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  1. Article ; Online: Peter Paetzold (1935-2023): a Chemist of Many Talents.

    Braunschweig, Holger / Arrowsmith, Merle

    Angewandte Chemie (International ed. in English)

    2024  Volume 63, Issue 7, Page(s) e202319179

    Abstract: Peter Paetzold passed away on August 17, 2023 in Aachen, Germany. One of the great pioneers of low-valent boron and boron cluster chemistry, he will also be remembered for his outstanding teaching and the passion he brought to all of his many interests ... ...

    Abstract Peter Paetzold passed away on August 17, 2023 in Aachen, Germany. One of the great pioneers of low-valent boron and boron cluster chemistry, he will also be remembered for his outstanding teaching and the passion he brought to all of his many interests beyond research.
    Language English
    Publishing date 2024-01-10
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.202319179
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: CAAC-stabilised 9,10-diboraanthracene: an electronically and structurally flexible platform for small-molecule activation and metal complexation.

    Dietz, Maximilian / Arrowsmith, Merle / Braunschweig, Holger

    Dalton transactions (Cambridge, England : 2003)

    2024  Volume 53, Issue 2, Page(s) 449–453

    Abstract: A biradical cyclic alkyl(amino)carbene-stabilised 9,10-diboraanthracene (DBA) activates small molecules such as hydrogen, phenyl azide or TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl) across its two boron atoms, while reactions with [(MeCN) ...

    Abstract A biradical cyclic alkyl(amino)carbene-stabilised 9,10-diboraanthracene (DBA) activates small molecules such as hydrogen, phenyl azide or TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl) across its two boron atoms, while reactions with [(MeCN)
    Language English
    Publishing date 2024-01-02
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt03787h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Tricoordinate Beryllium Radicals and Their Reactivity.

    Czernetzki, Corinna / Arrowsmith, Merle / Endres, Lukas / Krummenacher, Ivo / Braunschweig, Holger

    Inorganic chemistry

    2024  Volume 63, Issue 5, Page(s) 2670–2678

    Abstract: The one-electron reduction of [(CAAC)Be(Dur)Br] (CAAC = cyclic alkyl(amino)carbene, Dur = 2,3,5,6-tetramethylphenyl = duryl) with lithium sand in diethyl ether yields the first neutral, tricoordinate, and moderately stable beryllium radical, [(CAAC)( ... ...

    Abstract The one-electron reduction of [(CAAC)Be(Dur)Br] (CAAC = cyclic alkyl(amino)carbene, Dur = 2,3,5,6-tetramethylphenyl = duryl) with lithium sand in diethyl ether yields the first neutral, tricoordinate, and moderately stable beryllium radical, [(CAAC)(Et
    Language English
    Publishing date 2024-01-23
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.3c04014
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Synthesis, reduction and C-H activation chemistry of azaborinines with redox-active organoboryl substituents.

    Lamprecht, Anna / Arrowsmith, Merle / Dietz, Maximilian / Fuchs, Sonja / Rempel, Anna / Härterich, Marcel / Braunschweig, Holger

    Dalton transactions (Cambridge, England : 2003)

    2024  Volume 53, Issue 3, Page(s) 1004–1013

    Abstract: The 2,3,4,5,6-pentaphenyl-1,2-azaborinin-1-yl (PPAB) potassium complex 1 undergoes facile salt metathesis with 9,10-dibromo-9,10-dihydroboraanthracene ( ... ...

    Abstract The 2,3,4,5,6-pentaphenyl-1,2-azaborinin-1-yl (PPAB) potassium complex 1 undergoes facile salt metathesis with 9,10-dibromo-9,10-dihydroboraanthracene (DBA
    Language English
    Publishing date 2024-01-16
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt03826b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Experimental and Computational Study of a Confirmed Borylene-to-Diborene Dimerization.

    Heinz, Myron / Arrowsmith, Merle / Schweizer, Julia I / Krummenacher, Ivo / Holthausen, Max C / Braunschweig, Holger

    Journal of the American Chemical Society

    2023  Volume 145, Issue 41, Page(s) 22685–22696

    Abstract: While the dimerization of heavier group 13 carbene analogues to the corresponding alkene analogues is known and relatively well understood, the dimerization of dicoordinate borylenes (LRB:, L = neutral donor; R = anionic substituent) to the corresponding ...

