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Article ; Online: Efficient removal of carcinogenic Rosaniline Hydrochloride (Fuchsine) dye with Mg doped FeTiO nanocomposites

Salman Latif / Fahad Abdulaziz / Amir Al-Ahmed

Journal of Saudi Chemical Society, Vol 28, Iss 1, Pp 101778- (2024)

Experimental and statistical evaluation

2024

Abstract: This study focuses on the synthesis of new nanostructured absorbent materials and removal of hazardous Rosaniline Hydrochloride (fuchsine) dye from polluted water. For this, Mg doped FeTiO nanocomposite (FTMO-NCs) was synthesized by co-precipitation ... ...

Abstract	This study focuses on the synthesis of new nanostructured absorbent materials and removal of hazardous Rosaniline Hydrochloride (fuchsine) dye from polluted water. For this, Mg doped FeTiO nanocomposite (FTMO-NCs) was synthesized by co-precipitation method and thoroughly characterized to study its surface properties. The TEM image shows the FTMO-NCs are consists of crystalline particles sized in few nanometers of scale. The SAED pattern suggests the nanoscale polycrystalline nature of the FTMO-NCs. The homogeneously distributed MgO on the FeTiO-NCs further validates the spectra. Furthermore, the successful mixture of MgO with the FeTiO surface and the formation of FTMO-NCs are indicated by the well-defined elemental mapping of Fe, Ti, O, and Mg. Dye adsorption capacity, stability, and regeneration capability of the synthesized FTMO-NCs was evaluated by a series of experiments and varying parameters, such as, agitation time, nanocomposite mass, solution pH, dye concentration, etc. The pseudo-second-order kinetic model was found to be applicable based on the kinetic parameters calculated with a high correlation coefficient of 0.999. The findings indicate that the Langmuir isotherm is a better fit for the experimental data for the fuchsine adsorption on the FTMO-NPs in comparison to the other four models and shows the maximum adsorption capacity (Qmax) of 555.5 mg/g. Moreover, a double layer model was applied to study the statistical prediction of the favorability of the adsorption process of the dye on the nanocomposite. The Nm value for fuchsine adsorption was 550 mg/g, 255 mg/g, and 218 mg/g, respectively at 298 K, 308 K, and 318 K. The use of Mg-doped FeTiO nanocomposites (FTMO-NCs) for removing Rosaniline Hydrochloride (fuchsine) dye is a novel approach that brings together the unique properties of both materials. The incorporation of magnesium (Mg) into the FeTiO nanocomposite introduces new synergies and enhances the adsorption capabilities of the material. This innovation is particularly significant because ...
Keywords	FeTiMgO synthesis ; Adsorption mechanism ; Kinetics ; Isotherm ; Double layer model ; Statistical analysis ; Chemistry ; QD1-999
Subject code	660
Language	English
Publishing date	2024-01-01T00:00:00Z
Publisher	Elsevier
Document type	Article ; Online
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Article ; Online: Exploring determinants of sex and family history-based disparity in type 2 diabetes mellitus prevalence among clinical patients.

Alrashed, Fahad Abdulaziz / Iqbal, Muhammad / Alsubiheen, Abdulrahman M / Ahmad, Tauseef

BMC public health

2024 Volume 24, Issue 1, Page(s) 682

Abstract: Background: Type 2 diabetes mellitus represents a multifaceted disorder characterized by intricate pathophysiological mechanisms, encompassing diminished insulin secretion, augmented hepatic glucose production, and heightened insulin resistance. This ... ...

