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Article ; Online: Mononuclear or Coordination Polymer Complexes? Both Are Possible for 3,6,9-Trioxaundecanedioic Acid

Giovanni Bella / Jan Holub / Giuseppe Bruno / Francesco Nicolò / Antonio Santoro

Molecules, Vol 28, Iss 21, p

2023 Volume 7410

Abstract: Investigating the driving forces leading to the formation of a specific supramolecular architecture among a wide spectrum of all the possibly obtainable structures is not an easy task. The contemporary literature provides several models for correctly ... ...

Abstract	Investigating the driving forces leading to the formation of a specific supramolecular architecture among a wide spectrum of all the possibly obtainable structures is not an easy task. The contemporary literature provides several models for correctly predicting the thermodynamically accessible structures that can originate from a library of building blocks. Definitions are rigid by their very nature, so their application may sometimes require a shift in perspective. In the study presented herein, we describe the crystal structures of three metallo-supramolecular architectures assembled from deprotonated derivatives of 3,6,9-trioxaundecanedioic acid and Mn(II), Co(II) and Zn(II). In the Mn(II) case, the complexation resulted in a complex of a discrete/heptacoordinated nature, whereas the other two structures appeared as helical polymers. To explain such an anomaly, in this work, we describe how the interplay between the flexibility of the ligand spacer and the number of coordinating atoms involved determines the divergent or convergent organisation of the final coordination architecture.
Keywords	supramolecular chemistry ; self-assembly ; polymers ; metal complexes ; Organic chemistry ; QD241-441
Subject code	540
Language	English
Publishing date	2023-11-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Cure dialitiche domiciliari. Una frontiera da raggiungere, senza trascurare le criticità

Giuseppe Vanacore / Antonio Santoro

Giornale di Clinica Nefrologia e Dialisi, Vol 32, Iss

2020 Volume 1

Abstract: The National Plan of Chronicity, approved by the Italian State-Regions Conference, refers to the topic of home care, specifying how the fundamental objective of chronic care systems is to keep the sick person at home as much as possible. Currently, home ... ...

Abstract	The National Plan of Chronicity, approved by the Italian State-Regions Conference, refers to the topic of home care, specifying how the fundamental objective of chronic care systems is to keep the sick person at home as much as possible. Currently, home dialysis – both peritoneal and haemodialysis – uses high-quality safe technology systems and allows patients to perform therapy safely at home. ANED wishes to stress that the choice of dialysis treatment, which certainly depends on clinical evaluations, must at the same time consider the psychological and emotional aspects of the patient, the expectations and needs of his life and the social context, aiming at an increasingly personalized and sustainable therapy for patients and the healthcare system.
Keywords	Chronic kidney disease ; Home care ; Home dialysis ; Peritoneal dialysis ; Internal medicine ; RC31-1245 ; Diseases of the genitourinary system. Urology ; RC870-923
Subject code	360
Language	Italian
Publishing date	2020-12-01T00:00:00Z
Publisher	AboutScience Srl
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Intermolecular Forces Driving Hexamethylenetetramine Co-Crystal Formation, a DFT and XRD Analysis

Giovanni Bella / Francesco Nicolò / Giuseppe Bruno / Antonio Santoro

Molecules, Vol 26, Iss 5746, p

2021 Volume 5746

Abstract: Interest in co-crystals formation has been constantly growing since their discovery, almost a century ago. Such success is due to the ability to tune the physical-chemical properties of the components in solid state by avoiding a change in their ... ...

Abstract	Interest in co-crystals formation has been constantly growing since their discovery, almost a century ago. Such success is due to the ability to tune the physical-chemical properties of the components in solid state by avoiding a change in their molecular structure. The properties influenced by the co-crystals formation range from an improvement of mechanical features and chemical stability to different solubility. In the scientific research area, the pharmacological field is undoubtedly one of those in which an expansion of the co-crystal knowledge can offer wide benefits. In this work, we described the crystalline structure of hexamethylenetetramine co-crystallized with the isophthalic acid, and we compared it with another co-crystal, showing the same components but different stoichiometry. To give a wider overview on the nature of the interactions behind the observed crystal packing and to rationalize the reasons of its formation, a computational analysis on such structures was carried out.
Keywords	hexamethylenetetramine ; co-crystals ; SCXRD ; DFT analysis ; Organic chemistry ; QD241-441
Subject code	540
Language	English
Publishing date	2021-09-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Landscape Perception and Public Participation for the Conservation and Valorization of Cultural Landscapes

Antonio Santoro / Martina Venturi / Mauro Agnoletti

Land, Vol 10, Iss 2, p

The Case of the Cinque Terre and Porto Venere UNESCO Site

2021 Volume 93

Abstract: Europe retains a great variety of cultural landscapes that constitute a significant part of the European cultural heritage. In the last decades, these high-quality landscapes are facing several challenges due to socio-economic transformations that often ... ...

