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  1. Article ; Online: Recent advances in the carbon-phosphorus (C-P) bond formation from unsaturated compounds by s- and p-block metals.

    Banerjee, Indrani / Panda, Tarun K

    Organic & biomolecular chemistry

    2021  Volume 19, Issue 30, Page(s) 6571–6587

    Abstract: Researchers around the globe have witnessed several breakthroughs in s- and p-block metal chemistry. Over the past few years, several applications in catalysis associated with these main group metals have been established, and owing to their abundance ... ...

    Abstract Researchers around the globe have witnessed several breakthroughs in s- and p-block metal chemistry. Over the past few years, several applications in catalysis associated with these main group metals have been established, and owing to their abundance and low cost and they have proved to be essential alternatives to transition metal catalysts. In this review, we present a detailed discussion on the catalytic addition of P-H bonds from various phosphine reagents to multiple bonds of unsaturated substrates for the synthesis of organophosphorus compounds with C-P bonds promoted by various s- and p-block metal catalysts, as published in the last decade.
    Language English
    Publishing date 2021-07-07
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 2097583-1
    ISSN 1477-0539 ; 1477-0520
    ISSN (online) 1477-0539
    ISSN 1477-0520
    DOI 10.1039/d1ob01019k
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: A Protein and Membrane Integrity Study of TiO

    Barkhade, Tejal / Mahapatra, Santosh Kumar / Banerjee, Indrani

    The Journal of membrane biology

    2021  Volume 254, Issue 2, Page(s) 217–237

    Abstract: The paper assessed the toxic effect of titanium dioxide ( ... ...

    Abstract The paper assessed the toxic effect of titanium dioxide (TiO
    MeSH term(s) Iron/chemistry ; Membrane Potential, Mitochondrial ; Mitochondria/drug effects ; Nanoparticles/toxicity ; Spectroscopy, Fourier Transform Infrared ; Titanium/toxicity
    Chemical Substances titanium dioxide (15FIX9V2JP) ; Titanium (D1JT611TNE) ; Iron (E1UOL152H7)
    Language English
    Publishing date 2021-03-31
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3082-x
    ISSN 1432-1424 ; 0022-2631
    ISSN (online) 1432-1424
    ISSN 0022-2631
    DOI 10.1007/s00232-021-00177-y
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Enhancement of nutritional value of fried fish using an artificial intelligence approach

    Sadhu, Tithli / Banerjee, Indrani / Lahiri, Sandip Kumar / Chakrabarty, Jitamanyu

    Environmental science and pollution research. 2022 Mar., v. 29, no. 14

    2022  

    Abstract: Frying affects the nutritional quality of fish detrimentally. In this study, using Catla catla and mustard oil, experiments were carried out in varying temperatures (140–240 °C), times (5–20 min), and oil amounts (25–100 ml/kg of fish) which established ... ...

    Abstract Frying affects the nutritional quality of fish detrimentally. In this study, using Catla catla and mustard oil, experiments were carried out in varying temperatures (140–240 °C), times (5–20 min), and oil amounts (25–100 ml/kg of fish) which established drastic reduction of 44.97% and 99.40% for polyunsaturated fatty acid (PUFA)/saturated fatty acids (SFA) and index of atherogenicity (IA) profile, respectively. Artificial neural network (ANN) was implemented successfully to provide an association between the independent inputs with dependent outputs (values of R² were 0.99 and 0.98; RMSE were 0.038 and 0.046; and performance were 0.038 and 0.067 for PUFA/SFA and IA, respectively) by exhaustive search of various algorithms and activation functions available in literature. ANN model–based meta-heuristic, stochastic optimization formalisms, genetic algorithm (GA) and particle swarm optimization (PSO), were applied to optimize the combination of cooking parameters for improving the nutritional quality of food which improved the nutritional value by maximizing the PUFA/SFA profile up to 63.05% and minimizing the IA profile to 99.64%. Multi-objective genetic algorithm (MOGA) was also employed to tune the inputs by maintaining a balance between the contrasting outputs and enhance the overall food value simultaneously with multi-objective (beneficial for health, economic, and environment-friendly) proposal. MOGA was able to improve the PUFA/SFA profile up to 44.76% and reduce the IA profile to 92.94% concurrently with the reduction of wastage of culinary media and energy consumption, following the optimized cooking condition (118.92 °C, 6.06 min, 40 ml oil/kg of fish).
    Keywords Catla catla ; algorithms ; artificial intelligence ; energy ; fish ; mustard oil ; neural networks ; nutritive value ; pollution ; polyunsaturated fatty acids ; research
    Language English
    Dates of publication 2022-03
    Size p. 20048-20063.
    Publishing place Springer Berlin Heidelberg
    Document type Article
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-021-13548-8
    Database NAL-Catalogue (AGRICOLA)