Abstract	Background: Type 2 diabetes mellitus represents a multifaceted disorder characterized by intricate pathophysiological mechanisms, encompassing diminished insulin secretion, augmented hepatic glucose production, and heightened insulin resistance. This study aims to assess the sex (Male and Female only) and family history-based differences in the prevalence of T2DM and explore the determinants contributing to this disparity among clinical patients. Subjects and methods: The study encompassed a diverse pool of clinical patients, encompassing both individuals with diabetes and those without the condition, who had previously sought medical attention for clinical checkups at healthcare centers. The collected data included essential parameters such as blood pressure, weight, height, smoking habits, educational background, and physical activity levels. To ensure methodological rigor and data accuracy, blood pressure measurements adhered to the stringent guidelines set forth by the World Health Organization. Results: Participants of the present study reported diabetes, among which notable findings emerged regarding health indicators. It was observed that the prevalence of high blood pressure, obesity, and high blood cholesterol exhibited a statistically significant increase among the female participants, underscoring the sex-based disparities in these health parameters. The male population aged 60 or older, the presence of a family history of DM accentuated this risk, resulting in a striking 3.1 times higher prevalence compared to females, who exhibited a 2.4 times higher risk (OR = 2.4, p = 0.0008). This intriguing relationship between diabetes and cholesterol levels was not limited to sex. Both male (OR = 2.47) and female (OR = 2.1) diabetes patients displayed highly significant associations with cholesterol levels. The risk of T2DM was significantly associated with triglycerides in both sexes (1.58 times higher in males, and 1.71 times higher in females). Conclusions: The significance of hypertension as a comorbidity in T2DM, highlighting sex-specific associations and the potential impact of a family history of diabetes on blood pressure. Our findings emphasize the importance of considering lipid profiles, obesity, and their sex-specific associations when assessing and managing diabetes risk. Comprehensive diabetes care should include strategies for lipid control, weight management, and cardiovascular risk reduction, tailored to the individual's sex and specific risk profile.
MeSH term(s)	Humans ; Female ; Male ; Diabetes Mellitus, Type 2/epidemiology ; Prevalence ; Hypertension/epidemiology ; Obesity ; Cholesterol ; Lipids
Chemical Substances	Cholesterol (97C5T2UQ7J) ; Lipids
Language	English
Publishing date	2024-03-04
Publishing country	England
Document type	Journal Article
ZDB-ID	2041338-5
ISSN	1471-2458 ; 1471-2458
ISSN (online)	1471-2458
ISSN	1471-2458
DOI	10.1186/s12889-024-18170-0
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Article ; Online: Ecofriendly Elimination of Ni (II) Using Fabricated Nanocomposite Based on Chitosan/Silver Nanoparticles/Carbon Nanotubes

Eid M. S. Azzam / Walaa I. Elsofany / Fahad Abdulaziz / Hind A. AlGhamdi / Abdullah Y. AL alhareth

Polymers, Vol 15, Iss 2759, p

2023 Volume 2759

Abstract: Nickel ions are hazardous heavy metals that are non-biodegradable and can lead to allergic sensitivity and dermatitis. Nanomaterials are chosen for their effective elimination of impurities from water structures based entirely on the variety of therapy ... ...

Abstract	Nickel ions are hazardous heavy metals that are non-biodegradable and can lead to allergic sensitivity and dermatitis. Nanomaterials are chosen for their effective elimination of impurities from water structures based entirely on the variety of therapy and degree of purification. The target of this work was the combination of the properties of biopolymers such as chitosan, silver nanoparticles (SNPs), and carbon nanotubes (CNTs) in one ecofriendly compound for Ni (II) uptake from the aqueous solution. To attain this target, the endeavor was made by creating a nanocomposite based on chitosan/SNPs/CNTs. The characterization of the structure of the fabricated nanocomposite (Chit-SNPs-CNTs) was carried out using different techniques. The removal of Ni (II) was examined by studying the adsorption of Ni (II) ions onto the fabricated nanocomposite by batch adsorption using UV, XRD, XPS, and ICP techniques. Moreover, we investigated the effect of the contact time, pH of the solution, and mass of the adsorbent on the efficiency of the adsorption of Ni (II). The results show that the adsorption capacity of Ni (II) increased by increasing the contact time with a neutral pH. The maximum removal of Ni (II) ions (99.70%) was found using 0.3 g of the (Chit-SNPs-CNTs) nanocomposite. In addition, the results indicate that the fabricated nanocomposite has a high adsorption effectivity, which is associated to the function of the chitosan, SNPs, and CNTs in upgrading the adsorption efficiency. Finally, the results in the existing work indicate that the ecofriendly nanocomposite organized here gave excessive effectivity closer to the elimination of Ni (II).
Keywords	biopolymer ; silver nanoparticles ; carbon nanotubes ; ecofriendly nanocomposites ; wastewater ; Ni (II) ; Organic chemistry ; QD241-441
Subject code	620 ; 540
Language	English
Publishing date	2023-06-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
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Article ; Online: Investigating factors that influence residency program selection among medical students.

