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  1. AU="Chatterjee, Pabitra B"
  2. AU="Papandreou, Z"
  3. AU="Moore, E F"
  4. AU="Verhoeven, V"
  5. AU="Benchat, Noureddine" AU="Benchat, Noureddine"
  6. AU="El-Rayes, Mahmoud Kamil"
  7. AU="Aude de Watteville"
  8. AU="Balm, P W"
  9. AU="Peng, Zhenling"
  10. AU="Du, Peilin"
  11. AU="Yeh, Pamela"
  12. AU="Moloney, Gail"
  13. AU="Murphy, Ross G"
  14. AU="Petronilho, Sara"
  15. AU="Ordóñez, Raquel"
  16. AU="Mulvaney, Robert"
  17. AU="Amarin, Z"
  18. AU="Vadlin, S"
  19. AU="Erin E. Michalak"
  20. AU="Cassidy, Caitlin A"
  21. AU="Veronica Davalos"
  22. AU="Koba, Wade R"
  23. AU="Cui, Hongyan"
  24. AU="Ross, Nina E"
  25. AU="Atwa, Hanaa A"
  26. AU="Reid, Carly"

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  1. Artikel ; Online: Enantiopure chiroptical probes for circular dichroism and absorbance based detection of nerve gas simulants.

    Debnath, Snehasish / Chatterjee, Pabitra B

    Chemical communications (Cambridge, England)

    2022  Band 58, Heft 64, Seite(n) 9006–9009

    Abstract: A series of oxovanadium(V) compounds 1-4 were prepared and explored as stereodynamic chiroptical probes to detect a simulant of sarin known as diethyl chlorophosphate (DCP) without any interference from the competing analytes. Simultaneous CD cum UV/vis ... ...

    Abstract A series of oxovanadium(V) compounds 1-4 were prepared and explored as stereodynamic chiroptical probes to detect a simulant of sarin known as diethyl chlorophosphate (DCP) without any interference from the competing analytes. Simultaneous CD cum UV/vis based bimodal instant recognition of DCP using optically active probes is unprecedented. Upon fabricating the vanadium compound with a polymer has yielded a chiroptical membrane, which showed a change in its dichroic as well as colorimetric signals on interaction with DCP vapour at 1 ppm. EPR and UV/vis studies revealed an irreversible change of the CD-active V(V) to the CD-silent ternary V(V) species in presence of DCP
    Mesh-Begriff(e) Chemical Phenomena ; Circular Dichroism ; Magnetic Resonance Spectroscopy ; Nerve Agents ; Vanadium Compounds/chemistry
    Chemische Substanzen Nerve Agents ; Vanadium Compounds
    Sprache Englisch
    Erscheinungsdatum 2022-08-09
    Erscheinungsland England
    Dokumenttyp Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc03392e
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  2. Artikel: Enantiopure chiroptical probes for circular dichroism and absorbance based detection of nerve gas simulants

    Debnath, Snehasish / Chatterjee, Pabitra B.

    Chemical communications. 2022 Aug. 9, v. 58, no. 64

    2022  

    Abstract: A series of oxovanadium(v) compounds 1–4 were prepared and explored as stereodynamic chiroptical probes to detect a simulant of sarin known as diethyl chlorophosphate (DCP) without any interference from the competing analytes. Simultaneous CD cum UV/vis ... ...