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  4. Article ; Online: Calcium mediated efficient synthesis of N-arylamidines from organic nitriles and amines.

    Banerjee, Indrani / Sagar, Shweta / Panda, Tarun K

    Organic & biomolecular chemistry

    2020  Volume 18, Issue 22, Page(s) 4231–4237

    Abstract: Amidines are a preeminent group of organic compounds having wide applications in various industries. Here, we have developed a simple one-step reaction protocol for the facile synthesis of N-arylamidines catalysed by calcium bis(hexamethyldisilazide) [Ca{ ...

    Abstract Amidines are a preeminent group of organic compounds having wide applications in various industries. Here, we have developed a simple one-step reaction protocol for the facile synthesis of N-arylamidines catalysed by calcium bis(hexamethyldisilazide) [Ca{N(SiMe3)2}2(THF)2]. The amidine synthesis was readily achieved from organic nitriles and amines which provided a broad substrate scope ranging from electron-withdrawing to electron-donating substitutions as well as heterocyclic substitution. The reaction was carried out in a solvent-free medium under ambient conditions. The nucleophilic addition of aromatic amines to aryl nitriles led to good to excellent yields of the corresponding amidines. The reactivity of the amidines was further examined and the respective urea derivatives were achieved in excellent yields. The plausible mechanism involves the generation of an active calcium amido pre-catalyst that helps in the activation of nitriles in the reaction course.
    Language English
    Publishing date 2020-05-27
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2097583-1
    ISSN 1477-0539 ; 1477-0520
    ISSN (online) 1477-0539
    ISSN 1477-0520
    DOI 10.1039/d0ob00805b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Secondary structural analysis of non-mulberry silk fibroin nanoparticles synthesized by using microwave and acetone method.

    Asapur, Prithvi / Mahapatra, Santosh Kumar / Banerjee, Indrani

    Journal of biomolecular structure & dynamics

    2020  Volume 40, Issue 9, Page(s) 4100–4109

    Abstract: The 3D structure analysis for Muga silk protein was predicted through homology modeling and Ramachandran plot with the determination of quality index for Stereo/packing and 3D quality index. Silk Nanoparticles were synthesized using conventional ... ...

    Abstract The 3D structure analysis for Muga silk protein was predicted through homology modeling and Ramachandran plot with the determination of quality index for Stereo/packing and 3D quality index. Silk Nanoparticles were synthesized using conventional desolvation and microwave-assisted radiolysis method from Muga silk fibroin. The secondary structure evolution due to two different synthesis methods was investigated using FTIR and Circular Dichroism (CD) spectroscopy. The microwave synthesized nanoparticles showed enhanced β-sheet content than desolvation synthesized nanoparticles. The conformational changes of Muga silk fibroin protein to nanoparticle followed an ordered transition from random coil to α-helix then from α-helix to β-turn and from β-turn to β-sheets where α-helix and β-turn are the intermediate forms before getting stabilized to the metastable β-sheets structure. The thermodynamics involved in secondary structure evolution was studied from CD analysis and activation energy involved in the formation of the secondary structure was determined. Communicated by Ramaswamy H. Sarma.
    MeSH term(s) Acetone ; Fibroins/chemistry ; Microwaves ; Nanoparticles/chemistry ; Silk/chemistry ; Spectroscopy, Fourier Transform Infrared
    Chemical Substances Silk ; Acetone (1364PS73AF) ; Fibroins (9007-76-5)
    Language English
    Publishing date 2020-12-04
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 49157-3
    ISSN 1538-0254 ; 0739-1102
    ISSN (online) 1538-0254
    ISSN 0739-1102
    DOI 10.1080/07391102.2020.1852970
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Enhancement of nutritional value of fried fish using an artificial intelligence approach.

