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  1. Article ; Online: Holistic Approach toward a Damage-Less Sputtered Indium Tin Oxide Barrier Layer for High-Stability Inverted Perovskite Solar Cells and Modules.

    Reddy, Sathy Harshavardhan / Di Giacomo, Francesco / Matteocci, Fabio / Castriotta, Luigi Angelo / Di Carlo, Aldo

    ACS applied materials & interfaces

    2022  Volume 14, Issue 45, Page(s) 51438–51448

    Abstract: The commercialization of perovskite solar cells (PSCs) requires the development of long-term, highly operational-stable devices. An efficient barrier layer plays a key role in improving the device stability of planar PSCs. Here, we focus on the use of ... ...

    Abstract The commercialization of perovskite solar cells (PSCs) requires the development of long-term, highly operational-stable devices. An efficient barrier layer plays a key role in improving the device stability of planar PSCs. Here, we focus on the use of sputtered indium tin oxide (ITO) as a barrier layer to stop major degradations. To mitigate efficiency losses of cells with the ITO barrier, we optimized various sputtering process parameters such as ITO layer thickness, target power density, and working pressure. The fabricated planar inverted PSCs based on the novel ITO barrier optimization demonstrate a power conversion efficiency (PCE) of 19.05% on a cell area of 0.09 cm
    Language English
    Publishing date 2022-11-02
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.2c10251
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Flexible, Transparent, and Bifacial Perovskite Solar Cells and Modules Using the Wide-Band Gap FAPbBr

    Jafarzadeh, Farshad / Castriotta, Luigi Angelo / Legrand, Marie / Ory, Daniel / Cacovich, Stefania / Skafi, Zeynab / Barichello, Jessica / De Rossi, Francesca / Di Giacomo, Francesco / Di Carlo, Aldo / Brown, Thomas / Brunetti, Francesca / Matteocci, Fabio

    ACS applied materials & interfaces

    2024  Volume 16, Issue 14, Page(s) 17607–17616

    Abstract: Perovskite solar cells (PSCs) offer impressive performance and flexibility, thanks to their simple, low-temperature deposition methods. Their band gap tunability allows for a wide range of applications, transitioning from opaque to transparent devices. ... ...

    Abstract Perovskite solar cells (PSCs) offer impressive performance and flexibility, thanks to their simple, low-temperature deposition methods. Their band gap tunability allows for a wide range of applications, transitioning from opaque to transparent devices. This study introduces the first flexible, bifacial PSCs using the FAPbBr
    Language English
    Publishing date 2024-04-01
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.4c01071
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Laser-Scribing Optimization for Sprayed SnO

    Taheri, Babak / De Rossi, Francesca / Lucarelli, Giulia / Castriotta, Luigi Angelo / Di Carlo, Aldo / Brown, Thomas M / Brunetti, Francesca

    ACS applied energy materials

    2021  Volume 4, Issue 5, Page(s) 4507–4518

    Abstract: Flexible perovskite solar cells (FPSCs) are prime candidates for applications requiring a highly efficient, low-cost, lightweight, thin, and even foldable power source. Despite record efficiencies of lab-scale flexible devices (19.5% on a 0.1 ... ...

    Abstract Flexible perovskite solar cells (FPSCs) are prime candidates for applications requiring a highly efficient, low-cost, lightweight, thin, and even foldable power source. Despite record efficiencies of lab-scale flexible devices (19.5% on a 0.1 cm
    Language English
    Publishing date 2021-05-05
    Publishing country United States
    Document type Journal Article
    ISSN 2574-0962
    ISSN (online) 2574-0962
    DOI 10.1021/acsaem.1c00140
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Light-Stable Methylammonium-Free Inverted Flexible Perovskite Solar Modules on PET Exceeding 10.5% on a 15.7 cm² Active Area

    Castriotta, Luigi Angelo / Fuentes Pineda, Rosinda / Babu, Vivek / Spinelli, Pierpaolo / Taheri, Babak / Matteocci, Fabio / Brunetti, Francesca / Wojciechowski, Konrad / Di Carlo, Aldo

    ACS applied materials & interfaces. 2021 June 16, v. 13, no. 25

    2021  

    Abstract: Perovskite solar modules (PSMs) have been attracting the photovoltaic market, owing to low manufacturing costs and process versatility. The employment of flexible substrates gives the chance to explore new applications and further increase the ... ...

