Article ; Online: Toward the Design and Construction of Supramolecular Functional Molecular Materials Based on Metal-Metal Interactions.
Journal of the American Chemical Society
2022
Abstract: Supramolecular functional materials represent an emerging class of materials that have been governed by the supramolecular chemistry of self-assembled molecules. Such high-order molecular hierarchies have been stabilized by various kinds of noncovalent ... ...
Abstract | Supramolecular functional materials represent an emerging class of materials that have been governed by the supramolecular chemistry of self-assembled molecules. Such high-order molecular hierarchies have been stabilized by various kinds of noncovalent intermolecular forces including hydrogen bonding, electrostatic, donor-acceptor, π-π stacking interactions, and dispersion forces. Recently, metal-metal interactions have also emerged as an unconventional type of noncovalent interaction that is unique in the metal complex system for the construction of self-assembled metal-based materials. These metal-metal interactions have further imparted the self-assembled materials with rich spectroscopic functionalities. However, the systematic control of these hierarchical architectures through metal-metal interactions remains challenging. In this Perspective, we aim to stimulate research direction in the field with the utilization of such intriguing and unique directional noncovalent metal-metal interactions as one of the driving forces, highlighting the roles and significance of metal-metal interactions and ultimately facilitating a controlled and rational design and synthesis of metallosupramolecular functional materials with rich spectroscopic properties and huge potential for various applications. |
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Language | English |
Publishing date | 2022-12-09 |
Publishing country | United States |
Document type | Journal Article ; Review |
ZDB-ID | 3155-0 |
ISSN | 1520-5126 ; 0002-7863 |
ISSN (online) | 1520-5126 |
ISSN | 0002-7863 |
DOI | 10.1021/jacs.2c08551 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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