Synthesis and Characterization of Species of Composition η5-C5H5Cr(NO)2SR (R = C6H5, C6F5, t-C4H9) and [η5-C5H5CrNO]2(ER)2 (E = O, S, Se, Te, R = Alkyl, Aryl); Röntgenstrukturanalysen von [η5-C5H5(NO)Cr(μ-SeC6H5)2Cr(NO)-η5-C5H5] and [η5-C5H5(NO)Cr(μ-Se-n-C4H9)(μ-OH)Cr(NO)-η5-C5H5]
Zeitschrift für Naturforschung. 2014 June 2, v. 37, no. 1
2014
Abstract: The title compounds have been synthesized and characterized by elemental analysis, IR and ¹H NMR methods and mass spectra. The crystal and molecular structures of the binuclear complexes [η-C₅H₅(NO)Cr(μ-SeC₆H₅)₂Cr(NO)-η⁵-C₅H₅] and [η⁵-C₅H₅(NO)Crμ-Se-n-C₄ ... ...
| Abstract | The title compounds have been synthesized and characterized by elemental analysis, IR and ¹H NMR methods and mass spectra. The crystal and molecular structures of the binuclear complexes [η-C₅H₅(NO)Cr(μ-SeC₆H₅)₂Cr(NO)-η⁵-C₅H₅] and [η⁵-C₅H₅(NO)Crμ-Se-n-C₄H₉)(μ-OH)Cr(NO)-μ⁵-C₅H₅] have been determined by X-ray structure analysis. The latter is shown to have a four-membered ring consisting of two chromium atoms, one selenium, and one oxygen atom. |
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| Keywords | X-radiation ; chromium ; nitric oxide ; nuclear magnetic resonance spectroscopy ; oxygen ; selenium ; sulfur | ||||||||||
| Language | English | ||||||||||
| Dates of publication | 2014-0602 | ||||||||||
| Size | p. 13-23. | ||||||||||
| Publishing place | Verlag der Zeitschrift für Naturforschung | ||||||||||
| Document type | Article | ||||||||||
| ZDB-ID | 124635-5 | ||||||||||
| ISSN | 0340-5087 ; 0044-3174 ; 0932-0776 ; 0341-0447 ; 0341-0420 | ||||||||||
| ISSN | 0340-5087 ; 0044-3174 ; 0932-0776 ; 0341-0447 ; 0341-0420 | ||||||||||
| DOI | 10.1515/znb-1982-0104 | ||||||||||
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| Database | NAL-Catalogue (AGRICOLA) |
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