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  1. Thesis ; Online: Investigation of New Aerosol Particle Formation in Polar Regions

    Baccarini, Andrea

    2021  

    Keywords info:eu-repo/classification/ddc/550 ; Earth sciences
    Language English
    Publisher ETH Zurich
    Publishing country ch
    Document type Thesis ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  2. Book ; Online: MoMuCAMS

    Pohorsky, Roman / Baccarini, Andrea / Tolu, Julie / Winkel, Lenny H. E. / Schmale, Julia

    eISSN:

    A new modular platform for boundary layer aerosol and trace gas vertical measurements in extreme environments

    2024  

    Abstract: The Modular Multiplatform Compatible Air Measurement System (MoMuCAMS) is a newly developed in situ aerosol and trace gas measurement platform for lower-atmospheric vertical profiling. MoMuCAMS has been primarily designed to be attached to a Helikite, a ... ...

    Abstract The Modular Multiplatform Compatible Air Measurement System (MoMuCAMS) is a newly developed in situ aerosol and trace gas measurement platform for lower-atmospheric vertical profiling. MoMuCAMS has been primarily designed to be attached to a Helikite, a rugged tethered balloon type that is suitable for operations in cold and windy conditions. The system addresses the need for detailed vertical observations of atmospheric composition in the boundary layer and lower free troposphere, especially in polar and alpine regions. The MoMuCAMS encompasses a box that houses instrumentation, a heated inlet, a single-board computer to transmit data to the ground for in-flight decisions and a power distribution system. The enclosure can accommodate various combinations of instruments within its weight limit (e.g., 20 kg for a 45 m 3 balloon). This flexibility represents a unique feature, allowing for the study of multiple aerosol properties (number concentration, size distribution, optical properties, chemical composition and morphology), as well as trace gases (e.g., CO, CO 2 , O 3 , N 2 O) and meteorological variables (e.g., wind speed and direction, temperature, relative humidity, pressure). Different instrumental combinations are therefore possible to address the specific scientific focus of the observations. It is the first tethered-balloon-based system equipped with instrumentation providing a size distribution for aerosol particles within a large range, i.e., from 8 to 3370 nm, which is vital to understanding atmospheric processes of aerosols and their climate impacts through interaction with radiation and clouds. Here we present a characterization of the specifically developed inlet system and previously unreported instruments, most notably the miniaturized scanning electrical mobility spectrometer and a near-infrared carbon monoxide monitor. As of December 2022, MoMuCAMS has been tested during two field campaigns in the Swiss Alps in winter and fall 2021. It was further deployed in Fairbanks, Alaska, USA, in ...
    Subject code 333
    Language English
    Publishing date 2024-01-30
    Publishing country de
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Article ; Online: Atmospheric isoprene measurements reveal larger-than-expected Southern Ocean emissions.

    Ferracci, Valerio / Weber, James / Bolas, Conor G / Robinson, Andrew D / Tummon, Fiona / Rodríguez-Ros, Pablo / Cortés-Greus, Pau / Baccarini, Andrea / Jones, Roderic L / Galí, Martí / Simó, Rafel / Schmale, Julia / Harris, Neil R P

    Nature communications

    2024  Volume 15, Issue 1, Page(s) 2571

    Abstract: Isoprene is a key trace component of the atmosphere emitted by vegetation and other organisms. It is highly reactive and can impact atmospheric composition and climate by affecting the greenhouse gases ozone and methane and secondary organic aerosol ... ...

    Abstract Isoprene is a key trace component of the atmosphere emitted by vegetation and other organisms. It is highly reactive and can impact atmospheric composition and climate by affecting the greenhouse gases ozone and methane and secondary organic aerosol formation. Marine fluxes are poorly constrained due to the paucity of long-term measurements; this in turn limits our understanding of isoprene cycling in the ocean. Here we present the analysis of isoprene concentrations in the atmosphere measured across the Southern Ocean over 4 months in the summertime. Some of the highest concentrations ( >500 ppt) originated from the marginal ice zone in the Ross and Amundsen seas, indicating the marginal ice zone is a significant source of isoprene at high latitudes. Using the United Kingdom Earth System Model we show that current estimates of sea-to-air isoprene fluxes underestimate observed isoprene by a factor >20. A daytime source of isoprene is required to reconcile models with observations. The model presented here suggests such an increase in isoprene emissions would lead to >8% decrease in the hydroxyl radical in regions of the Southern Ocean, with implications for our understanding of atmospheric oxidation and composition in remote environments, often used as proxies for the pre-industrial atmosphere.
    Language English
    Publishing date 2024-03-22
    Publishing country England
    Document type Journal Article
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-024-46744-4
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Book ; Online: Late summer transition from a free-tropospheric to boundary layer source of Aitken mode aerosol in the high Arctic

    Price, Ruth / Baccarini, Andrea / Schmale, Julia / Zieger, Paul / Brooks, Ian M. / Field, Paul / Carslaw, Ken S.

    eISSN:

    2023  

    Abstract: In the Arctic, the aerosol budget plays a particular role in determining the behaviour of clouds, which are important for the surface energy balance and thus for the region’s climate. A key question is the extent to which cloud condensation nuclei in the ...

