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  1. Article ; Online: Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations.

    Bohnenberger, Jan / Krossing, Ingo

    Angewandte Chemie (International ed. in English)

    2020  Volume 59, Issue 14, Page(s) 5581–5585

    Abstract: The oxidation of Fe(CO) ...

    Abstract The oxidation of Fe(CO)
    Language English
    Publishing date 2020-01-24
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.201915942
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Going Homoleptic: Synthesis and Full Characterization of Stable Manganese Tetranitrosyl Cation Salts.

    Bohnenberger, Jan / Derstine, Brandon / Daub, Michael / Krossing, Ingo

    Angewandte Chemie (International ed. in English)

    2019  Volume 58, Issue 28, Page(s) 9586–9589

    Abstract: Although similar to carbon monoxide, the chemistry of homoleptic nitrogen monoxide complexes is fundamentally unexplored compared to their carbonyl analogues. Herein we report the synthesis of the first truly homoleptic transition-metal nitrosyl cation ... ...

    Abstract Although similar to carbon monoxide, the chemistry of homoleptic nitrogen monoxide complexes is fundamentally unexplored compared to their carbonyl analogues. Herein we report the synthesis of the first truly homoleptic transition-metal nitrosyl cation as the salt of the weakly coordinating anions (WCAs) [Al(OR
    Language English
    Publishing date 2019-06-05
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.201904191
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Understanding the effect of lattice polarisability on the electrochemical properties of lithium tetrahaloaluminates, LiAlX₄ (X = Cl, Br, I)

    Flores-González, Nicolás / López, Martí / Minafra, Nicolò / Bohnenberger, Jan / Viñes, Francesc / Rudić, Svemir / Krossing, Ingo / Zeier, Wolfgang G. / Illas, Francesc / Gregory, Duncan H.

    Journal of materials chemistry A. 2022 June 28, v. 10, no. 25

    2022  

    Abstract: Establishing links between the structure and physical properties of solid-state ionic conductors contributes not only to a rationale of their fundamental nature, but also provides design principles to accelerate the discovery of new materials. Lithium ... ...

    Abstract Establishing links between the structure and physical properties of solid-state ionic conductors contributes not only to a rationale of their fundamental nature, but also provides design principles to accelerate the discovery of new materials. Lithium ion conduction in complex halides is not well-elucidated and so the interplay between lattice dynamics, electronic structure, and electrochemical properties in such halides has been explored in the isostructural family of lithium tetrahaloaluminates LiAlX₄ (X = Cl, Br, I). Using a combination of experimental methods (diffuse reflectance UV-Vis spectroscopy, pulse-echo speed of sound measurements, Raman spectroscopy, inelastic neutron scattering) and periodic Density Functional Theory (DFT) based calculations, we demonstrate that softer lattices (quantified in terms of Debye frequencies or Li-phonon band centres as a function of X) provide lower activation energies for Li⁺ migration. However, the relationship between polarisability and Li⁺ conductivity is not straightforward. In line with expectations emergent from the Meyer–Neldel rule, the activation energy for Li⁺ hopping, Eₐ, and the pre-exponential terms collated as σ₀ in the Arrenhius equation for activated conductivity, correlate. It is also evident that the electrochemical oxidative potential limit correlates with the X⁻ phonon band centre in the Vibrational Density of States (VDOS) and that the Electrochemical stability Window (EW) and optical band gap are interlinked, as expected.
    Keywords Raman spectroscopy ; activation energy ; density functional theory ; electrochemistry ; equations ; lithium ; neutrons ; reflectance ; ultraviolet-visible spectroscopy
    Language English
    Dates of publication 2022-0628
    Size p. 13467-13475.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ZDB-ID 2702232-8
    ISSN 2050-7496 ; 2050-7488
    ISSN (online) 2050-7496
    ISSN 2050-7488
    DOI 10.1039/d2ta02821b
    Database NAL-Catalogue (AGRICOLA)

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  4. Article ; Online: Group 6 Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization, and Analysis of the Bonding Compared with the Isoelectronic Group 5 Hexacarbonylates.

    Bohnenberger, Jan / Kratzert, Daniel / Gorantla, Sai Manoj N V T / Pan, Sudip / Frenking, Gernot / Krossing, Ingo

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2020  Volume 26, Issue 71, Page(s) 17203–17211

    Abstract: The syntheses of the two novel complexes [Ag{Mo/W(CO) ...

    Abstract The syntheses of the two novel complexes [Ag{Mo/W(CO)
    Language English
    Publishing date 2020-11-26
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1478547-X
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.202003934
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue.

    Bohnenberger, Jan / Feuerstein, Wolfram / Himmel, Daniel / Daub, Michael / Breher, Frank / Krossing, Ingo

    Nature communications

    2019  Volume 10, Issue 1, Page(s) 624

    Abstract: Homoleptic carbonyl radical cations are a textbook family of complexes hitherto unknown in the condensed phase, leaving their properties and applications fundamentally unexplored. Here we report on two stable 17-electron [Cr(CO) ...

    Abstract Homoleptic carbonyl radical cations are a textbook family of complexes hitherto unknown in the condensed phase, leaving their properties and applications fundamentally unexplored. Here we report on two stable 17-electron [Cr(CO)
    Language English
    Publishing date 2019-02-07
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-019-08517-2
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article: Completing the triad: synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals.

    Bohnenberger, Jan / Schmitt, Manuel / Feuerstein, Wolfram / Krummenacher, Ivo / Butschke, Burkhard / Czajka, Jakub / Malinowski, Przemysław J / Breher, Frank / Krossing, Ingo

    Chemical science

    2020  Volume 11, Issue 14, Page(s) 3592–3603

    Abstract: Oxidation of M(CO) ...

    Abstract Oxidation of M(CO)
    Language English
    Publishing date 2020-03-06
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/c9sc06445a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article: Facile and systematic access to the least-coordinating WCA [(R

    Martens, Arthur / Weis, Philippe / Krummer, Michael Christian / Kreuzer, Marvin / Meierhöfer, Andreas / Meier, Stefan C / Bohnenberger, Jan / Scherer, Harald / Riddlestone, Ian / Krossing, Ingo

    Chemical science

    2018  Volume 9, Issue 35, Page(s) 7058–7068

    Abstract: By reaction of the Lewis acid ... ...

    Abstract By reaction of the Lewis acid Me
    Language English
    Publishing date 2018-08-01
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/c8sc02591f
    Database MEDical Literature Analysis and Retrieval System OnLINE

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