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  1. Article ; Online: Modeling and correction of image drift in dynamic shadowgraphy experiments.

    Castellini, Stefano / Brizioli, Matteo / Giraudet, Cédric / Carpineti, Marina / Croccolo, Fabrizio / Giavazzi, Fabio / Vailati, Alberto

    The European physical journal. E, Soft matter

    2024  Volume 47, Issue 4, Page(s) 25

    Abstract: The study of phoretic transport phenomena under non-stationary conditions presents several challenges, mostly related to the stability of the experimental apparatus. This is particularly true when investigating with optical means the subtle temperature ... ...

    Abstract The study of phoretic transport phenomena under non-stationary conditions presents several challenges, mostly related to the stability of the experimental apparatus. This is particularly true when investigating with optical means the subtle temperature and concentration fluctuations that arise during diffusion processes, superimposed to the macroscopic state of the system. Under these conditions, the tenuous signal from fluctuations is easily altered by the presence of artifacts. Here, we address an experimental issue frequently reported in the investigation by means of dynamic shadowgraphy of the non-equilibrium fluctuations arising in liquid mixtures under non-stationary conditions, such as those arising after the imposition or removal of a thermal stress, where experiments show systematically the presence of a spurious contribution in the reconstructed structure function of the fluctuations, which depends quadratically from the time delay. We clarify the mechanisms responsible for this artifact, showing that it is caused by the imperfect alignment of the sample cell with respect to gravity, which couples the temporal evolution of the concentration profile within the sample with the optical signal collected by the shadowgraph diagnostics. We propose a data analysis protocol that enables disentangling the spurious contributions and the genuine dynamics of the fluctuations, which can be thus reliably reconstructed.
    Language English
    Publishing date 2024-04-08
    Publishing country France
    Document type Journal Article
    ZDB-ID 2004003-9
    ISSN 1292-895X ; 1292-8941
    ISSN (online) 1292-895X
    ISSN 1292-8941
    DOI 10.1140/epje/s10189-024-00413-y
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Dynamics of non-equilibrium concentration fluctuations during free-diffusion in highly stratified solutions of glycerol and water.

    Castellini, Stefano / Carpineti, Marina / Giraudet, Cédric / Croccolo, Fabrizio / Vailati, Alberto

    The Journal of chemical physics

    2023  Volume 158, Issue 24

    Abstract: We investigate the non-equilibrium fluctuations occurring during free diffusion between two solutions of glycerol and water with various concentration differences. The non-linearity of the system, determined by the strong stratification of the sample, ... ...

    Abstract We investigate the non-equilibrium fluctuations occurring during free diffusion between two solutions of glycerol and water with various concentration differences. The non-linearity of the system, determined by the strong stratification of the sample, requires introducing an interpretation model able to characterize the dependence of the correlation properties of the non-equilibrium fluctuations on the local thermophysical variables of the system. The proposed model allows us to characterize the dynamics of non-equilibrium fluctuations in the presence of a wide range of relaxation times determined by the strong stratification of the sample, at variance with the cumulant methods commonly used in dynamic light scattering experiments, which work well in the presence of a moderate dispersion of relaxation times.
    MeSH term(s) Water ; Glycerol ; Diffusion ; Solutions
    Chemical Substances Water (059QF0KO0R) ; Glycerol (PDC6A3C0OX) ; Solutions
    Language English
    Publishing date 2023-06-23
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3113-6
    ISSN 1089-7690 ; 0021-9606
    ISSN (online) 1089-7690
    ISSN 0021-9606
    DOI 10.1063/5.0151752
    Database MEDical Literature Analysis and Retrieval System OnLINE

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