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  1. Article ; Online: Stress factor identification and Risk Probabilistic Number (RPN) analysis of Li-ion batteries based on worldwide electric vehicle usage

    Haber, Marc / Azaïs, Philippe / Genies, Sylvie / Raccurt, Olivier

    Applied Energy. 2023 Aug., v. 343 p.121250-

    2023  

    Abstract: Having clear insights of the stress factors that the electric vehicle (EV) batteries encounter during their service lifetime is crucial for more reliable ageing testing and modelling. Since the first deployment of Li-ion battery based EV, numerous ... ...

    Abstract Having clear insights of the stress factors that the electric vehicle (EV) batteries encounter during their service lifetime is crucial for more reliable ageing testing and modelling. Since the first deployment of Li-ion battery based EV, numerous driving campaigns with field data were published. The goal of this article is to gather, assess and analyse them in order to quantify the stress factors depending on the EV type. The targeted stress factors are the temperature of the cells, the discharging and charging rates, as well as the SOC ranges. 228 million km of driving and 7.8 million trips worth of data for over 37,000 EV were investigated. Along with this literature enquiry, data from an EV in which cells’ temperature was monitored for driving, charging and parking conditions, complemented the analysis. For each stress factor, results were collected, homogenised and compared with each other in order to draw conclusions. Finally, a Risk Probabilistic Number (RPN) was used to evaluate the stress factors with respect to their impact on the ageing of Li-ion batteries, considering a central European weather. The most critical stress factors for BEV cells are cycling at high mid-SOC regions and high SOC idle times. Concerning HEV cells, high power cycling at mid-SOC regions is the most critical stress, and no stresses were identified during idle times. PHEV cells’ most critical stress factors are large DOD cycling and high charge/discharge power. Mild and low temperatures are found to be the most common in such weathers. The RPN analysis serves as a guide for parametrizing and designing reliable accelerated ageing testing on Li-ion batteries depending on their application.
    Keywords electric vehicles ; energy ; lithium batteries ; risk ; temperature ; weather ; BEV ; BTMS ; C-rate ; CD ; CS ; D ; DCFC ; DOD ; EOL ; EV ; HEV ; ICE ; L1 ; L2 ; LIB ; NMC ; P ; P-rate ; PHEV ; RPN ; S ; SOC ; Tamb ; Tcells ; WLTP ; Electric vehicle ; Li-ion battery ; Stress factors ; Ageing ; Usage analysis ; Risk Probabilistic Number (RPN)
    Language English
    Dates of publication 2023-08
    Publishing place Elsevier Ltd
    Document type Article ; Online
    ZDB-ID 2000772-3
    ISSN 0306-2619
    ISSN 0306-2619
    DOI 10.1016/j.apenergy.2023.121250
    Database NAL-Catalogue (AGRICOLA)

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  2. Article ; Online: Potentialities of a mesoporous activated carbon as virus detection probe in aquatic systems

    Delafosse, Doriane / Reinert, Laurence / Azaïs, Philippe / Fontvieille, Dominique / Soneda, Yasushi / Morand, Patrice / Duclaux, Laurent

    Journal of Virological Methods. 2022 May, v. 303 p.114496-

    2022  

    Abstract: Enteric viruses are widely spread in water environments, some being harmful for human communities. Regular epidemics highlight the usefulness of analysing such viruses in wastewaters as a tool for epidemiologists to monitor the extent of their ... ...