    Abstract In the Arctic, the aerosol budget plays a particular role in determining the behaviour of clouds, which are important for the surface energy balance and thus for the region’s climate. A key question is the extent to which cloud condensation nuclei in the high Arctic summertime boundary layer are controlled by local emission and formation processes as opposed to transport from outside. Each of these sources is likely to respond differently to future changes in ice cover. Here we use a global model and observations from ship and aircraft field campaigns to understand the source of high Arctic aerosol in late summer. We find that particles formed remotely, i.e. at latitudes outside the Arctic, are the dominant source of boundary layer Aitken mode particles during the sea ice melt period up to the end of August. Particles from such remote sources, entrained into the boundary layer from the free troposphere, account for nucleation and Aitken mode particle concentrations that are otherwise underestimated by the model. This source from outside the high Arctic declines as photochemical rates decrease towards the end of summer and is largely replaced by local new particle formation driven by iodic acid created during freeze-up. Such a local source increases the simulated Aitken mode particle concentrations by 2 orders of magnitude during sea ice freeze-up and is consistent with strong fluctuations in nucleation mode concentrations that occur in September. Our results suggest a high-Arctic aerosol regime shift in late summer, and only after this shift do cloud condensation nuclei become sensitive to local aerosol processes.
    Subject code 551
    Language English
    Publishing date 2023-03-06
    Publishing country de
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  5. Book ; Online: Late summer transition from a free-tropospheric to boundary layer source of Aitken mode aerosol in the high Arctic

    Price, Ruth / Baccarini, Andrea / Schmale, Julia / Zieger, Paul / Brooks, Ian M. / Field, Paul / Carslaw, Ken S.

    eISSN: 1680-7324

    2023  

    Abstract: In the Arctic, the aerosol budget plays a particular role in determining the behaviour of clouds, which are important for the surface energy balance and thus for the region’s climate. A key question is the extent to which cloud condensation nuclei in the ...

    Abstract In the Arctic, the aerosol budget plays a particular role in determining the behaviour of clouds, which are important for the surface energy balance and thus for the region’s climate. A key question is the extent to which cloud condensation nuclei in the high Arctic summertime boundary layer are controlled by local emission and formation processes as opposed to transport from outside. Each of these sources is likely to respond differently to future changes in ice cover. Here we use a global model and observations from ship and aircraft field campaigns to understand the source of high Arctic aerosol in late summer. We find that particles formed remotely, i.e. at latitudes outside the Arctic, are the dominant source of boundary layer Aitken mode particles during the sea ice melt period up to the end of August. Particles from such remote sources, entrained into the boundary layer from the free troposphere, account for nucleation and Aitken mode particle concentrations that are otherwise underestimated by the model. This source from outside the high Arctic declines as photochemical rates decrease towards the end of summer and is largely replaced by local new particle formation driven by iodic acid created during freeze-up. Such a local source increases the simulated Aitken mode particle concentrations by 2 orders of magnitude during sea ice freeze-up and is consistent with strong fluctuations in nucleation mode concentrations that occur in September. Our results suggest a high-Arctic aerosol regime shift in late summer, and only after this shift do cloud condensation nuclei become sensitive to local aerosol processes.
    Subject code 551
    Language English
    Publishing date 2023-03-06
    Publishing country de
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  6. Article ; Online: A central arctic extreme aerosol event triggered by a warm air-mass intrusion.

    Dada, Lubna / Angot, Hélène / Beck, Ivo / Baccarini, Andrea / Quéléver, Lauriane L J / Boyer, Matthew / Laurila, Tiia / Brasseur, Zoé / Jozef, Gina / de Boer, Gijs / Shupe, Matthew D / Henning, Silvia / Bucci, Silvia / Dütsch, Marina / Stohl, Andreas / Petäjä, Tuukka / Daellenbach, Kaspar R / Jokinen, Tuija / Schmale, Julia

    Nature communications

    2022  Volume 13, Issue 1, Page(s) 5290

    Abstract: Frequency and intensity of warm and moist air-mass intrusions into the Arctic have increased over the past decades and have been related to sea ice melt. During our year-long expedition in the remote central Arctic Ocean, a record-breaking increase in ... ...