    Abstract Perovskite solar modules (PSMs) have been attracting the photovoltaic market, owing to low manufacturing costs and process versatility. The employment of flexible substrates gives the chance to explore new applications and further increase the fabrication throughput. However, the present state-of-the-art of flexible perovskite solar modules (FPSMs) does not show any data on light-soaking stability, revealing that the scientific community is still far from the potential marketing of the product. During this work, we demonstrate, for the first time, an outstanding light stability of FPSMs over 1000 h considering the recovering time (T₈₀ = 730 h), exhibiting a power conversion efficiency (PCE) of 10.51% over a 15.7 cm² active area obtained with scalable processes by exploiting blade deposition of a transporting layer and a stable double-cation perovskite (cesium and formamidinium, CsFA) absorber.
    Keywords cesium ; markets ; photostability
    Language English
    Dates of publication 2021-0616
    Size p. 29576-29584.
    Publishing place American Chemical Society
    Document type Article
    ISSN 1944-8252
    DOI 10.1021/acsami.1c05506
    Database NAL-Catalogue (AGRICOLA)

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  5. Article ; Online: Light-Stable Methylammonium-Free Inverted Flexible Perovskite Solar Modules on PET Exceeding 10.5% on a 15.7 cm

    Castriotta, Luigi Angelo / Fuentes Pineda, Rosinda / Babu, Vivek / Spinelli, Pierpaolo / Taheri, Babak / Matteocci, Fabio / Brunetti, Francesca / Wojciechowski, Konrad / Di Carlo, Aldo

    ACS applied materials & interfaces

    2021  

    Abstract: Perovskite solar modules (PSMs) have been attracting the photovoltaic market, owing to low manufacturing costs and process versatility. The employment of flexible substrates gives the chance to explore new applications and further increase the ... ...

    Abstract Perovskite solar modules (PSMs) have been attracting the photovoltaic market, owing to low manufacturing costs and process versatility. The employment of flexible substrates gives the chance to explore new applications and further increase the fabrication throughput. However, the present state-of-the-art of flexible perovskite solar modules (FPSMs) does not show any data on light-soaking stability, revealing that the scientific community is still far from the potential marketing of the product. During this work, we demonstrate, for the first time, an outstanding light stability of FPSMs over 1000 h considering the recovering time (
    Language English
    Publishing date 2021-06-16
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.1c05506
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Doping Strategy for Efficient and Stable Triple Cation Hybrid Perovskite Solar Cells and Module Based on Poly(3-hexylthiophene) Hole Transport Layer.

    Yaghoobi Nia, Narges / Lamanna, Enrico / Zendehdel, Mahmoud / Palma, Alessandro L / Zurlo, Francesca / Castriotta, Luigi Angelo / Di Carlo, Aldo

    Small (Weinheim an der Bergstrasse, Germany)

    2019  Volume 15, Issue 49, Page(s) e1904399

    Abstract: As the hole transport layer (HTL) for perovskite solar cells (PSCs), poly(3-hexylthiophene) (P3HT) has been attracting great interest due to its low-cost, thermal stability, oxygen impermeability, and strong hydrophobicity. In this work, a new doping ... ...

    Abstract As the hole transport layer (HTL) for perovskite solar cells (PSCs), poly(3-hexylthiophene) (P3HT) has been attracting great interest due to its low-cost, thermal stability, oxygen impermeability, and strong hydrophobicity. In this work, a new doping strategy is developed for P3HT as the HTL in triple-cation/double-halide ((FA
    Language English
    Publishing date 2019-10-08
    Publishing country Germany
    Document type Journal Article
    ISSN 1613-6829
    ISSN (online) 1613-6829
    DOI 10.1002/smll.201904399
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Book ; Online: Matching the photocurrent of perovskite/organic tandem solar modules by varying the cell width

    Cerrillo, Jose Garcia / Distler, Andreas / Matteocci, Fabio / Forberich, Karen / Wagner, Michael / Basu, Robin / Castriotta, Luigi Angelo / Jafarzadeh, Farshad / Brunetti, Francesca / Yang, Fu / Li, Ning / Mendoza, Asiel Neftali Corpus / Di Carlo, Aldo / Brabec, Christoph J. / Egelhaaf, Hans-Joachim

    2023  

    Abstract: Photocurrent matching in conventional monolithic tandem solar cells is achieved by choosing semiconductors with complementary absorption spectra and by carefully adjusting the optical properties of the complete top and bottom stacks. However, for thin ... ...

    Abstract Photocurrent matching in conventional monolithic tandem solar cells is achieved by choosing semiconductors with complementary absorption spectra and by carefully adjusting the optical properties of the complete top and bottom stacks. However, for thin film photovoltaic technologies at the module level, another design variable significantly alleviates the task of photocurrent matching, namely the cell width, whose modification can be readily realized by the adjustment of the module layout. Herein we demonstrate this concept at the experimental level for the first time for a 2T-mechanically stacked perovskite (FAPbBr3)/organic (PM6:Y6:PCBM) tandem mini-module, an unprecedented approach for these emergent photovoltaic technologies fabricated in an independent manner. An excellent Isc matching is achieved by tuning the cell widths of the perovskite and organic modules to 7.22 mm (PCEPVKT-mod= 6.69%) and 3.19 mm (PCEOPV-mod= 12.46%), respectively, leading to a champion efficiency of 14.94% for the tandem module interconnected in series with an aperture area of 20.25 cm2. Rather than demonstrating high efficiencies at the level of small lab cells, our successful experimental proof-of-concept at the module level proves to be particularly useful to couple devices with non-complementary semiconductors, either in series or in parallel electrical connection, hence overcoming the limitations imposed by the monolithic structure.
    Keywords Condensed Matter - Materials Science ; Physics - Applied Physics
    Subject code 600
    Publishing date 2023-09-22
    Publishing country us
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  8. Article ; Online: Author Correction: A universal co-solvent dilution strategy enables facile and cost-effective fabrication of perovskite photovoltaics.