    Sadhu, Tithli / Banerjee, Indrani / Lahiri, Sandip Kumar / Chakrabarty, Jitamanyu

    Environmental science and pollution research international

    2021  Volume 29, Issue 14, Page(s) 20048–20063

    Abstract: Frying affects the nutritional quality of fish detrimentally. In this study, using Catla catla and mustard oil, experiments were carried out in varying temperatures (140-240 °C), times (5-20 min), and oil amounts (25-100 ml/kg of fish) which established ... ...

    Abstract Frying affects the nutritional quality of fish detrimentally. In this study, using Catla catla and mustard oil, experiments were carried out in varying temperatures (140-240 °C), times (5-20 min), and oil amounts (25-100 ml/kg of fish) which established drastic reduction of 44.97% and 99.40% for polyunsaturated fatty acid (PUFA)/saturated fatty acids (SFA) and index of atherogenicity (IA) profile, respectively. Artificial neural network (ANN) was implemented successfully to provide an association between the independent inputs with dependent outputs (values of R
    MeSH term(s) Animals ; Artificial Intelligence ; Fatty Acids ; Fatty Acids, Unsaturated ; Neural Networks, Computer ; Nutritive Value
    Chemical Substances Fatty Acids ; Fatty Acids, Unsaturated
    Language English
    Publishing date 2021-03-24
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-021-13548-8
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Homology modeling and molecular docking study of biogenic Muga silk nanoparticles as putative drug-binding system.

    Asapur, Prithvi C / Sahare, Purushottam D / Mahapatra, Santosh Kumar / Banerjee, Indrani

    Biotechnology and applied biochemistry

    2021  Volume 69, Issue 1, Page(s) 129–135

    Abstract: The recent emergence of natural biopolymers as drug delivery vehicles is attributed to their biodegradability and less systemic toxicity. Muga silk nanoparticles were prepared using microwave radiolysis method and were characterized by Fourier transform ... ...

    Abstract The recent emergence of natural biopolymers as drug delivery vehicles is attributed to their biodegradability and less systemic toxicity. Muga silk nanoparticles were prepared using microwave radiolysis method and were characterized by Fourier transform infrared spectroscopy, circular dichroism, X-ray diffraction and transmission electron microscopy. To find the applicability in the drug delivery system of these nanoparticle and to know the binding site(s), a computational study was carried out. The structure of the Muga protein is predicted using homology modeling, which is further used for molecular docking. The in silico molecular docking between the Muga silk nanoparticles and three United States Food and Drug Administration-approved model drugs of doxorubicin, remdesivir and dexamethasone was performed. The binding capabilities and binding energy of the Muga silk proteins with these drugs are determined. The basic idea of the active site and the residues involved in the binding of the drugs/ligands is also studied. Doxorubicin showed the highest binding affinity of -8.7 kcal/mol and that of the remdesivir and dexamethasone are found to be -7.2 and -7.9 kcal/mol, respectively. Such high binding affinity(ies) would help for slow drug release kinetics and the other two drugs can be loaded when the requirement is for sustained drug release. The data were also validated using the UV-vis. spectroscopy.
    MeSH term(s) Drug Liberation ; Molecular Docking Simulation ; Nanoparticles ; Pharmaceutical Preparations ; Silk ; Spectroscopy, Fourier Transform Infrared
    Chemical Substances Pharmaceutical Preparations ; Silk
    Language English
    Publishing date 2021-03-02
    Publishing country United States
    Document type Journal Article
    ZDB-ID 883433-7
    ISSN 1470-8744 ; 0885-4513
    ISSN (online) 1470-8744
    ISSN 0885-4513
    DOI 10.1002/bab.2088
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Catalytic Hydroboration and Reductive Amination of Carbonyl Compounds by HBpin using a Zinc Promoter.

