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  1. Book ; Online: Green Chemistry

    Kumar, Brajesh / Debut, Alexis

    New Perspectives

    2022  

    Keywords Organic chemistry ; Chemistry
    Language English
    Size 1 electronic resource (268 pages)
    Publisher IntechOpen
    Document type Book ; Online
    Note English
    HBZ-ID HT030377303
    ISBN 9781803557793 ; 1803557796
    Database ZB MED Catalogue: Medicine, Health, Nutrition, Environment, Agriculture

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  2. Article: Honeybee pollen assisted biosynthesis of nanogold and its application as catalyst in reduction of 4-nitrophenol.

    Kumar, Brajesh / Smita, Kumari / Angulo, Yolanda / Debut, Alexis / Cumbal, Luis

    Heliyon

    2022  Volume 8, Issue 8, Page(s) e10191

    Abstract: Nowadays, the exploration of natural materials for the production of nanoparticles is of special interest due to its ecofriendly nature. In this paper, we presented the biosynthesis of gold nanoparticles (AuNPs) in a green route by using water extract of ...

    Abstract Nowadays, the exploration of natural materials for the production of nanoparticles is of special interest due to its ecofriendly nature. In this paper, we presented the biosynthesis of gold nanoparticles (AuNPs) in a green route by using water extract of pollen from Andean honeybees. Furthermore, AuNPs have been characterized by various techniques and tested for the catalytic reduction of 4-nitrophenol (4-NP). The biosynthesized AuNPs were analyzed using UV-vis spectroscopy, Transmission electron microscopy (TEM), Dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) spectroscopy to confirm their optical properties, stability, surface morphology, and purity. The synthesized AuNPs proved to be well dispersed, spherical, and triangular in shape, with particle sizes ranging from 7 to 42 nm having λ
    Language English
    Publishing date 2022-08-11
    Publishing country England
    Document type Journal Article
    ZDB-ID 2835763-2
    ISSN 2405-8440
    ISSN 2405-8440
    DOI 10.1016/j.heliyon.2022.e10191
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Hydrothermal Synthesis of Bismuth Ferrite Hollow Spheres with Enhanced Visible-Light Photocatalytic Activity.

    Cadenbach, Thomas / Sanchez, Valeria / Chiquito Ríos, Daniela / Debut, Alexis / Vizuete, Karla / Benitez, Maria J

    Molecules (Basel, Switzerland)

    2023  Volume 28, Issue 13

    Abstract: In recent years, semiconductor hollow spheres have gained much attention due to their unique combination of morphological, chemical, and physico-chemical properties. In this work, we report for the first time the synthesis of BiFeO3 hollow spheres by a ... ...

    Abstract In recent years, semiconductor hollow spheres have gained much attention due to their unique combination of morphological, chemical, and physico-chemical properties. In this work, we report for the first time the synthesis of BiFeO3 hollow spheres by a facile hydrothermal treatment method. The mechanism of formation of pure phase BiFeO3 hollow spheres is investigated systematically by variation of synthetic parameters such as temperature and time, ratio and amount of precursors, pressure, and calcination procedures. The samples were characterized by X-ray powder diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, and UV-vis diffuse reflectance spectroscopy. We observe that the purity and morphology of the synthesized materials are very sensitive to synthesis parameters. In general, the chemically and morphologically very robust hollow spheres have diameters in the range of 200 nm to 2 μm and a wall thickness of 50-200 nm. The synthesized BiFeO3 hollow spheres were applied as catalysts in the photodegradation of the model pollutant Rhodamine B under visible-light irradiation. Notably, the photocatalyst demonstrated exceptionally high removal efficiencies leading to complete degradation of the dye in less than 150 min at neutral pH. The superior efficiencies of the synthesized material are attributed to the unique features of hollow spheres. The active species in the photocatalytic process have been identified by trapping experiments.
    MeSH term(s) Bismuth ; Light ; Ferric Compounds ; Photolysis
    Chemical Substances Bismuth (U015TT5I8H) ; ferrite (1317-54-0) ; Ferric Compounds
    Language English
    Publishing date 2023-06-29
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules28135079
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: COVID-19: Pandemic in Ecuador: a health disparities perspective.