    Abstract Frequency and intensity of warm and moist air-mass intrusions into the Arctic have increased over the past decades and have been related to sea ice melt. During our year-long expedition in the remote central Arctic Ocean, a record-breaking increase in temperature, moisture and downwelling-longwave radiation was observed in mid-April 2020, during an air-mass intrusion carrying air pollutants from northern Eurasia. The two-day intrusion, caused drastic changes in the aerosol size distribution, chemical composition and particle hygroscopicity. Here we show how the intrusion transformed the Arctic from a remote low-particle environment to an area comparable to a central-European urban setting. Additionally, the intrusion resulted in an explosive increase in cloud condensation nuclei, which can have direct effects on Arctic clouds' radiation, their precipitation patterns, and their lifetime. Thus, unless prompt actions to significantly reduce emissions in the source regions are taken, such intrusion events are expected to continue to affect the Arctic climate.
    Language English
    Publishing date 2022-09-08
    Publishing country England
    Document type Journal Article
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-022-32872-2
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Insights into the molecular composition of semi-volatile aerosols in the summertime central Arctic Ocean using FIGAERO-CIMS.

    Siegel, Karolina / Karlsson, Linn / Zieger, Paul / Baccarini, Andrea / Schmale, Julia / Lawler, Michael / Salter, Matthew / Leck, Caroline / Ekman, Annica M L / Riipinen, Ilona / Mohr, Claudia

    Environmental science: atmospheres

    2021  Volume 1, Issue 4, Page(s) 161–175

    Abstract: The remote central Arctic during summertime has a pristine atmosphere with very low aerosol particle concentrations. As the region becomes increasingly ice-free during summer, enhanced ocean-atmosphere fluxes of aerosol particles and precursor gases may ... ...

    Abstract The remote central Arctic during summertime has a pristine atmosphere with very low aerosol particle concentrations. As the region becomes increasingly ice-free during summer, enhanced ocean-atmosphere fluxes of aerosol particles and precursor gases may therefore have impacts on the climate. However, large knowledge gaps remain regarding the sources and physicochemical properties of aerosols in this region. Here, we present insights into the molecular composition of semi-volatile aerosol components collected in September 2018 during the MOCCHA (Microbiology-Ocean-Cloud-Coupling in the High Arctic) campaign as part of the Arctic Ocean 2018 expedition with the Swedish Icebreaker
    Language English
    Publishing date 2021-03-15
    Publishing country England
    Document type Journal Article
    ISSN 2634-3606
    ISSN (online) 2634-3606
    DOI 10.1039/d0ea00023j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article: Sources, Occurrence and Characteristics of Fluorescent Biological Aerosol Particles Measured Over the Pristine Southern Ocean.

    Moallemi, Alireza / Landwehr, Sebastian / Robinson, Charlotte / Simó, Rafel / Zamanillo, Marina / Chen, Gang / Baccarini, Andrea / Schnaiter, Martin / Henning, Silvia / Modini, Robin L / Gysel-Beer, Martin / Schmale, Julia

    Journal of geophysical research. Atmospheres : JGR

    2021  Volume 126, Issue 11, Page(s) e2021JD034811

    Abstract: In this study, we investigate the occurrence of primary biological aerosol particles (PBAP) over all sectors of the Southern Ocean (SO) based on a 90-day data set collected during the Antarctic Circumnavigation Expedition (ACE) in austral summer 2016- ... ...

