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  1. Article: Behavior of Ternary Mixtures of Hydrogen Bond Acceptors and Donors in Terms of Band Gap Energies.

    Mannu, Alberto / Cardano, Francesca / Baldino, Salvatore / Fin, Andrea

    Materials (Basel, Switzerland)

    2021  Volume 14, Issue 12

    Abstract: Three ternary mixtures composed by choline chloride (ChCl), ethylene glycol (EG), and a second hydrogen bond donor (HBD) as ethanol (A), 2-propanol (B), and glycerol (C) were studied in terms of composition related to the band gap energy (BGE). A Design ... ...

    Abstract Three ternary mixtures composed by choline chloride (ChCl), ethylene glycol (EG), and a second hydrogen bond donor (HBD) as ethanol (A), 2-propanol (B), and glycerol (C) were studied in terms of composition related to the band gap energy (BGE). A Design of Experiments (DoE) approach, and in particular a
    Language English
    Publishing date 2021-06-20
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2487261-1
    ISSN 1996-1944
    ISSN 1996-1944
    DOI 10.3390/ma14123418
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Imidazo[1,5-

    Renno, Giacomo / Cardano, Francesca / Volpi, Giorgio / Barolo, Claudia / Viscardi, Guido / Fin, Andrea

    Molecules (Basel, Switzerland)

    2022  Volume 27, Issue 12

    Abstract: Imidazo[1,5- ...

    Abstract Imidazo[1,5-
    MeSH term(s) Fluorescent Dyes/chemistry ; Lipid Bilayers ; Liposomes ; Pyridines/chemistry ; Solvents/chemistry
    Chemical Substances Fluorescent Dyes ; Lipid Bilayers ; Liposomes ; Pyridines ; Solvents
    Language English
    Publishing date 2022-06-16
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules27123856
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Spiropyrans for light-controlled drug delivery.

    Cardano, Francesca / Del Canto, Elisa / Giordani, Silvia

    Dalton transactions (Cambridge, England : 2003)

    2019  Volume 48, Issue 41, Page(s) 15537–15544

    Abstract: The supramolecular assembly of acetylsalicylic acid to a merocyanine-Zn complex translates into a photo-controllable drug delivery system. Herein, we present the synthesis and spectroscopic analysis of a three-component assembly combining a spiropyran ... ...

    Abstract The supramolecular assembly of acetylsalicylic acid to a merocyanine-Zn complex translates into a photo-controllable drug delivery system. Herein, we present the synthesis and spectroscopic analysis of a three-component assembly combining a spiropyran derivative, a zinc(ii) cation, and acetylsalicylic acid. The ON/OFF system can be modulated by safe and easily affordable stimuli, for the specific delivery of more than one active compound. Our results confirm the formation of a ternary system in solution, where the behaviour is dominated by photo-induced responses, and pave the way for the use of such smart platforms for medicinal chemistry purposes.
    MeSH term(s) Aspirin/chemistry ; Benzopyrans/chemistry ; Drug Carriers/chemistry ; Indoles/chemistry ; Light ; Nitro Compounds/chemistry ; Photochemical Processes ; Zinc/chemistry
    Chemical Substances Benzopyrans ; Drug Carriers ; Indoles ; Nitro Compounds ; spiropyran ; Zinc (J41CSQ7QDS) ; Aspirin (R16CO5Y76E)
    Language English
    Publishing date 2019-07-24
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c9dt02092f
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Photo-Responsive Graphene and Carbon Nanotubes to Control and Tackle Biological Systems.

    Cardano, Francesca / Frasconi, Marco / Giordani, Silvia

    Frontiers in chemistry

    2018  Volume 6, Page(s) 102

    Abstract: Photo-responsive multifunctional nanomaterials are receiving considerable attention for biological applications because of their unique properties. The functionalization of the surface of carbon nanotubes (CNTs) and graphene, among other carbon based ... ...

    Abstract Photo-responsive multifunctional nanomaterials are receiving considerable attention for biological applications because of their unique properties. The functionalization of the surface of carbon nanotubes (CNTs) and graphene, among other carbon based nanomaterials, with molecular switches that exhibit reversible transformations between two or more isomers in response to different kind of external stimuli, such as electromagnetic radiation, temperature and pH, has allowed the control of the optical and electrical properties of the nanomaterial. Light-controlled molecular switches, such as azobenzene and spiropyran, have attracted a lot of attention for nanomaterial's functionalization because of the remote modulation of their physicochemical properties using light stimulus. The enhanced properties of the hybrid materials obtained from the coupling of carbon based nanomaterials with light-responsive switches has enabled the fabrication of smart devices for various biological applications, including drug delivery, bioimaging and nanobiosensors. In this review, we highlight the properties of photo-responsive carbon nanomaterials obtained by the conjugation of CNTs and graphene with azobenzenes and spiropyrans molecules to investigate biological systems, devising possible future directions in the field.
    Language English
    Publishing date 2018-04-12
    Publishing country Switzerland
    Document type Journal Article ; Review
    ZDB-ID 2711776-5
    ISSN 2296-2646
    ISSN 2296-2646
    DOI 10.3389/fchem.2018.00102
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Ratiometric temperature sensing with fluorescent thermochromic switches.

    Mazza, Mercedes M A / Cardano, Francesca / Cusido, Janet / Baker, James D / Giordani, Silvia / Raymo, Françisco M

    Chemical communications (Cambridge, England)

    2019  Volume 55, Issue 8, Page(s) 1112–1115

    Abstract: The connection of fluorescent chromophores to switchable heterocycles translates into molecular probes with ratiometric response to temperature. The opening and closing of their heterocyclic component equilibrates two emissive species with resolved ... ...

    Abstract The connection of fluorescent chromophores to switchable heterocycles translates into molecular probes with ratiometric response to temperature. The opening and closing of their heterocyclic component equilibrates two emissive species with resolved fluorescence. Their relative emission intensities change monotonically with temperature to enable the visualization of thermal distributions at the microscale.
    Language English
    Publishing date 2019-01-09
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/c8cc09482a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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