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  1. Article ; Online: That Table of Contents Image Looks Really Interesting: *Click*!

    Buriak, Jillian M

    ACS nano

    2023  Volume 17, Issue 15, Page(s) 14189–14191

    Language English
    Publishing date 2023-08-08
    Publishing country United States
    Document type Editorial
    ISSN 1936-086X
    ISSN (online) 1936-086X
    DOI 10.1021/acsnano.3c06220
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: First Impressions of

    Buriak, Jillian M

    ACS nano

    2022  Volume 16, Issue 12, Page(s) 19609–19611

    Language English
    Publishing date 2022-12-27
    Publishing country United States
    Document type Editorial
    ISSN 1936-086X
    ISSN (online) 1936-086X
    DOI 10.1021/acsnano.2c11900
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: ACS Nano

    Buriak, Jillian M

    ACS nano

    2020  Volume 14, Issue 10, Page(s) 12263–12264

    Language English
    Publishing date 2020-10-26
    Publishing country United States
    Document type Editorial
    ISSN 1936-086X
    ISSN (online) 1936-086X
    DOI 10.1021/acsnano.0c08327
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: ACS Applied Materials & Interfaces and Chemistry of Materials To Exclusively Publish Full Articles in 2019

    Buriak, Jillian M / Schanze, Kirk S

    ACS applied materials & interfaces

    2019  Volume 11, Issue 5, Page(s) 4703–4704

    Language English
    Publishing date 2019-01-29
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.9b00304
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Best Practices for Simulations and Calculations of Nanomaterials for Energy Applications: Avoiding "Garbage In, Garbage Out".

    Salanne, Mathieu / Buriak, Jillian M / Chen, Xiaodong / Chueh, William / Hersam, Mark C / Schaak, Raymond E

    ACS nano

    2023  Volume 17, Issue 7, Page(s) 6147–6149

    Language English
    Publishing date 2023-04-11
    Publishing country United States
    Document type Editorial
    ISSN 1936-086X
    ISSN (online) 1936-086X
    DOI 10.1021/acsnano.3c02368
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Our 2019 Virtual Issue: Methods and Protocols in Materials Science.

    Buriak, Jillian M / Kaplan, David L

    ACS biomaterials science & engineering

    2019  Volume 5, Issue 5, Page(s) 2052–2053

    Language English
    Publishing date 2019-04-23
    Publishing country United States
    Document type Editorial
    ISSN 2373-9878
    ISSN (online) 2373-9878
    DOI 10.1021/acsbiomaterials.9b00506
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article: Mixing, Domains, and Fast Li-Ion Dynamics in Ternary Li–Sb–Bi Battery Anode Alloys

    Kalisvaart, W. Peter / Chaudhary, Madhusudan / Bhattacharya, Amit / Michaelis, Vladimir K. / Buriak, Jillian M.

    Journal of physical chemistry. 2022 Feb. 01, v. 126, no. 5

    2022  

    Abstract: Both antimony and bismuth can alloy with up to three molar equivalents of lithium and are therefore attractive candidates for replacing graphite in Li-ion battery anodes. Li₃Sb and Li₃Bi have the same cubic structure (Fm3̅m), but the ternary Li–Sb–Bi ... ...

    Abstract Both antimony and bismuth can alloy with up to three molar equivalents of lithium and are therefore attractive candidates for replacing graphite in Li-ion battery anodes. Li₃Sb and Li₃Bi have the same cubic structure (Fm3̅m), but the ternary Li–Sb–Bi system has not been studied. We synthesized Li₃(SbₓBi₁–ₓ) with different Sb mole fractions at room temperature by ball milling. These ternary alloys all have cubic crystal structures, as determined by X-ray diffraction (XRD), but show a tendency toward phase segregation for x = 0.25 and 0.50. For x = 0.25, the lattice parameter presents a clear positive deviation from Vegard’s law in XRD, while for x = 0.50, XRD reveals two phases after milling, with the Bi-rich minority phase diminishing after thermal annealing. Solid-state nuclear magnetic resonance spectroscopy provides evidence for a Sb-enriched environment around the Li atoms for Li₃Sb₀.₂₅Bi₀.₇₅, and nuclear spin–lattice relaxation measurements of the binary and ternary alloy phases point to low activation energies and rapid Li-ion diffusion in Li₃Bi.
    Keywords alloys ; ambient temperature ; anodes ; antimony ; bismuth ; graphene ; lithium ; lithium batteries ; nuclear magnetic resonance spectroscopy
    Language English
    Dates of publication 2022-0201
    Size p. 2394-2402.
    Publishing place American Chemical Society
    Document type Article
    ISSN 1932-7455
    DOI 10.1021/acs.jpcc.1c09785
    Database NAL-Catalogue (AGRICOLA)

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  8. Article: Reconsidering X-ray Photoelectron Spectroscopy Quantification of Substitution Levels of Monolayers on Unoxidized Silicon Surfaces

    Hu, Minjia / Luber, Erik J / Buriak, Jillian M

    Journal of physical chemistry. 2020 June 30, v. 124, no. 30

    2020  

    Abstract: The covalent functionalization of unoxidized silicon surfaces is of interest for a wide range of applications and for fundamental studies linking surface functionalization and electronic properties. Determination of the level of substitution (yield) of a ...