    Toulkeridis, Theofilos / Seqqat, Rachid / Torres A, Marbel / Ortiz-Prado, Esteban / Debut, Alexis

    Revista de salud publica (Bogota, Colombia)

    2023  Volume 22, Issue 3, Page(s) 304–308

    Abstract: Background: The global COVID-19 pandemic initiated in Ecuador with the patient zero in February 2020 and since more than 40,000 persons have been tested positive to the virus, leaving some 3,500 deceased, while approximately about 10,500 persons above ... ...

    Abstract Background: The global COVID-19 pandemic initiated in Ecuador with the patient zero in February 2020 and since more than 40,000 persons have been tested positive to the virus, leaving some 3,500 deceased, while approximately about 10,500 persons above annual average numbers died within March to May. A strict lockdown was applied by mid-March, which resulted to a severe economic crisis in the country. Although during the lockdown.
    Objective: Our study postulates, that persons who are most likely to be infected during such secondary wave will be people who have already health issues to which we count besides the known ones, especially those who are already suffer by the distribution of volcanic ashes, as such pyroclastic material is known to affect lunges and thyroids. occurred a notable decrease in the number of new cases, the spread of the infection was already massive, untechnical, political and economic decisions will certainly lead to continuous wave of infections for months.
    Methods: A descriptive ecological study of information related to COVID-19 infection at a national level using official data from the Minister of Public Health and volcanic ash fall by geographical area in Ecuador.
    Results: The mortality rate per canton indicated that those with lower attack rates are the ones with highest mortality rate. For instance, Portovelo (21.3/100,000), Playas (18.4/100,000), Santa Rosa (15.8/100,000), Suscal (15.3/100,000) and Penipe (14.3/100,000) reported the highest mortality rate per 100,000 people. The main distribution of such volcanic material is within the central to northern area of the Highlands and Inter-Andean Valley of Ecuador, due to the analysis of some 7394 satellite images of the last 21 years.
    Conclusions: We conclude that areas with high vulnerabilities are also most susceptible to develop COVID-19. Such areas with their respective populations will be affected above average and shall be protected in particular within the presently starting during possible second wave of infection.
    MeSH term(s) Humans ; COVID-19/epidemiology ; Ecuador/epidemiology ; Pandemics ; Communicable Disease Control ; Public Health
    Language English
    Publishing date 2023-01-18
    Publishing country Colombia
    Document type Journal Article
    ZDB-ID 2060572-9
    ISSN 0124-0064
    ISSN 0124-0064
    DOI 10.15446/rsap.V22n3.88102
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Photochemical Reduction of Silver Nanoparticles on Diatoms

    León-Valencia, Adrián / Briceño, Sarah / Reinoso, Carlos / Vizuete, Karla / Debut, Alexis / Caetano, Manuel / González Romero, Gema

    Mar Drugs. 2023 Mar. 17, v. 21, no. 3

    2023  

    Abstract: In this work, the photochemical reduction method was used at 440 or 540 nm excitation wavelengths to optimize the deposition of silver nanoparticles on the diatom surface as a potential DNA biosensor. The as-synthesized nanocomposites were characterized ... ...

    Abstract In this work, the photochemical reduction method was used at 440 or 540 nm excitation wavelengths to optimize the deposition of silver nanoparticles on the diatom surface as a potential DNA biosensor. The as-synthesized nanocomposites were characterized by ultraviolet-visible spectroscopy (UV-Vis), Fourier transforms infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM), fluorescence microscopy, and Raman spectroscopy. Our results revealed a 5.5-fold enhancement in the fluorescence response of the nanocomposite irradiated at 440 nm with DNA. The enhanced sensitivity comes from the optical coupling of the guided-mode resonance of the diatoms and the localized surface plasmon of the silver nanoparticles interacting with the DNA. The advantage of this work involves the use of a low-cost green method to optimize the deposition of plasmonic nanoparticles on diatoms as an alternative fabrication method for fluorescent biosensors.
    Keywords Bacillariophyceae ; DNA ; Raman spectroscopy ; X-ray photoelectron spectroscopy ; biosensors ; fluorescence ; fluorescence microscopy ; nanocomposites ; nanoparticles ; nanosilver ; photochemistry ; transmission electron microscopy ; ultraviolet-visible spectroscopy
    Language English
    Dates of publication 2023-0317
    Publishing place Multidisciplinary Digital Publishing Institute
    Document type Article ; Online
    ZDB-ID 2175190-0
    ISSN 1660-3397
    ISSN 1660-3397
    DOI 10.3390/md21030185
    Database NAL-Catalogue (AGRICOLA)