Abstract	Europe retains a great variety of cultural landscapes that constitute a significant part of the European cultural heritage. In the last decades, these high-quality landscapes are facing several challenges due to socio-economic transformations that often compromise their integrity. This situation is even worse for terraced landscapes, as in the case of the Porto Venere and Cinque Terre UNESCO World Heritage List site. The Management Plan developed for this area needs to deal with different issues: abandonment of terraced cultivations and growth of secondary forests, hydrogeological risk and high touristic pressure. Public participation is increasingly important in the process of decision-making, for incorporating the ideas and the needs of the local communities, helping to find effective solutions for the valorization of historic landscapes and for improving the quality of life. This research has investigated the perception of the local community regarding the current landscape dynamics and other critical issues studying the opinions of two social groups: farmers and residents. The purpose was to identify the best management strategies for the Management Plan and to actively involve the population in the decisions. The involvement of the local community turned out to be a very effective tool for the development of the Management Plan, suggesting a focus on the conservation of dry-stone terraces and the reduction of reforestation processes, as the strongest perceived threat is the abandonment of cultivated terraces and the resulting risk of landslides. The methodology applied in this study can be reproduced in other cultural landscapes characterized by high quality, complexity and fragility, while an active involvement of the population turned out to be important also for increasing the feeling that institutions take care of its issues.
Keywords	landscape dynamics ; forests ; public perception ; historical landscapes ; agricultural heritage ; UNESCO WHL ; Agriculture ; S
Subject code	710
Language	English
Publishing date	2021-01-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Rural Landscape Planning and Forest Management in Tuscany (Italy)

Mauro Agnoletti / Antonio Santoro

Forests, Vol 9, Iss 8, p

2018 Volume 473

Abstract: The article analyzes the relationships between landscape planning and forests in Italy with a specific focus on Tuscany. For the Tuscan region landscape represents a fundamental value from the cultural, economic, environmental and social point of view. ... ...

Abstract	The article analyzes the relationships between landscape planning and forests in Italy with a specific focus on Tuscany. For the Tuscan region landscape represents a fundamental value from the cultural, economic, environmental and social point of view. This is why it was the first region of Italy to develop a landscape plan in 2014, according to the National Code for Cultural Heritage, setting up a Landscape Observatory to monitor the application of the plan in 2016. The plan is the main instrument providing a vision for the development model of the region and guidelines for the planning of rural areas also affecting forest management. The construction of the plan has caused an intense debate, due to the strict limitations imposed to soil consumption, to agricultural and forest activities. Forests cover more than the half of the regional surface, but 30% of them is the result of the abandonment of farmed land occurred in the last decades, while 50% of the forests are currently managed. The article examines how the values connected to the forests have been identified an assessed in the plan, the strict limitations for their protection but also the decision to allow the restoration of farmed land to maintain a balance between farmed and forest land in the landscape. Landscape and forest is the topic of the chapter about Italy in the FAO SOFO 2018.
Keywords	landscape planning ; sustainable forest management ; historical rural landscapes ; Plant ecology ; QK900-989
Subject code	710
Language	English
Publishing date	2018-08-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Agricultural Heritage Systems and Landscape Perception among Tourists. The Case of Lamole, Chianti (Italy)

Antonio Santoro / Martina Venturi / Mauro Agnoletti

Sustainability, Vol 12, Iss 3509, p

2020 Volume 3509

Abstract: The Global Important Agricultural Heritage Systems (GIAHS) program, promoted by the Food and Agriculture Organization (FAO), recognizes the multifunctional role of agricultural heritage systems. Traditional terraced landscapes represent important ... ...