    Abstract A series of oxovanadium(v) compounds 1–4 were prepared and explored as stereodynamic chiroptical probes to detect a simulant of sarin known as diethyl chlorophosphate (DCP) without any interference from the competing analytes. Simultaneous CD cum UV/vis based bimodal instant recognition of DCP using optically active probes is unprecedented. Upon fabricating the vanadium compound with a polymer has yielded a chiroptical membrane, which showed a change in its dichroic as well as colorimetric signals on interaction with DCP vapour at 1 ppm. EPR and UV/vis studies revealed an irreversible change of the CD-active V(v) to the CD-silent ternary V(v) species in presence of DCP via a transient V(iv) species. Nucleophilic attack of the alkoxo oxygen of 1–4 to the electrophilic P atom of DCP resulted in the formation of ternary V(v) compounds as confirmed by ⁵¹V/³¹P NMR.
    Schlagwörter Lewis acids ; Lewis bases ; absorbance ; chemical species ; circular dichroism spectroscopy ; colorimetry ; enantiomers ; nerve tissue ; oxygen ; polymers ; vanadium ; vanadyl ions ; vapors
    Sprache Englisch
    Erscheinungsverlauf 2022-0809
    Umfang p. 9006-9009.
    Erscheinungsort The Royal Society of Chemistry
    Dokumenttyp Artikel
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc03392e
    Datenquelle NAL Katalog (AGRICOLA)

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  3. Artikel ; Online: A Water-Soluble Wavy Coordination Polymer of Cu(II) as a Turn-On Luminescent Probe for Histidine and Histidine-Rich Proteins/Peptides.

    Ghosh, Riya / Nair, Ratish R / Ghosh, Shibaji / Debnath, Snehasish / Chatterjee, Pabitra B

    Inorganic chemistry

    2024  Band 63, Heft 18, Seite(n) 8320–8328

    Abstract: Histidine plays an essential role in most biological systems. Changes in the homeostasis of histidine and histidine-rich proteins are connected to several diseases. Herein, we report a water-soluble Cu(II) coordination polymer, labeled CuCP, for the ... ...

    Abstract Histidine plays an essential role in most biological systems. Changes in the homeostasis of histidine and histidine-rich proteins are connected to several diseases. Herein, we report a water-soluble Cu(II) coordination polymer, labeled CuCP, for the fluorimetric detection of histidine and histidine-rich proteins and peptides. Single-crystal structure determination of CuCP revealed a two-dimensional wavy network structure in which a carboxylate group connects the individual Cu(II) dimer unit in a syn-anti conformation. The weakly luminescent and water-soluble CuCP shows turn-on blue emission in the presence of histidine and histidine-rich peptides and proteins. The polymer can also stain histidine-rich proteins via gel electrophoresis. The limits of quantifications for histidine, glycine-histidine, serine-histidine, human serum albumin (HSA), bovine serum albumin, pepsin, trypsin, and lysozyme were found to be 300, 160, 600, 300, 600, 800, 120, and 290 nM, respectively. Utilizing the fluorescence turn-on property of CuCP, we measured HSA quantitatively in the urine samples. We also validated the present urinary HSA measurement assay with existing analytical techniques. Job's plot,
    Mesh-Begriff(e) Copper/chemistry ; Copper/analysis ; Histidine/chemistry ; Histidine/analysis ; Histidine/urine ; Humans ; Water/chemistry ; Peptides/chemistry ; Proteins/chemistry ; Proteins/analysis ; Coordination Complexes/chemistry ; Coordination Complexes/chemical synthesis ; Solubility ; Polymers/chemistry ; Cattle ; Fluorescent Dyes/chemistry ; Fluorescent Dyes/chemical synthesis ; Luminescent Agents/chemistry ; Luminescent Agents/chemical synthesis ; Animals
    Chemische Substanzen Copper (789U1901C5) ; Histidine (4QD397987E) ; Water (059QF0KO0R) ; Peptides ; Proteins ; Coordination Complexes ; histidine-rich proteins ; Polymers ; Fluorescent Dyes ; Luminescent Agents
    Sprache Englisch
    Erscheinungsdatum 2024-04-25
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.4c00665
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  4. Artikel ; Online: Affinity Studies of Hemicyanine Derived Water Soluble Colorimetric Probes with Reactive Oxygen/Nitrogen/Sulfur Species.