    Kumar, Ravi / Rawal, Parveen / Banerjee, Indrani / Pada Nayek, Hari / Gupta, Puneet / Panda, Tarun K

    Chemistry, an Asian journal

    2022  Volume 17, Issue 5, Page(s) e202200013

    Abstract: The chemoselective hydroboration of aldehydes and ketones, catalyzed by Zinc(II) complexes [ ... ...

    Abstract The chemoselective hydroboration of aldehydes and ketones, catalyzed by Zinc(II) complexes [κ
    MeSH term(s) Amination ; Amines/chemistry ; Catalysis ; Ketones/chemistry ; Zinc
    Chemical Substances Amines ; Ketones ; Zinc (J41CSQ7QDS)
    Language English
    Publishing date 2022-01-28
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2233006-9
    ISSN 1861-471X ; 1861-4728
    ISSN (online) 1861-471X
    ISSN 1861-4728
    DOI 10.1002/asia.202200013
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Electrochemical Aptamer-Based Biosensors for Measurements in Undiluted Human Saliva.

    Nguyen, Minh-Dat / Nguyen, Khoa-Nam / Malo, Samuel / Banerjee, Indrani / Wu, Donghui / Du-Thumm, Laurence / Dauphin-Ducharme, Philippe

    ACS sensors

    2023  Volume 8, Issue 12, Page(s) 4625–4635

    Abstract: Although blood remains a gold standard diagnostic fluid for most health exams, it involves an unpleasant and relatively invasive sampling procedure (finger pricking or venous draw). Saliva contains many relevant and useful biomarkers for diagnostic ... ...

    Abstract Although blood remains a gold standard diagnostic fluid for most health exams, it involves an unpleasant and relatively invasive sampling procedure (finger pricking or venous draw). Saliva contains many relevant and useful biomarkers for diagnostic purposes, and its collection, in contrast, is noninvasive and can be obtained with minimal effort. Current saliva analyses are, however, achieved using chromatography or lateral flow assays, which, despite their high accuracy and sensitivity, can demand expensive laboratory-based instruments operated by trained personnel or offer only semiquantitative results. In response, we investigated electrochemical aptamer-based (E-AB) biosensors, a reagentless sensing platform, to allow for continuous and real-time measurements directly in undiluted, unstimulated human whole saliva. As a proof-of-concept study, we developed E-AB biosensors capable of detecting low-molecular-weight analytes (glucose and adenosine monophosphate (AMP)). To our knowledge, we report the first E-AB sensor for glucose, an approach that is inherently independent of its chemical reactivity in contrast to home glucometers. For these three sensors, we evaluated their figures of merits, stability, and reusability over short- and long-term exposure directly in saliva. In doing so, we found that E-AB sensors allow rapid and convenient molecular measurements in whole saliva with unprecedented sensitivities in the pico- to nanomolar regime and could be regenerated and reused up to 7 days when washed and stored in phosphate-buffered saline at room temperature. We envision that salivary molecular measurements using E-AB sensors are a promising alternative to invasive techniques and can be used for improved point-of-care clinical diagnosis and at-home measurements.
    MeSH term(s) Humans ; Saliva/chemistry ; Aptamers, Nucleotide/chemistry ; Electrochemical Techniques/methods ; Biosensing Techniques/methods ; Glucose/analysis
    Chemical Substances Aptamers, Nucleotide ; Glucose (IY9XDZ35W2)
    Language English
    Publishing date 2023-11-22
    Publishing country United States
    Document type Journal Article
    ISSN 2379-3694
    ISSN (online) 2379-3694
    DOI 10.1021/acssensors.3c01624
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article: Study of mitochondrial swelling, membrane fluidity and ROS production induced by nano-TiO

    Barkhade, Tejal / Mahapatra, Santosh Kumar / Banerjee, Indrani

    Toxicology research

    2019  Volume 8, Issue 5, Page(s) 711–722

    Abstract: The potential impact of ... ...

    Abstract The potential impact of TiO
    Language English
    Publishing date 2019-07-24
    Publishing country England
    Document type Journal Article
    ZDB-ID 2684701-2
    ISSN 2045-4538 ; 2045-452X
    ISSN (online) 2045-4538
    ISSN 2045-452X
    DOI 10.1039/c9tx00143c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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