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  6. Article ; Online: Kinetic study of the catalytic cracking of waste motor oil using biomass-derived heterogeneous catalysts

    Rodriguez, Yuliana / Guerra, Renato / Vizuete, Karla / Debut, Alexis / Streitwieser, Daniela Almeida / Mora, Jose R. / Ponce, Sebastián

    Waste Management. 2023 July, v. 167 p.46-54

    2023  

    Abstract: Herein, biochar from biomass residues is demonstrated as active materials for the catalytic cracking of waste motor oil into diesel-like fuels. Above all, alkali-treated rice husk biochar showed great activity with a 250% increase in the kinetic constant ...

    Abstract Herein, biochar from biomass residues is demonstrated as active materials for the catalytic cracking of waste motor oil into diesel-like fuels. Above all, alkali-treated rice husk biochar showed great activity with a 250% increase in the kinetic constant compared to the thermal cracking. It also showed better activity than synthetic materials, as previously reported. Moreover, much lower activation energy (185.77to293.48kJmol) for the cracking process was also obtained. According to materials characterization, the catalytic activity was more related to the nature of the biochar's surface than its specific surface area. Finally, liquid products complied with all the physical properties defined by international standards for diesel-like fuels, with the presence of hydrocarbons chains between C10-C27 similar to the ones obtained in commercial diesel.
    Keywords activation energy ; biochar ; biomass ; catalytic activity ; liquids ; oils ; rice hulls ; surface area ; waste management ; Waste motor oil ; Kinetic study ; Biochar catalyst ; Residual biomass ; Chemical recycling ; Diesel-like fuel
    Language English
    Dates of publication 2023-07
    Size p. 46-54.
    Publishing place Elsevier Ltd
    Document type Article ; Online
    ZDB-ID 2001471-5
    ISSN 1879-2456 ; 0956-053X
    ISSN (online) 1879-2456
    ISSN 0956-053X
    DOI 10.1016/j.wasman.2023.05.027
    Database NAL-Catalogue (AGRICOLA)

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  7. Article ; Online: Honeybee pollen assisted biosynthesis of nanogold and its application as catalyst in reduction of 4-nitrophenol

    Kumar, Brajesh / Smitā Kumārī / Angulo, Yolanda / Debut, Alexis / Cumbal, Luis

    Heliyon. 2022 Aug., v. 8, no. 8 p.e10191-

    2022  

    Abstract: Nowadays, the exploration of natural materials for the production of nanoparticles is of special interest due to its ecofriendly nature. In this paper, we presented the biosynthesis of gold nanoparticles (AuNPs) in a green route by using water extract of ...