    Ghosh, Riya / Debnath, Snehasish / Bhattacharya, Arnab / Chatterjee, Pabitra B

    Chembiochem : a European journal of chemical biology

    2023  Band 24, Heft 5, Seite(n) e202200541

    Abstract: Peroxynitrite ( ... ...

    Abstract Peroxynitrite (ONOO
    Mesh-Begriff(e) Reactive Oxygen Species/chemistry ; Reactive Nitrogen Species/chemistry ; Oxygen ; Peroxynitrous Acid ; Colorimetry ; Water/chemistry ; Nitrogen ; Fluorescent Dyes/chemistry ; Sulfur
    Chemische Substanzen Reactive Oxygen Species ; Reactive Nitrogen Species ; Oxygen (S88TT14065) ; Peroxynitrous Acid (14691-52-2) ; tetramethylene hemicyanine ; Water (059QF0KO0R) ; Nitrogen (N762921K75) ; Fluorescent Dyes ; Sulfur (70FD1KFU70)
    Sprache Englisch
    Erscheinungsdatum 2023-02-07
    Erscheinungsland Germany
    Dokumenttyp Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2020469-3
    ISSN 1439-7633 ; 1439-4227
    ISSN (online) 1439-7633
    ISSN 1439-4227
    DOI 10.1002/cbic.202200541
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  5. Artikel ; Online: Copper(II)-Incorporated Porphyrin-Based Porous Organic Polymer for a Nonenzymatic Electrochemical Glucose Sensor.

    Bhaduri, Samanka Narayan / Ghosh, Debojit / Debnath, Snehasish / Biswas, Rima / Chatterjee, Pabitra B / Biswas, Papu

    Inorganic chemistry

    2023  Band 62, Heft 10, Seite(n) 4136–4146

    Abstract: To date, the fabrication of multifunctional nanoplatforms based on a porous organic polymer for electrochemical sensing of biorelevant molecules has received considerable attention in the search for a more active, robust, and sensitive electrocatalyst. ... ...

    Abstract To date, the fabrication of multifunctional nanoplatforms based on a porous organic polymer for electrochemical sensing of biorelevant molecules has received considerable attention in the search for a more active, robust, and sensitive electrocatalyst. Here, in this report, we have developed a new porous organic polymer based on porphyrin (TEG-POR) from a polycondensation reaction between a triethylene glycol-linked dialdehyde and pyrrole. The Cu(II) complex of the polymer Cu-TEG-POR shows high sensitivity and a low detection limit for glucose electro-oxidation in an alkaline medium. The characterization of the as-synthesized polymer was done by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, and
    Mesh-Begriff(e) Humans ; Copper/chemistry ; Porosity ; Porphyrins ; Polymers ; Electrochemical Techniques ; Glucose/analysis ; Electrodes
    Chemische Substanzen Copper (789U1901C5) ; Porphyrins ; Polymers ; Glucose (IY9XDZ35W2)
    Sprache Englisch
    Erscheinungsdatum 2023-03-02
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.2c04072
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  6. Artikel ; Online: Fabrication of a paper-based facile and low-cost microfluidic device and digital imaging technique for point-of-need monitoring of hypochlorite.

    Debnath, Snehasish / Ghosh, Riya / Pragti / Mukhopadhyay, Suman / Baskaran, Kamesh Viswanathan / Chatterjee, Pabitra B

    The Analyst

    2023  Band 148, Heft 17, Seite(n) 4072–4083

    Abstract: Lab-on-a-paper-based devices are promising alternatives to the existing arduous techniques for point-of-need monitoring. The present work reports an instant and facile method to produce a microfluidic paper-based analytical device (μPAD). The fabricated ... ...

