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  1. Article ; Online: Nitrogen availability in biochar-based fertilizers depending on activation treatment and nitrogen source.

    Castejón-Del Pino, Raúl / Cayuela, María L / Sánchez-García, María / Sánchez-Monedero, Miguel A

    Waste management (New York, N.Y.)

    2023  Volume 158, Page(s) 76–83

    Abstract: Different activation and N-doping treatments were used to produce biochar-based fertilizers (BBFs) with increased N concentration and slow N release. Pristine biochars were produced by pyrolysis of olive tree pruning feedstock at low and high ... ...

    Abstract Different activation and N-doping treatments were used to produce biochar-based fertilizers (BBFs) with increased N concentration and slow N release. Pristine biochars were produced by pyrolysis of olive tree pruning feedstock at low and high temperatures (400 and 800 °C). These biochars were activated either by ultrasonication, or oxidation with hydrogen peroxide (H
    MeSH term(s) Fertilizers/analysis ; Nitrogen ; Hydrogen Peroxide ; Charcoal ; Soil ; Urea ; Water
    Chemical Substances biochar ; Fertilizers ; Nitrogen (N762921K75) ; Hydrogen Peroxide (BBX060AN9V) ; Charcoal (16291-96-6) ; Soil ; Urea (8W8T17847W) ; Water (059QF0KO0R)
    Language English
    Publishing date 2023-01-13
    Publishing country United States
    Document type Journal Article
    ZDB-ID 2001471-5
    ISSN 1879-2456 ; 0956-053X
    ISSN (online) 1879-2456
    ISSN 0956-053X
    DOI 10.1016/j.wasman.2023.01.007
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Nitrogen availability in biochar-based fertilizers depending on activation treatment and nitrogen source

    Castejón-del Pino, Raúl / Cayuela, María L. / Sánchez-García, María / Sánchez-Monedero, Miguel A.

    Waste Management. 2023 Mar., v. 158 p.76-83

    2023  

    Abstract: Different activation and N-doping treatments were used to produce biochar-based fertilizers (BBFs) with increased N concentration and slow N release. Pristine biochars were produced by pyrolysis of olive tree pruning feedstock at low and high ... ...

    Abstract Different activation and N-doping treatments were used to produce biochar-based fertilizers (BBFs) with increased N concentration and slow N release. Pristine biochars were produced by pyrolysis of olive tree pruning feedstock at low and high temperatures (400 and 800 °C). These biochars were activated either by ultrasonication, or oxidation with hydrogen peroxide (H₂O₂) or nitric acid (HNO₃) to increase their N retention potential. Subsequently biochars were enriched with N with either urea or ammonium sulfate. The activation of low-temperature biochars with HNO₃ was the most effective treatment leading to new surface carboxylic groups that facilitated the later enrichment with N. When treated with urea, BBFs reached 7.0 N%, whereas the H₂O₂ activation only allowed an increase up to 2.0 N%. The use of urea as the external N source was the most efficient for incorporating N. Urea treated biochars had a water-soluble fraction that represented up to 14.5 % of the total N. The hydrolyzable N fraction, composed by amides and simple N heterocycles originated by the N-doping treatments, and nitro groups generated from HNO₃ activation, represented up to 60 % of the total N. This study relates the N chemical forms in the new BBFs to potential N availability in soil. The presence of water-soluble, hydrolyzable and non-hydrolyzable N implied that these BBFs may supply N that would be progressively available for plants, acting as slow-release fertilizers.
    Keywords Olea europaea ; ammonium sulfate ; biochar ; feedstocks ; heterocyclic compounds ; hydrogen peroxide ; nitric acid ; nitrogen ; oxidation ; pyrolysis ; soil ; total nitrogen ; ultrasonic treatment ; urea ; waste management ; water solubility ; Agricultural waste ; Olive tree pruning ; N-doped biochar ; Available N ; Nitrogen use efficiency ; Oxidizing treatment
    Language English
    Dates of publication 2023-03
    Size p. 76-83.
    Publishing place Elsevier Ltd
    Document type Article ; Online
    Note Use and reproduction
    ZDB-ID 2001471-5
    ISSN 1879-2456 ; 0956-053X
    ISSN (online) 1879-2456
    ISSN 0956-053X
    DOI 10.1016/j.wasman.2023.01.007
    Database NAL-Catalogue (AGRICOLA)

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