LIVIVO - The Search Portal for Life Sciences

zur deutschen Oberfläche wechseln
Advanced search

Search results

Result 1 - 3 of total 3

Search options

  1. Article: Recent advances in the catalytic transfer hydrogenation of furfural to furfuryl alcohol over heterogeneous catalysts

    An, Zhidong / Li, Jiang

    Green chemistry. 2022 Mar. 7, v. 24, no. 5

    2022  

    Abstract: Catalytic transfer hydrogenation (CTH) has recently emerged as a highly attractive approach for achieving biomass-based hydrogenation due to its avoidance of high-pressure fossil-derived H₂ and potentially reduced process costs. As numerous studies ... ...

    Abstract Catalytic transfer hydrogenation (CTH) has recently emerged as a highly attractive approach for achieving biomass-based hydrogenation due to its avoidance of high-pressure fossil-derived H₂ and potentially reduced process costs. As numerous studies relating to the CTH of furfural (FF) have been reported recently, it is quite urgent to systematically review the recent advances, especially those in which excellent catalytic performance is achieved over simple solid acid–base catalysts. In this review, recent advances relating to the CTH of FF over heterogeneous catalysts, including metal catalysts and solid acid–base catalysts, are extensively summarized. Some potential research trends for the design of more effective catalysts and the realization of the practical industrial production of furfuryl alcohol (FFA) via CTH are also proposed. As acidic or basic sites always play an important role during biomass conversion, the great progress made in the area of CTH also provides great potential for other reactions, especially reductive functionalization.
    Keywords biomass ; catalytic activity ; furfural ; furfuryl alcohol ; green chemistry ; hydrogenation
    Language English
    Dates of publication 2022-0307
    Size p. 1780-1808.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ZDB-ID 2006274-6
    ISSN 1463-9270 ; 1463-9262
    ISSN (online) 1463-9270
    ISSN 1463-9262
    DOI 10.1039/d1gc04440k
    Database NAL-Catalogue (AGRICOLA)

    More links

    Kategorien

    Order via subito

    This service is chargeable due to the Delivery terms set by subito. Orders including an article and supplementary material will be classified as separate orders. In these cases, fees will be demanded for each order.

  2. Article ; Online: Highly active, ultra-low loading single-atom iron catalysts for catalytic transfer hydrogenation.

    An, Zhidong / Yang, Piaoping / Duan, Delong / Li, Jiang / Wan, Tong / Kong, Yue / Caratzoulas, Stavros / Xiang, Shuting / Liu, Jiaxing / Huang, Lei / Frenkel, Anatoly I / Jiang, Yuan-Ye / Long, Ran / Li, Zhenxing / Vlachos, Dionisios G

    Nature communications

    2023  Volume 14, Issue 1, Page(s) 6666

    Abstract: Highly effective and selective noble metal-free catalysts attract significant attention. Here, a single-atom iron catalyst is fabricated by saturated adsorption of trace iron onto zeolitic imidazolate framework-8 (ZIF-8) followed by pyrolysis. Its ... ...

    Abstract Highly effective and selective noble metal-free catalysts attract significant attention. Here, a single-atom iron catalyst is fabricated by saturated adsorption of trace iron onto zeolitic imidazolate framework-8 (ZIF-8) followed by pyrolysis. Its performance toward catalytic transfer hydrogenation of furfural is comparable to state-of-the-art catalysts and up to four orders higher than other Fe catalysts. Isotopic labeling experiments demonstrate an intermolecular hydride transfer mechanism. First principles simulations, spectroscopic calculations and experiments, and kinetic correlations reveal that the synthesis creates pyrrolic Fe(II)-plN
    Language English
    Publishing date 2023-10-20
    Publishing country England
    Document type Journal Article
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-023-42337-9
    Database MEDical Literature Analysis and Retrieval System OnLINE

    More links

    Kategorien

    Order via subito

    This service is chargeable due to the Delivery terms set by subito. Orders including an article and supplementary material will be classified as separate orders. In these cases, fees will be demanded for each order.

  3. Article: Influence of Bacillus subtilis phoR on cell wall anionic polymers.

    Müler, Jörg P / An, Zhidong / Merad, Tarek / Hancock, Ian C / Harwood, Colin R

    Microbiology (Reading, England)

    1997  Volume 143 Pt 3, Page(s) 947–956

    Abstract: In Bacillus subtilis the Pho regulon is controlled by a sensor and regulator protein pair, PhoR and PhoP, that respond to phosphate concentrations. To facilitate studies of the Pho regulon, a strain with an altered PhoR protein was isolated by in vitro ... ...

    Abstract In Bacillus subtilis the Pho regulon is controlled by a sensor and regulator protein pair, PhoR and PhoP, that respond to phosphate concentrations. To facilitate studies of the Pho regulon, a strain with an altered PhoR protein was isolated by in vitro mutagenesis. The mutation in this strain (phoR12) leads to the production of a PhoR sensor kinase that, unlike the wild-type, is functionally active in phosphate-replete conditions. The lesion in PhoR12 was shown to be a single base change that results in an Arg to Ser substitution in a region of PhoR that is highly conserved in histidine sensor kinases. While a phoR-negative mutant was unable to induce the synthesis of cell wall teichuronic acid under phosphate-limited conditions, the phoR12 mutant showed a relative increase in teichuronic acid and a decrease in teichoic acid, even under phosphate-replete conditions. The latter suggests that some or all of the genes required for teichuronic acid synthesis are members of the Pho regulon.
    MeSH term(s) Amino Acid Sequence ; Anions ; Bacillus subtilis/genetics ; Bacillus subtilis/metabolism ; Bacterial Proteins/genetics ; Bacterial Proteins/metabolism ; Cell Wall/metabolism ; Gene Expression Regulation, Bacterial ; Molecular Sequence Data ; Mutation ; Polymers/metabolism ; Sequence Alignment
    Chemical Substances Anions ; Bacterial Proteins ; Polymers ; PhoB protein, Bacteria (104220-36-2)
    Language English
    Publishing date 1997-03
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 1180712-x
    ISSN 1465-2080 ; 1350-0872
    ISSN (online) 1465-2080
    ISSN 1350-0872
    DOI 10.1099/00221287-143-3-947
    Database MEDical Literature Analysis and Retrieval System OnLINE

    More links

    Kategorien

    In stock of ZB MED Cologne/Königswinter

    Ud II Zs.140: Show issues Location:
    Je nach Verfügbarkeit (siehe Angabe bei Bestand)
    bis Jg. 2021: Bestellungen von Artikeln über das Online-Bestellformular
    ab Jg. 2022: Lesesaal (EG)

    Order via subito

    This service is chargeable due to the Delivery terms set by subito. Orders including an article and supplementary material will be classified as separate orders. In these cases, fees will be demanded for each order.

To top