    Abstract While the dimerization of heavier group 13 carbene analogues to the corresponding alkene analogues is known and relatively well understood, the dimerization of dicoordinate borylenes (LRB:, L = neutral donor; R = anionic substituent) to the corresponding diborenes (LRB═BRL) has never been directly observed. In this study we present the first example of a formal borylene-to-diborene dimerization through abstraction of a labile phosphine ligand from the tricoordinate hydroborylene precursor (CAAC)(Me
    Language English
    Publishing date 2023-10-06
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.3c07979
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: 1,2-Dialkynyldiboranes(4): B-B

    Schorr, Fabian / Arrowsmith, Merle / Fantuzzi, Felipe / Rempel, Anna / Braunschweig, Holger

    Dalton transactions (Cambridge, England : 2003)

    2022  Volume 51, Issue 16, Page(s) 6197–6203

    Abstract: The reactivity of three 1,2-dialkynyl-1,2-diaminodiborane(4) derivatives, ... ...

    Abstract The reactivity of three 1,2-dialkynyl-1,2-diaminodiborane(4) derivatives, B
    Language English
    Publishing date 2022-04-20
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d2dt00683a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Dibenzoberylloles: antiaromatic s-block fluorene analogues.

    Tröster, Tobias / Endres, Franziska / Arrowsmith, Merle / Endres, Lukas / Fantuzzi, Felipe / Braunschweig, Holger

    Chemical communications (Cambridge, England)

    2023  Volume 59, Issue 60, Page(s) 9199–9202

    Abstract: Among a series of Lewis-base-stabilised antiaromatic dibenzoberylloles (DBBes) the cyclic alkyl(amino)carbene (CAAC) analogue undergoes a complex but highly selective thermal decomposition, involving the breaking and making of four bonds each, which ... ...

    Abstract Among a series of Lewis-base-stabilised antiaromatic dibenzoberylloles (DBBes) the cyclic alkyl(amino)carbene (CAAC) analogue undergoes a complex but highly selective thermal decomposition, involving the breaking and making of four bonds each, which yields a rare beryllium
    Language English
    Publishing date 2023-07-25
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d3cc02736h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Synthesis and Reactivity of Highly Electron-Rich Zerovalent Group 10 Diborabenzene Pogo-Stick Complexes.

    Dietz, Maximilian / Arrowsmith, Merle / Endres, Lukas / Paprocki, Valerie / Engels, Bernd / Braunschweig, Holger

    Journal of the American Chemical Society

    2023  Volume 145, Issue 40, Page(s) 22222–22231

    Abstract: A cyclic alkyl(amino)carbene (CAAC)-stabilized 1,4-diborabenzene (DBB, ...

    Abstract A cyclic alkyl(amino)carbene (CAAC)-stabilized 1,4-diborabenzene (DBB,
    Language English
    Publishing date 2023-10-02
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.3c08323
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Bonn / Germany

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  9. Article ; Online: Synthesis and Reactivity of Tricoordinate Organoberyllium Azides.

    Czernetzki, Corinna / Kunz, Tanja / Huynh, Silvia / Lamprecht, Anna / Sprenger, Jan / Finze, Maik / Arrowsmith, Merle / Braunschweig, Holger

    Angewandte Chemie (International ed. in English)

    2024  Volume 63, Issue 18, Page(s) e202401279

    Abstract: A series of terminal mono- and disubstituted beryllium azides of the form [(CAAC)Be( ... ...

    Abstract A series of terminal mono- and disubstituted beryllium azides of the form [(CAAC)Be(N
    Language English
    Publishing date 2024-03-25
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.202401279
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Platinum-Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene.

    Brunecker, Carina / Arrowsmith, Merle / Fantuzzi, Felipe / Braunschweig, Holger

    Angewandte Chemie (International ed. in English)

    2021  Volume 60, Issue 31, Page(s) 16864–16868

    Abstract: The 1:2 reaction of [μ-(dmpm)Pt(nbe)] ...

    Abstract The 1:2 reaction of [μ-(dmpm)Pt(nbe)]
    Language English
    Publishing date 2021-06-24
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.202106161
    Database MEDical Literature Analysis and Retrieval System OnLINE

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