    Abstract Lab-on-a-paper-based devices are promising alternatives to the existing arduous techniques for point-of-need monitoring. The present work reports an instant and facile method to produce a microfluidic paper-based analytical device (μPAD). The fabricated μPAD has been used to detect hypochlorite (OCl
    Mesh-Begriff(e) Humans ; Hypochlorous Acid/chemistry ; Fluorescent Dyes/toxicity ; Fluorescent Dyes/chemistry ; HEK293 Cells ; HeLa Cells ; Spectrometry, Fluorescence/methods ; Microfluidic Analytical Techniques ; Paper
    Chemische Substanzen Hypochlorous Acid (712K4CDC10) ; Fluorescent Dyes
    Sprache Englisch
    Erscheinungsdatum 2023-08-21
    Erscheinungsland England
    Dokumenttyp Journal Article
    ZDB-ID 210747-8
    ISSN 1364-5528 ; 0003-2654
    ISSN (online) 1364-5528
    ISSN 0003-2654
    DOI 10.1039/d3an00533j
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  7. Artikel ; Online: Label-Free Detection of Unbound Bilirubin and Nitrophenol Explosives in Water by a Mechanosynthesized Dual Functional Zinc Complex: Recognition of Picric Acid in Various Common Organic Media.

    Nair, Ratish R / Debnath, Snehasish / Ghosh, Riya / Bhattacharya, Arnab / Raju, M / Chatterjee, Pabitra B

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2023  Band 30, Heft 9, Seite(n) e202303068

    Abstract: High levels of unconjugated bilirubin (UB) in serum lead to asymptomatic and neonatal jaundice and brain dysfunctions. Herein, we have reported the detection of UB at as low as 1 μM in an aqueous alkaline medium using a Zn(II) complex. The specificity of ...

    Abstract High levels of unconjugated bilirubin (UB) in serum lead to asymptomatic and neonatal jaundice and brain dysfunctions. Herein, we have reported the detection of UB at as low as 1 μM in an aqueous alkaline medium using a Zn(II) complex. The specificity of the complex has been validated by the HPLC in the concentration window 6-90 μM, which is rare. The sensory response of the probe at physiological pH against nitro explosives developed it as an instant-acting fluorosensor for picric acid (PA) and 2,4-dinitrophenol (2,4-DNP). Spectroscopic titration provided a binding constant of 4×10
    Mesh-Begriff(e) Infant, Newborn ; Humans ; Nitrophenols ; Water ; Zinc ; 2,4-Dinitrophenol ; Antifungal Agents ; Bilirubin ; Picrates
    Chemische Substanzen picric acid (A49OS0F91S) ; Nitrophenols ; Water (059QF0KO0R) ; Zinc (J41CSQ7QDS) ; 2,4-Dinitrophenol (Q13SKS21MN) ; Antifungal Agents ; Bilirubin (RFM9X3LJ49) ; Picrates
    Sprache Englisch
    Erscheinungsdatum 2023-12-27
    Erscheinungsland Germany
    Dokumenttyp Journal Article
    ZDB-ID 1478547-X
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.202303068
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  8. Artikel ; Online: Advances in the Development of Water-Soluble Fluorogenic Probes for Bioimaging of Hypochlorite/Hypochlorous Acid in Cells and Organisms.

    Debnath, Snehasish / Ghosh, Riya / Nair, Ratish R / Pradhan, Debjani / Chatterjee, Pabitra B

    ACS omega

    2022  Band 7, Heft 43, Seite(n) 38122–38149

    Abstract: This mini-review summarizes the development of intracellular fluorogenic probes for biological investigations of hypochlorous acid/hypochlorite (HOCl/ ... ...

    Abstract This mini-review summarizes the development of intracellular fluorogenic probes for biological investigations of hypochlorous acid/hypochlorite (HOCl/OCl
    Sprache Englisch
    Erscheinungsdatum 2022-10-17
    Erscheinungsland United States
    Dokumenttyp Journal Article ; Review
    ISSN 2470-1343
    ISSN (online) 2470-1343
    DOI 10.1021/acsomega.2c04840
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  9. Artikel ; Online: Reporting Coumarin Ensembled Vanadium(V) Compounds and Their Affinity Studies Toward Biological Thiols Probed by Fluorescence Spectroscopy.