    Abstract Enteric viruses are widely spread in water environments, some being harmful for human communities. Regular epidemics highlight the usefulness of analysing such viruses in wastewaters as a tool for epidemiologists to monitor the extent of their dissemination among populations. In this context, CNovel™ Powdered Activated Carbon (PAC) was chosen for its high porosity and high adsorption capacity to investigate sorbent ability to be used as part of of virus detection probes. Self-supported PAC Foils (PAC-F), PAC coated Brushes (PAC-B) and PAC Sampler (PAC-S) were used to prospect PAC efficacy in virus adsorption and above all, the feasibility of virus retrieval from them, allowing to further analysis such as molecular analysis quantification. Aiming at the development of a field-operational tool, PAC saturation and reusability were also investigated, as well as PAC-polarisation effect on its adsorption capacity. Our results pointed out that sorbent-based probes exhibited a high adsorption efficacy of spiked Murine Norovirus (MNV-1) in bare 0.1 M NaCl solution (>90 % for PAC-B and >86 % for PAC-F at ≈10⁷ genome unit virus concentration), with no saturation within our experimental framework. On the other hand, polarisation assays using PAC-F as electrode, did not demonstrate any adsorption improvement. Experiments on PAC probes reusability suggested that they should be used three times at the most for a maximum efficiency. Values of virus retrieval were low (up to 11 % with PAC-B and up to 14 % with PAC-F in 0.1 M NaCl virus suspensions), illustrating the need for the techniques to be improved. A preliminary field assay using PAC-S, demonstrated that our catch-and-retrieve protocol yielded to the detection of autochthonous human Norovirus Genogroup I (NoV GI) and Adenovirus (AdV), in wastewaters suggesting its promising application as virus detection tool in such high loaded and complex waters.
    Keywords Adenoviridae ; Norovirus ; activated carbon ; adsorption ; electrodes ; genome ; humans ; mice ; porosity ; porous media ; sorbents ; viruses ; wastewater ; Enteric viruses ; Powdered activated carbon ; Sorbent-based probe ; Virus analysis ; Wastewater analysis
    Language English
    Dates of publication 2022-05
    Publishing place Elsevier B.V.
    Document type Article ; Online
    ZDB-ID 8013-5
    ISSN 1879-0984 ; 0166-0934
    ISSN (online) 1879-0984
    ISSN 0166-0934
    DOI 10.1016/j.jviromet.2022.114496
    Database NAL-Catalogue (AGRICOLA)

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  3. Article: New PEDOT Derivatives Electrocoated on Silicon Nanowires Protected with ALD Nanometric Alumina for Ultrastable Microsupercapacitors.

    Dietrich, Marc / Paillardet, Loïc / Valero, Anthony / Deschanels, Mathieu / Azaïs, Philippe / Gentile, Pascal / Sadki, Saïd

    Materials (Basel, Switzerland)

    2022  Volume 15, Issue 17

    Abstract: This work deals with electroactive conducting polymers (ECPs) used as a complementary component on purely capacitive silicon nanowires protected by a 3 nm alumina layer. Accordingly, in this work, we use a fast and simple deposition method to create a ... ...

    Abstract This work deals with electroactive conducting polymers (ECPs) used as a complementary component on purely capacitive silicon nanowires protected by a 3 nm alumina layer. Accordingly, in this work, we use a fast and simple deposition method to create a pseudocapacitive material based on the electropolymerization in aqueous micellar media (SDS and SDBS 0.01 M) of hydroxymethyl-EDOT (EDOT-OH) onto 3 nm alumina-coated silicon nanowires (Al
    Language English
    Publishing date 2022-08-30
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2487261-1
    ISSN 1996-1944
    ISSN 1996-1944
    DOI 10.3390/ma15175997
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Potentialities of a mesoporous activated carbon as virus detection probe in aquatic systems.

    Delafosse, Doriane / Reinert, Laurence / Azaïs, Philippe / Fontvieille, Dominique / Soneda, Yasushi / Morand, Patrice / Duclaux, Laurent

    Journal of virological methods

    2022  Volume 303, Page(s) 114496

    Abstract: Enteric viruses are widely spread in water environments, some being harmful for human communities. Regular epidemics highlight the usefulness of analysing such viruses in wastewaters as a tool for epidemiologists to monitor the extent of their ... ...

    Abstract Enteric viruses are widely spread in water environments, some being harmful for human communities. Regular epidemics highlight the usefulness of analysing such viruses in wastewaters as a tool for epidemiologists to monitor the extent of their dissemination among populations. In this context, CNovel™ Powdered Activated Carbon (PAC) was chosen for its high porosity and high adsorption capacity to investigate sorbent ability to be used as part of of virus detection probes. Self-supported PAC Foils (PAC-F), PAC coated Brushes (PAC-B) and PAC Sampler (PAC-S) were used to prospect PAC efficacy in virus adsorption and above all, the feasibility of virus retrieval from them, allowing to further analysis such as molecular analysis quantification. Aiming at the development of a field-operational tool, PAC saturation and reusability were also investigated, as well as PAC-polarisation effect on its adsorption capacity. Our results pointed out that sorbent-based probes exhibited a high adsorption efficacy of spiked Murine Norovirus (MNV-1) in bare 0.1 M NaCl solution (>90 % for PAC-B and >86 % for PAC-F at ≈10
    MeSH term(s) Adsorption ; Animals ; Charcoal ; Humans ; Mice ; Waste Water ; Water Pollutants, Chemical ; Water Purification/methods
    Chemical Substances Waste Water ; Water Pollutants, Chemical ; Charcoal (16291-96-6)
    Language English
    Publishing date 2022-02-15
    Publishing country Netherlands
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 8013-5
    ISSN 1879-0984 ; 0166-0934
    ISSN (online) 1879-0984
    ISSN 0166-0934
    DOI 10.1016/j.jviromet.2022.114496
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article: Exploring electrolyte organization in supercapacitor electrodes with solid-state NMR.