    Abstract The covalent functionalization of unoxidized silicon surfaces is of interest for a wide range of applications and for fundamental studies linking surface functionalization and electronic properties. Determination of the level of substitution (yield) of a reaction on a silicon surface is necessary as the number of functional groups bound to the surface is directly linked to properties. X-ray photoelectron spectroscopy, XPS, is the most common analytical method for determining the substitution level of the chemical handle on the silicon surface, typically a Si–H or Si–Cl bond, through which a new stable bond is formed to link the molecule to the surface. Calculations using the atomic ratio of carbon to silicon, as determined by XPS, do not take into account the effect of adventitious hydrocarbons and retained solvent, and the substitution level is typically measured by first assuming 100% substitution of a fictitious hydrocarbon layer with an effective thickness determined by the XPS intensity ratio of C to Si; the actual substitution level is then taken as the ratio of the effective thickness to the theoretical height of the molecule. In this work, we present an alternative and more physically meaningful approach to deriving expressions for the substitution level that is based on the proportionality of the photoelectron attenuation length to the substitution level. For all-hydrocarbon molecules grafted to a silicon surface, this new approach yields the same equations for substitution levels as an earlier effective thickness model. More importantly, unlike the effective thickness models, this method can be extended to include molecules with a heteroatom “tag”, such as fluorine and chalcogenides, for determining coverage by XPS. The use of the heteroatomic tags is shown to provide a greater degree of certainty with respect to calculating the coverage on silicon. We finish with a simple flowchart to guide the reader to the appropriate equation for both Si(111) and Si(100) surfaces.
    Keywords X-ray photoelectron spectroscopy ; carbon ; equations ; fluorine ; models ; silicon ; solvents
    Language English
    Dates of publication 2020-0630
    Size p. 16461-16477.
    Publishing place American Chemical Society
    Document type Article
    Note NAL-AP-2-clean
    ISSN 1932-7455
    DOI 10.1021/acs.jpcc.0c04101
    Database NAL-Catalogue (AGRICOLA)

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  9. Article ; Online: Open the floodgates for online feedback on scientific papers? Not so fast.

    Buriak, Jillian M

    ACS nano

    2013  Volume 7, Issue 1, Page(s) 1–2

    MeSH term(s) Information Dissemination ; Internet ; Nanotechnology ; Peer Review ; Periodicals as Topic ; Publishing
    Language English
    Publishing date 2013-01-22
    Publishing country United States
    Document type Editorial
    ISSN 1936-086X
    ISSN (online) 1936-086X
    DOI 10.1021/nn400152h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article: Kinetics of Plasmon-Driven Hydrosilylation of Silicon Surfaces: Photogenerated Charges Drive Silicon–Carbon Bond Formation

    Rao, Chengcheng / Olsen, Brian C. / Luber, Erik J. / Buriak, Jillian M.

    Journal of physical chemistry. 2021 Aug. 09, v. 125, no. 32

    2021  

    Abstract: Optically transparent PDMS stamps coated with a layer of gold nanoparticles were employed as plasmonic stamps to drive surface chemistry on silicon surfaces. Illumination of a sandwich of plasmonic stamps, an alkene ink, and hydride-terminated silicon ... ...

    Abstract Optically transparent PDMS stamps coated with a layer of gold nanoparticles were employed as plasmonic stamps to drive surface chemistry on silicon surfaces. Illumination of a sandwich of plasmonic stamps, an alkene ink, and hydride-terminated silicon with green light of a moderate intensity drives hydrosilylation on the surface. The key to the mechanism of hydrosilylation is the presence of holes at the Si–H-terminated interface, which is followed by attack by a proximal alkene and formation of a silicon–carbon bond. In this study, detailed kinetic studies of hydrosilylation on silicon with different doping levels, n++, p++, n, p, and intrinsic, were carried out to provide further insights into the role of the metal–insulator–semiconductor junction that is set up during the stamping. Moderately doped n-type and p-type silicon are found to have the fastest rate of hydrosilylation, approximately 10 times faster than highly doped n++ and p++ silicon and about 20 times faster than intrinsic silicon. The kinetic studies were correlated with the properties of the moderately doped silicon substrates, and they point to the near-optimal convergence of factors in moderately doped silicon that result in the fastest observed rates of hydrosilylation. Moderately doped silicon has a sufficiently large depletion width and built-in field that result in most photogenerated holes in the bulk being swept to the surface while also being able to separate electron–hole pairs generated by the intense E-field of the gold nanoparticle LSPR. These conditions lead to the highest concentration of holes at the silicon surface and highest rates of hydrosilylation.
    Keywords green light ; lighting ; nanogold ; silicon
    Language English
    Dates of publication 2021-0809
    Size p. 17983-17992.
    Publishing place American Chemical Society
    Document type Article
    ISSN 1932-7455
    DOI 10.1021/acs.jpcc.1c04738
    Database NAL-Catalogue (AGRICOLA)

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