    Abstract In this study, we investigate the occurrence of primary biological aerosol particles (PBAP) over all sectors of the Southern Ocean (SO) based on a 90-day data set collected during the Antarctic Circumnavigation Expedition (ACE) in austral summer 2016-2017. Super-micrometer PBAP (1-16 µm diameter) were measured by a wide band integrated bioaerosol sensor (WIBS-4). Low (3σ) and high (9σ) fluorescence thresholds are used to obtain statistics on fluorescent and hyper-fluorescent PBAP, respectively. Our focus is on data obtained over the pristine ocean, that is, more than 200 km away from land. The results indicate that (hyper-)fluorescent PBAP are correlated to atmospheric variables associated with sea spray aerosol (SSA) particles (wind speed, total super-micrometer aerosol number concentration, chloride and sodium concentrations). This suggests that a main source of PBAP over the SO is SSA. The median percentage contribution of fluorescent and hyper-fluorescent PBAP to super-micrometer SSA was 1.6% and 0.13%, respectively. We demonstrate that the fraction of (hyper-)fluorescent PBAP to total super-micrometer particles positively correlates with concentrations of bacteria and several taxa of pythoplankton measured in seawater, indicating that marine biota concentrations modulate the PBAP source flux. We investigate the fluorescent properties of (hyper-)fluorescent PBAP for several events that occurred near land masses. We find that the fluorescence signal characteristics of particles near land is much more variable than over the pristine ocean. We conclude that the source and concentration of fluorescent PBAP over the open ocean is similar across all sampled sectors of the SO.
    Language English
    Publishing date 2021-06-09
    Publishing country United States
    Document type Journal Article
    ZDB-ID 710256-2
    ISSN 2169-8996 ; 2169-897X ; 0148-0227
    ISSN (online) 2169-8996
    ISSN 2169-897X ; 0148-0227
    DOI 10.1029/2021JD034811
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Using Novel Molecular-Level Chemical Composition Observations of High Arctic Organic Aerosol for Predictions of Cloud Condensation Nuclei.

    Siegel, Karolina / Neuberger, Almuth / Karlsson, Linn / Zieger, Paul / Mattsson, Fredrik / Duplessis, Patrick / Dada, Lubna / Daellenbach, Kaspar / Schmale, Julia / Baccarini, Andrea / Krejci, Radovan / Svenningsson, Birgitta / Chang, Rachel / Ekman, Annica M L / Riipinen, Ilona / Mohr, Claudia

    Environmental science & technology

    2022  Volume 56, Issue 19, Page(s) 13888–13899

    Abstract: Predictions of cloud droplet activation in the late summertime (September) central Arctic Ocean are made ... ...

    Abstract Predictions of cloud droplet activation in the late summertime (September) central Arctic Ocean are made using
    Language English
    Publishing date 2022-09-16
    Publishing country United States
    Document type Journal Article
    ISSN 1520-5851
    ISSN (online) 1520-5851
    DOI 10.1021/acs.est.2c02162
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article: Physical and Chemical Properties of Cloud Droplet Residuals and Aerosol Particles During the Arctic Ocean 2018 Expedition.

    Karlsson, Linn / Baccarini, Andrea / Duplessis, Patrick / Baumgardner, Darrel / Brooks, Ian M / Chang, Rachel Y-W / Dada, Lubna / Dällenbach, Kaspar R / Heikkinen, Liine / Krejci, Radovan / Leaitch, W Richard / Leck, Caroline / Partridge, Daniel G / Salter, Matthew E / Wernli, Heini / Wheeler, Michael J / Schmale, Julia / Zieger, Paul

    Journal of geophysical research. Atmospheres : JGR

    2022  Volume 127, Issue 11, Page(s) e2021JD036383

    Abstract: Detailed knowledge of the physical and chemical properties and sources of particles that form clouds is especially important in pristine areas like the Arctic, where particle concentrations are often low and observations are sparse. Here, we present in ... ...

    Abstract Detailed knowledge of the physical and chemical properties and sources of particles that form clouds is especially important in pristine areas like the Arctic, where particle concentrations are often low and observations are sparse. Here, we present in situ cloud and aerosol measurements from the central Arctic Ocean in August-September 2018 combined with air parcel source analysis. We provide direct experimental evidence that Aitken mode particles (particles with diameters ≲70 nm) significantly contribute to cloud condensation nuclei (CCN) or cloud droplet residuals, especially after the freeze-up of the sea ice in the transition toward fall. These Aitken mode particles were associated with air that spent more time over the pack ice, while size distributions dominated by accumulation mode particles (particles with diameters ≳70 nm) showed a stronger contribution of oceanic air and slightly different source regions. This was accompanied by changes in the average chemical composition of the accumulation mode aerosol with an increased relative contribution of organic material toward fall. Addition of aerosol mass due to aqueous-phase chemistry during in-cloud processing was probably small over the pack ice given the fact that we observed very similar particle size distributions in both the whole-air and cloud droplet residual data. These aerosol-cloud interaction observations provide valuable insight into the origin and physical and chemical properties of CCN over the pristine central Arctic Ocean.
    Language English
    Publishing date 2022-06-02
    Publishing country United States
    Document type Journal Article
    ZDB-ID 710256-2
    ISSN 2169-8996 ; 2169-897X ; 0148-0227
    ISSN (online) 2169-8996
    ISSN 2169-897X ; 0148-0227
    DOI 10.1029/2021JD036383
    Database MEDical Literature Analysis and Retrieval System OnLINE

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