Abstract	The Global Important Agricultural Heritage Systems (GIAHS) program, promoted by the Food and Agriculture Organization (FAO), recognizes the multifunctional role of agricultural heritage systems. Traditional terraced landscapes represent important touristic destinations, and Chianti is one of the most well-known areas of Italy for rural tourism. The high-quality landscape of Lamole, consisting of forests and terraced agricultural areas, is included in the Italian National Register of Historical Rural Landscapes thanks to local farmers who recently restored the traditional landscape, considering it important both for tourism and product quality. The main aim of this research was to investigate, using anonymous questionnaires, whether tourists are aware of the characteristics of the Lamole landscape in comparison with other parts of Chianti. Results show that tourists clearly express their preference for the traditional landscape, which is comprised of a mosaic of agricultural patches with dry-stone terraces and forests, and that the level of landscape diversification is similar to 180 years ago. As tourism is a major resource, public institutions should support farmers in preserving the traditional landscape, investing in paths and information, as requested by tourists. The methodology has proved to be useful for addressing local planning, and to help farmers to achieve sustainable development in well-known touristic rural areas.
Keywords	terraced landscape ; agricultural heritage ; GIAHS ; landscape perception ; rural tourism ; Tuscany ; Environmental effects of industries and plants ; TD194-195 ; Renewable energy sources ; TJ807-830 ; Environmental sciences ; GE1-350
Subject code	710 ; 910
Language	English
Publishing date	2020-04-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: A Review of the Role of Forests and Agroforestry Systems in the FAO Globally Important Agricultural Heritage Systems (GIAHS) Programme

Antonio Santoro / Martina Venturi / Remo Bertani / Mauro Agnoletti

Forests, Vol 11, Iss 860, p

2020 Volume 860

Abstract: Traditional agroforestry systems have received increasing attention in recent decades for their multifunctional role and as a sustainable development model for rural areas. At the international level, the Food and Agriculture Organization (FAO) launched ... ...

Abstract	Traditional agroforestry systems have received increasing attention in recent decades for their multifunctional role and as a sustainable development model for rural areas. At the international level, the Food and Agriculture Organization (FAO) launched the Globally Important Agricultural Heritage Systems (GIAHS) programme in 2002 with the aim of identifying agricultural systems of global importance; preserving landscapes, agrobiodiversity and traditional knowledge; applying the dynamic conservation principles while promoting sustainable development. The aim of the research is to carry out a review of the inscription dossiers of all the 59 sites already included in the GIAHS programme, in order to analyze the role of forests and agroforestry systems. Moreover, the main traditional management techniques have been identified and briefly described, as traditional forest-related knowledge is particularly important for sustainable forest management. Forests and agroforestry systems have been found to be important or crucial in about half of the sites. The main role assigned to forests and agroforestry systems in GIAHS proposals is related to the production of timber, fuelwood and by-products for the local communities according to sustainable and traditional management techniques. Among these, they also play important roles in hydrogeological protection, water regulation and biodiversity maintenance, representing examples both of human adaptation to different environments and of resilient systems that could help to face global challenges such as hydrogeological risk and climate change. The review of the GIAHS inscription dossiers also highlighted the lack of a uniform approach in dealing with forest issues, especially for what concern the description of management plans and the relation with protected areas or forest planning instruments.
Keywords	agricultural heritage ; agroforestry ; FAO ; GIAHS ; rural landscape ; sustainable forest management ; Plant ecology ; QK900-989
Subject code	333
Language	English
Publishing date	2020-08-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Forest Surface Changes and Cultural Values

Francesco Piras / Martina Venturi / Federica Corrieri / Antonio Santoro / Mauro Agnoletti

Forests, Vol 12, Iss 531, p

The Forests of Tuscany (Italy) in the Last Century

2021 Volume 531

Abstract: Despite the definition of social and cultural values as the third pillar of Sustainable Forest Management (SFM) in 2003 and the guidelines for their implementation in SFM in 2007 issued by the Ministerial Conference on the Protection of Forest in Europe ( ...