    Deschamps, Michaël / Gilbert, Edouard / Azais, Philippe / Raymundo-Piñero, Encarnación / Ammar, Mohammed Ramzi / Simon, Patrick / Massiot, Dominique / Béguin, François

    Nature materials

    2013  Volume 12, Issue 4, Page(s) 351–358

    Abstract: Supercapacitors are electrochemical energy-storage devices that exploit the electrostatic interaction between high-surface-area nanoporous electrodes and electrolyte ions. Insight into the molecular mechanisms at work inside supercapacitor carbon ... ...

    Abstract Supercapacitors are electrochemical energy-storage devices that exploit the electrostatic interaction between high-surface-area nanoporous electrodes and electrolyte ions. Insight into the molecular mechanisms at work inside supercapacitor carbon electrodes is obtained with (13)C and (11)B ex situ magic-angle spinning nuclear magnetic resonance (MAS-NMR). In activated carbons soaked with an electrolyte solution, two distinct adsorption sites are detected by NMR, both undergoing chemical exchange with the free electrolyte molecules. On charging, anions are substituted by cations in the negative carbon electrode and cations by anions in the positive electrode, and their proportions in each electrode are quantified by NMR. Moreover, acetonitrile molecules are expelled from the adsorption sites at the negative electrode alone. Two nanoporous carbon materials were tested, with different nanotexture orders (using Raman and (13)C MAS-NMR spectroscopies), and the more disordered carbon shows a better capacitance and a better tolerance to high voltages.
    Language English
    Publishing date 2013-02-17
    Publishing country England
    Document type Journal Article
    ZDB-ID 2088679-2
    ISSN 1476-4660 ; 1476-1122
    ISSN (online) 1476-4660
    ISSN 1476-1122
    DOI 10.1038/nmat3567
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Novel Preparation of N-Doped SnO

    Wang, Luyuan Paul / Leconte, Yann / Feng, Zhenxing / Wei, Chao / Zhao, Yi / Ma, Qing / Xu, Wenqian / Bourrioux, Samantha / Azais, Philippe / Srinivasan, Madhavi / Xu, Zhichuan J

    Advanced materials (Deerfield Beach, Fla.)

    2016  Volume 29, Issue 6

    Abstract: Laser pyrolyzed ... ...

    Abstract Laser pyrolyzed SnO
    Language English
    Publishing date 2016-12-05
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1474949-X
    ISSN 1521-4095 ; 0935-9648
    ISSN (online) 1521-4095
    ISSN 0935-9648
    DOI 10.1002/adma.201603286
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: A solid-state NMR study of C(70): a model molecule for amorphous carbons.

    Deschamps, Michaël / Cadars, Sylvian / Gilbert, Edouard / Azaïs, Philippe / Raymundo-Pinero, Encarnacion / Béguin, François / Massiot, Dominique

    Solid state nuclear magnetic resonance

    2012  Volume 42, Page(s) 81–86

    Abstract: We show that natural abundance, solid-state MAS-NMR (13)C INADEQUATE spectra can be recorded for crystallized C(70), using the through-bond J-coupling for the magnetization transfer. The effect of strong J-coupling can be lessened at high magnetic fields, ...

    Abstract We show that natural abundance, solid-state MAS-NMR (13)C INADEQUATE spectra can be recorded for crystallized C(70), using the through-bond J-coupling for the magnetization transfer. The effect of strong J-coupling can be lessened at high magnetic fields, allowing the observation of cross-peaks between close resonances. DFT calculations of the chemical shifts show an excellent agreement with the experimental values. A correlation is observed between the average CCC bond angles and the (13)C chemical shift, offering a way to understand the dispersion of (13)C chemical shifts in nanoporous activated carbons in terms of local deviations from planarity.
    MeSH term(s) Carbon/chemistry ; Magnetic Resonance Spectroscopy/methods ; Molecular Conformation
    Chemical Substances Carbon (7440-44-0)
    Language English
    Publishing date 2012-04
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 1122088-0
    ISSN 1527-3326 ; 0926-2040
    ISSN (online) 1527-3326
    ISSN 0926-2040
    DOI 10.1016/j.ssnmr.2012.01.001
    Database MEDical Literature Analysis and Retrieval System OnLINE

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