    Abstract Nowadays, the exploration of natural materials for the production of nanoparticles is of special interest due to its ecofriendly nature. In this paper, we presented the biosynthesis of gold nanoparticles (AuNPs) in a green route by using water extract of pollen from Andean honeybees. Furthermore, AuNPs have been characterized by various techniques and tested for the catalytic reduction of 4-nitrophenol (4-NP). The biosynthesized AuNPs were analyzed using UV-vis spectroscopy, Transmission electron microscopy (TEM), Dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) spectroscopy to confirm their optical properties, stability, surface morphology, and purity. The synthesized AuNPs proved to be well dispersed, spherical, and triangular in shape, with particle sizes ranging from 7 to 42 nm having λₘₐₓ at 530 nm. Moreover, FTIR suggests the capping of AuNPs with pollen constituents and XRD confirms the crystalline structure of AuNPs. Additionally, prepared AuNPs were demonstrated to be effective in reducing organic pollutant 4-NP to 4-aminophenol (k = 59.17898 × 10⁻³ min⁻¹, R² = 0.994). All of these studies have emphasized that AuNPs production can be scale up by using naturally available pollen grains and open up a new perspective for beekeepers.
    Keywords Fourier transform infrared spectroscopy ; X-ray diffraction ; aminophenols ; biosynthesis ; catalysts ; crystal structure ; honey bees ; nanogold ; nanoparticles ; p-nitrophenol ; pollen ; pollutants ; transmission electron microscopy ; ultraviolet-visible spectroscopy ; Andes region ; Honeybee pollen ; Gold nanoparticles ; Catalysis ; UV-Vis spectroscopy ; TEM ; Ecofriendly
    Language English
    Dates of publication 2022-08
    Publishing place Elsevier Ltd
    Document type Article ; Online
    Note Use and reproduction
    ZDB-ID 2835763-2
    ISSN 2405-8440
    ISSN 2405-8440
    DOI 10.1016/j.heliyon.2022.e10191
    Database NAL-Catalogue (AGRICOLA)

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  8. Article: Andean Sacha Inchi (

    Kumar, Brajesh / Smita, Kumari / Debut, Alexis / Cumbal, Luis

    Bioengineering (Basel, Switzerland)

    2020  Volume 7, Issue 2

    Abstract: In this work, Andean sacha inchi ( ...

    Abstract In this work, Andean sacha inchi (
    Language English
    Publishing date 2020-06-06
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2746191-9
    ISSN 2306-5354
    ISSN 2306-5354
    DOI 10.3390/bioengineering7020054
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article: Sticky bacteria: Combined effect of galactose and high ferric iron concentration on extracellular polymeric substances production and the attachment of

    Moncayo, Eduardo A / Debut, Alexis / Vizuete, Karla / Jumbo-Flores, Diana / Aguirre, Paulina

    Frontiers in microbiology

    2022  Volume 13, Page(s) 951402

    Abstract: Adaptation and microbial attachment mechanisms for the degradation of sulfide ores are mediated by the production of extracellular polymeric substances (EPS) and their role in biofilm formation. EPS production responds to induction mechanisms associated ... ...

    Abstract Adaptation and microbial attachment mechanisms for the degradation of sulfide ores are mediated by the production of extracellular polymeric substances (EPS) and their role in biofilm formation. EPS production responds to induction mechanisms associated with environmental conditions. In this study, the double induction of EPS with galactose and high ferric iron concentrations in planktonic cells of
    Language English
    Publishing date 2022-09-12
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2587354-4
    ISSN 1664-302X
    ISSN 1664-302X
    DOI 10.3389/fmicb.2022.951402
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article: Magnetite Impregnated Lignocellulosic Biomass for Zn(II) Removal.

    Asimbaya, Christopher / Rosas-Laverde, Nelly Maria / Galeas, Salome / Debut, Alexis / Guerrero, Victor H / Pruna, Alina

    Materials (Basel, Switzerland)

    2022  Volume 15, Issue 3

    Abstract: Magnetic composites obtained by impregnation of lignocellulosic biomass with magnetite nanoparticles were used for zinc(II) removal from aqueous synthetic solutions. Laurel, canelo and eucalyptus sawdust, with a particle size between 74 and 150 µm were ... ...

    Abstract Magnetic composites obtained by impregnation of lignocellulosic biomass with magnetite nanoparticles were used for zinc(II) removal from aqueous synthetic solutions. Laurel, canelo and eucalyptus sawdust, with a particle size between 74 and 150 µm were used as support. Structural and morphological examinations of the composites confirmed the presence of magnetite nanoparticles in the lignocellulosic support. Transmission Electron Microscopy showed nanoparticles with diameters of about 20 nm. The maximum removal efficiencies for 7 g L
    Language English
    Publishing date 2022-01-19
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2487261-1
    ISSN 1996-1944
    ISSN 1996-1944
    DOI 10.3390/ma15030728
    Database MEDical Literature Analysis and Retrieval System OnLINE

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