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  1. Article ; Online: Flexible and Transparent Electrode Based on Ag-Nanowire Embedded Colorless Poly(amide-imide)

    Jaegun Lee / Ju-Young Choi / Junhwan Jang / Sechang Park / Gyumin Ji / Seung-Hyun Lee / Dam-Bi Kim / Kang-Hoon Yoon / Chan-Moon Chung / Soohaeng Cho

    Nanomaterials, Vol 12, Iss 1457, p

    2022  Volume 1457

    Abstract: Graphene oxide-cysteamine-silver nanoparticle (GCA)/silver nanowire (AgNW)/GCA/colorless poly(amide-imide) (cPAI) structures based on cPAI substrates with polyimide and polyamide syntheses were fabricated to study their characteristics. A layer of ... ...

    Abstract Graphene oxide-cysteamine-silver nanoparticle (GCA)/silver nanowire (AgNW)/GCA/colorless poly(amide-imide) (cPAI) structures based on cPAI substrates with polyimide and polyamide syntheses were fabricated to study their characteristics. A layer of electrodes was constructed using a sandwich structure—such as GCA/AgNW/GCA—with cPAI used as a substrate to increase the heat resistance and improve their mechanical properties. Furthermore, to overcome the disadvantages of AgNWs—such as their high surface roughness and weak adhesion between the substrate and electrode layers—electrodes with embedded structures were fabricated using a peel-off process. Through bending, tapping, and durability tests, it was confirmed that these multilayer electrodes exhibited better mechanical durability than conventional AgNW electrodes. Resistive random-access memory based on GCA/AgNW/GCA/cPAI electrodes was fabricated, and its applicability to nonvolatile memory was confirmed. The memory device had an ON/OFF current ratio of ~10 4 @0.5 V, exhibiting write-once-read-many time characteristics, maintaining these memory characteristics for up to 300 sweep cycles. These findings suggest that GCA/AgNW/GCA/cPAI electrodes could be used as flexible and transparent electrodes for next-generation flexible nonvolatile memories.
    Keywords colorless poly(amide-imide) ; Ag nanowire ; GO-cysteamine-Ag nanoparticle (GCA) ; transparent and flexible electrode ; resistive switching memory ; Chemistry ; QD1-999
    Subject code 620
    Language English
    Publishing date 2022-04-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  2. Article ; Online: Transparent Self-Cleaning Coatings Based on Colorless Polyimide/Silica Sol Nanocomposite

    Yun-Je Choi / Ju-Hee Ko / Seung-Won Jin / Hyun-Soo An / Dam-Bi Kim / Kang-Hoon Yoon / Hyun-Woo Kim / Chan-Moon Chung

    Polymers, Vol 13, Iss 4100, p

    2021  Volume 4100

    Abstract: We herein report transparent self-cleaning coatings based on polyimide-fluorinated silica sol (PIFSS) nanocomposite. Polyamic acid-silica sol (PASS) suspensions were synthesized by adding four different amounts of a silica sol suspension to each end- ... ...

    Abstract We herein report transparent self-cleaning coatings based on polyimide-fluorinated silica sol (PIFSS) nanocomposite. Polyamic acid-silica sol (PASS) suspensions were synthesized by adding four different amounts of a silica sol suspension to each end-capped polyamic acid solution. The PASS suspensions were spin-coated on glass slides, thermally imidized and treated with triethoxy-1 H ,1 H ,2 H ,2 H -perfluorodecylsilane (TEFDS) to prepare PIFSS coatings. The PIFSS coatings showed high resistance to separation from glass substrates and thermal stability. Furthermore, the PIFSS coatings on the glass substrate could be cleanly removed using polar aprotic solvents and repeated coating was possible. As the amount of silica sol particles in the PIFSS coating was increased, the hydrophobic contact angle increased. Among them, PIFSS-10 and PIFSS-15 coatings showed nearly superhydrophobic contact angles (144° and 148°, respectively) and good self-cleaning property. It was confirmed by SEM and AFM studies that their hydrophobic and self-cleaning properties are due to uniform particle distribution and relatively high surface roughness. PIFSS-10 coating showed a high transmittance value (88%) at 550 nm and good self-cleaning property, therefore suitable as a transparent self-cleaning coating. The advantages of the coating are that the fabrication process is simple, and the substrate is reusable. The PIFSS coating is expected to be applied in solar cell panels, windows, lenses and safety goggles.
    Keywords self-cleaning ; transparent ; hydrophobic ; polyimide ; silica sol ; nanocomposite ; Organic chemistry ; QD241-441
    Subject code 620
    Language English
    Publishing date 2021-11-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Article ; Online: Flexible Transparent Electrode Characteristics of Graphene Oxide/Cysteamine/AgNP/AgNW Structure

    Junhwan Jang / Ju-Young Choi / Jihyun Jeon / Jeongjun Lee / Jaehyuk Im / Jaegun Lee / Seung-Won Jin / Hyeong-Joo Park / Seung-Hyun Lee / Dam-Bi Kim / Chan-Moon Chung / Soohaeng Cho

    Nanomaterials, Vol 10, Iss 2352, p

    2020  Volume 2352

    Abstract: Graphene oxide (GO)–cysteamine–Ag nanoparticles (GCA)–silver nanowire (AgNW) fabricated by depositing GCA over sprayed AgNWs on PET films were proposed for transparent and flexible electrodes, and their optical, electrical, and mechanical properties were ...

    Abstract Graphene oxide (GO)–cysteamine–Ag nanoparticles (GCA)–silver nanowire (AgNW) fabricated by depositing GCA over sprayed AgNWs on PET films were proposed for transparent and flexible electrodes, and their optical, electrical, and mechanical properties were analyzed by energy-dispersive X-ray spectroscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, atomic force microscopy, scanning electron microscopy, transmission electron microscopy, current-voltage measurements, and bending test. GCA–AgNW electrodes show optical transmittance of >80% at 550 nm and exhibit a high figure-of-merit value of up to 116.13 in the samples with sheet resistances of 20–40 Ω/◻. It was observed that the detrimental oxidation of bare AgNWs over time was considerably decreased, and the mechanical robustness was improved. To apply the layer as an actual electrode in working devices, a Pt/GO/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate/GCA–AgNW/polyethylene terephthalate structure was fabricated, and resistive switching memory was demonstrated. On the basis of these results, we confirm that the proposed GCA–AgNW layer can be used as transparent and flexible electrode.
    Keywords silver nanowire ; GO-cysteamine-AgNP (GCA) ; transparent and flexible electrode ; resistive switching memory ; Chemistry ; QD1-999
    Subject code 620
    Language English
    Publishing date 2020-11-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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