    Zhang, Hong / Darabi, Kasra / Nia, Narges Yaghoobi / Krishna, Anurag / Ahlawat, Paramvir / Guo, Boyu / Almalki, Masaud Hassan S / Su, Tzu-Sen / Ren, Dan / Bolnykh, Viacheslav / Castriotta, Luigi Angelo / Zendehdel, Mahmoud / Pan, Linfeng / Alonso, Sandy Sanchez / Li, Ruipeng / Zakeeruddin, Shaik M / Hagfeldt, Anders / Rothlisberger, Ursula / Di Carlo, Aldo /
    Amassian, Aram / Grätzel, Michael

    Nature communications

    2022  Volume 13, Issue 1, Page(s) 7726

    Language English
    Publishing date 2022-12-13
    Publishing country England
    Document type Published Erratum
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-022-35132-5
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: A universal co-solvent dilution strategy enables facile and cost-effective fabrication of perovskite photovoltaics.

    Zhang, Hong / Darabi, Kasra / Nia, Narges Yaghoobi / Krishna, Anurag / Ahlawat, Paramvir / Guo, Boyu / Almalki, Masaud Hassan S / Su, Tzu-Sen / Ren, Dan / Bolnykh, Viacheslav / Castriotta, Luigi Angelo / Zendehdel, Mahmoud / Pan, Lingfeng / Alonso, Sandy Sanchez / Li, Ruipeng / Zakeeruddin, Shaik M / Hagfeldt, Anders / Rothlisberger, Ursula / Di Carlo, Aldo /
    Amassian, Aram / Grätzel, Michael

    Nature communications

    2022  Volume 13, Issue 1, Page(s) 89

    Abstract: Cost management and toxic waste generation are two key issues that must be addressed before the commercialization of perovskite optoelectronic devices. We report a groundbreaking strategy for eco-friendly and cost-effective fabrication of highly ... ...

    Abstract Cost management and toxic waste generation are two key issues that must be addressed before the commercialization of perovskite optoelectronic devices. We report a groundbreaking strategy for eco-friendly and cost-effective fabrication of highly efficient perovskite solar cells. This strategy involves the usage of a high volatility co-solvent, which dilutes perovskite precursors to a lower concentration (<0.5 M) while retaining similar film quality and device performance as a high concentration (>1.4 M) solution. More than 70% of toxic waste and material cost can be reduced. Mechanistic insights reveal ultra-rapid evaporation of the co-solvent together with beneficial alteration of the precursor colloidal chemistry upon dilution with co-solvent, which in-situ studies and theoretical simulations confirm. The co-solvent tuned precursor colloidal properties also contribute to the enhancement of the stability of precursor solution, which extends its processing window thus minimizing the waste. This strategy is universally successful across different perovskite compositions, and scales from small devices to large-scale modules using industrial spin-coating, potentially easing the lab-to-fab translation of perovskite technologies.
    Language English
    Publishing date 2022-01-10
    Publishing country England
    Document type Journal Article
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-021-27740-4
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Fabrication and Morphological Characterization of High-Efficiency Blade-Coated Perovskite Solar Modules.

    Matteocci, Fabio / Vesce, Luigi / Kosasih, Felix Utama / Castriotta, Luigi Angelo / Cacovich, Stefania / Palma, Alessandro Lorenzo / Divitini, Giorgio / Ducati, Caterina / Di Carlo, Aldo

    ACS applied materials & interfaces

    2019  Volume 11, Issue 28, Page(s) 25195–25204

    Abstract: Organo-metal halide perovskite demonstrates a large potential for achieving highly efficient photovoltaic devices. The scaling-up process represents one of the major challenges to exploit this technology at the industrial level. Here, the scaling-up of ... ...

    Abstract Organo-metal halide perovskite demonstrates a large potential for achieving highly efficient photovoltaic devices. The scaling-up process represents one of the major challenges to exploit this technology at the industrial level. Here, the scaling-up of perovskite solar modules from 5 × 5 to 10 × 10 cm
    Language English
    Publishing date 2019-07-03
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.9b05730
    Database MEDical Literature Analysis and Retrieval System OnLINE

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