Article ; Online: Chemoselective derivatisation and ultrahigh resolution mass spectrometry for the determination of hydroxyl functional groups within complex bio-oils.
RSC advances
2023 Volume 13, Issue 26, Page(s) 17727–17741
Abstract: Bio-oils are a renewable alternative resource for the production of fine chemicals and fuels. Bio-oils are characterised by a high content of oxygenated compounds with a diverse array of different chemical functionalities. Here, we performed a chemical ... ...
Abstract | Bio-oils are a renewable alternative resource for the production of fine chemicals and fuels. Bio-oils are characterised by a high content of oxygenated compounds with a diverse array of different chemical functionalities. Here, we performed a chemical reaction to transform the hydroxyl group of the various components in a bio-oil prior to characterisation with ultrahigh resolution mass spectrometry (UHRMS). The derivatisations were first evaluated using twenty lignin-representative standards with different structural features. Our results indicate a highly chemoselective transformation of the hydroxyl group despite the presence of other functional groups. Mono- and di-acetate products were observed in acetone-acetic anhydride (acetone-Ac |
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Language | English |
Publishing date | 2023-06-12 |
Publishing country | England |
Document type | Journal Article |
ISSN | 2046-2069 |
ISSN (online) | 2046-2069 |
DOI | 10.1039/d3ra02779a |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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