    Debnath, Snehasish / Navadiya, Sumit V / Ghosh, Riya / Pradhan, Debjani / Chatterjee, Pabitra B

    Chemistry, an Asian journal

    2022  

    Abstract: Fluorescence spectroscopic studies of a pair of new oxido-vanadium(V) compounds with biological thiols, such as homocysteine (Hcy), cysteine (Cys), and glutathione (GSH), have been investigated in this article. Despite notable progress in vanadium-thiol ... ...

    Abstract Fluorescence spectroscopic studies of a pair of new oxido-vanadium(V) compounds with biological thiols, such as homocysteine (Hcy), cysteine (Cys), and glutathione (GSH), have been investigated in this article. Despite notable progress in vanadium-thiol chemistry, no attention has been paid to exploring vanadium-based optical probes to study their interaction with biothiols. For this purpose, two oxido-vanadium(V) compounds, 1 and 2, have been prepared involving a tridentate ONO donor-based luminescent coumarin-derived ligand. Single crystal X-ray diffraction analysis, NMR (1H, 13C and 51V) spectroscopy, XPS, and DFT calculations have been used to establish their identities. The vanadium center in these compounds has a distorted octahedral environment. In compound 2, a methanol molecule is coordinated to the vanadium(V) center in the trans position of the terminal oxido moiety. The latter exerts a strong trans-labilizing influence on the coordinating methanol. Both 1 and 2 are weakly fluorescent. Photophysical investigations of the vanadium complexes in aqueous media at physiological pH (7.4) in the presence of various biothiols and amino acids showed significant fluorescence enhancement (83-fold) of the vanadium complexes, specifically with Hcy. The specific affinity of the complexes for Hcy remained unchanged even in the presence of other biothiols and amino acids. Kinetic investigation reveals pseudo-first order behavior of the compound with Hcy. Mechanistic studies have manifested that Hcy-induced reduction triggers the decomplexation of the vanadium compound, followed by hydrolysis and subsequent cyclization. Time-correlated single photon counting suggested that the radiative rate constant (kr) of 1 and 2 in the presence of Hcy serves as the prime factor for the fluorescence enhancement of the medium. Compound 1 has been tested efficiently for Hcy measurement in blood plasma rendering it suitable for practical applications.
    Sprache Englisch
    Erscheinungsdatum 2022-11-30
    Erscheinungsland Germany
    Dokumenttyp Journal Article
    ZDB-ID 2233006-9
    ISSN 1861-471X ; 1861-4728
    ISSN (online) 1861-471X
    ISSN 1861-4728
    DOI 10.1002/asia.202201162
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  10. Artikel ; Online: Studies on the interaction between oxido/dioxidovanadium(V) compounds and reactive oxygen species: Synthesis, characterization, and photophysical investigation.

    Ghosh, Riya / Debnath, Snehasish / Bhattacharya, Arnab / Pradhan, Debjani / Chatterjee, Pabitra B

    Journal of inorganic biochemistry

    2022  Band 233, Seite(n) 111845

    Abstract: Singlet oxygen ( ...

    Abstract Singlet oxygen (
    Mesh-Begriff(e) Crystallography, X-Ray ; Hypochlorous Acid ; Ligands ; Singlet Oxygen ; Vanadium/chemistry
    Chemische Substanzen Ligands ; Vanadium (00J9J9XKDE) ; Singlet Oxygen (17778-80-2) ; Hypochlorous Acid (712K4CDC10)
    Sprache Englisch
    Erscheinungsdatum 2022-05-13
    Erscheinungsland United States
    Dokumenttyp Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 162843-4
    ISSN 1873-3344 ; 0162-0134
    ISSN (online) 1873-3344
    ISSN 0162-0134
    DOI 10.1016/j.jinorgbio.2022.111845
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