Abstract	Despite the definition of social and cultural values as the third pillar of Sustainable Forest Management (SFM) in 2003 and the guidelines for their implementation in SFM in 2007 issued by the Ministerial Conference on the Protection of Forest in Europe (MCPFE), the importance of cultural values is not sufficiently transferred into forest planning and conservation. Tuscany is widely known for the quality of its cultural landscape, however, the abandonment of agro-pastoral surfaces as a consequence of rural areas depopulation, has led to widespread reforestation and to the abandonment of forest management. In addition, due to the interruption of a regular forest management and to the fact that most of the population lives in cities, forests are no more perceived as part of the cultural heritage, but mainly as a natural landscape. Due to this trend traditional forest management techniques, such as coppicing, have also been considered as a factor of degradation and not even a historical management form. The aim of the study is therefore to analyze forest surface changes in Tuscany in the last century to assess the importance of cultural values. Results highlighted that already in 1881 most of forests were regularly managed and that in 1936 more than 76% of broadleaved forests were managed as coppice. Between 1936 and 2016 forests increased their surface from 876,518 to 1,161,383 hectares due to the abandonment of the countryside, and 30% of the forests currently included in protected areas are the result of secondary successions. The findings of this study suggest the revision of national forest policies and, more in general, the adaptation of forest strategies to local conditions.
Keywords	forest planning ; forest management ; cultural landscape ; cultural forests ; sustainable forest management ; Plant ecology ; QK900-989
Subject code	710
Language	English
Publishing date	2021-04-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: The Role of Trees Outside Forests in the Cultural Landscape of the Colline del Prosecco UNESCO Site

Antonio Santoro / Francesco Piras / Beatrice Fiore / Niccolò Frassinelli / Alessandra Bazzurro / Mauro Agnoletti

Forests, Vol 13, Iss 514, p

2022 Volume 514

Abstract: The multifunctional role of Trees Outside Forests (TOF) is largely recognized in scientific literature, but they are still rarely considered in forest inventories and planning, with consequent underestimation of their role and amount. In addition, their ... ...

Abstract	The multifunctional role of Trees Outside Forests (TOF) is largely recognized in scientific literature, but they are still rarely considered in forest inventories and planning, with consequent underestimation of their role and amount. In addition, their cultural role has rarely been considered both at scientific and management level as well as in UNESCO sites. TOF characterize many European cultural landscapes, including the one of the Colline del Prosecco, inscribed in 2019 in the UNESCO World Heritage List. One of the reasons of the inclusion, in fact, is the landscape mosaic made of vineyards interspersed with small woodlands and tree rows. This paper focuses on two types of TOF, Small Woods and Linear Tree Formations (TOF NON A/U). Their detailed mapping and the performing of different spatial analysis allowed us to assess their role and to provide data for future monitoring and for local forest planning. Results confirmed that TOF NON A/U are one of the main features of the UNESCO site landscape: despite the limited overall surface (1.95% of the area), 931 different patches have been identified. Spatial analysis highlighted the key landscape and ecological roles, acting as intermediate features between large forest patches, and also an important role for hydrological protection (they can be found also in slopes above 80% of inclination). The study provided a detailed mapping and database of one of the main features of the Colline del Prosecco UNESCO site cultural landscape, verifying the multifunctional role of TOF NON A/U and the necessity to include them into local forest planning, but also suggesting their inclusion in national forest inventories.
Keywords	trees outside forest ; forest management ; forest planning ; cultural landscape ; cultural forests ; UNESCO ; Plant ecology ; QK900-989
Subject code	710
Language	English
Publishing date	2022-03-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: Photoinduced Electron Transfer in Organized Assemblies—Case Studies

Antonio Santoro / Giovanni Bella / Ambra M. Cancelliere / Scolastica Serroni / Giuliana Lazzaro / Sebastiano Campagna

Molecules, Vol 27, Iss 2713, p

2022 Volume 2713

Abstract: In this review, photoinduced electron transfer processes in specifically designed assembled architectures have been discussed in the light of recent results reported from our laboratories. A convenient and useful way to study these systems is described ... ...

Abstract	In this review, photoinduced electron transfer processes in specifically designed assembled architectures have been discussed in the light of recent results reported from our laboratories. A convenient and useful way to study these systems is described to understand the rules that drive a light-induced charge-separated states and its subsequent decay to the ground state, also with the aim of offering a tutorial for young researchers. Assembled systems of covalent or supramolecular nature have been presented, and some functional multicomponent systems for the conversion of light energy into chemical energy have been discussed.
Keywords	electron transfer ; artificial photosynthesis ; supramolecular assemblies ; donor-bridge-acceptor system ; transient absorption spectroscopy ; Organic chemistry ; QD241-441
Language	English
Publishing date	2022-04-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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