Alaqeel, Saud Abdulaziz / Alhammad, Bader Khalid / Basuhail, Suhail Mohsen / Alderaan, Khayyal Mohammed / Alhawamdeh, Abdulla Taher / Alquhayz, Mohammed Fahad / Alzunaidi, Alwaleed Mansour / Alrashed, Fahad Abdulaziz

BMC medical education

2023 Volume 23, Issue 1, Page(s) 615

Abstract: Backgrounds: Medical students and interns face several decisions during their career development. One of the most critical decisions they have to make is choosing a residency program that suits their career goals and aspirations. The selection process ... ...

Abstract	Backgrounds: Medical students and interns face several decisions during their career development. One of the most critical decisions they have to make is choosing a residency program that suits their career goals and aspirations. The selection process can be challenging, as several factors can influence the decision-making process. There was limited research on the role of GPA and opportunities in residency program selection. Therefore, this study examines the factors that influence interns' and 5th-year medical students' choices of residency programs. Methods: Observational and analytical cross-sectional studies were conducted at King Saud University (KSU) in Riyadh, Saudi Arabia. A sample of 5th-year medical students as well as medical interns was included in the study. This study only includes students who were interested in choosing a residency program in one of these eight domains: Medicine, Family Medicine, Orthopedics, Pediatrics, Radiology, Surgery, Obstetrics/Gynecology, and Ophthalmology. Results: The total number of students with 5th-year medical students was 205 (60.1%) and the number of students with medical interns was 135 (39.5%). The majority of students (51.0%) had a GPA above 4.5 out of 5, followed by 3.5 to 4.5 among 146 (42.8) students, and only 21 (6.2) had a GPA below 3.5. Those students with less than a 3.5 GPA out of 5 were found not to have any favorite residency program specialties when it came to academic achievement. Furthermore, in the case of those students whose GPA was 3.5 to 4.5, they had a certain mindset when it came to choosing a residency program. A 1.9 times greater likelihood of selecting obstetrics and gynecology (OR = 1.9, p = 0.19) was achieved by students with GPAs between 3.5 and 4.5, followed by a 1.5 times greater probability of selecting radiology (OR = 1.5; p = 0.55). High achievers, ophthalmology (OR = 1.7; p = 0.32) and surgery (OR = 1.4; p = 0.31) were the most popular residency programs. A student with a high GPA (mean score = 7.3) also chooses his or her career based on better opportunities than a student with a low GPA (mean score = 6.8). Conclusions: The study highlights the correlation between academic achievement and preferred specialties for future careers among medical students. While the study's findings should be considered in the context of various other factors such as lifestyle, social life, and income can influence students' preferred specialties for residency programs.
MeSH term(s)	Humans ; Child ; Female ; Male ; Pregnancy ; Students, Medical ; Cross-Sectional Studies ; Internship and Residency ; Academic Success ; Radiology
Language	English
Publishing date	2023-08-29
Publishing country	England
Document type	Observational Study ; Journal Article
ZDB-ID	2044473-4
ISSN	1472-6920 ; 1472-6920
ISSN (online)	1472-6920
ISSN	1472-6920
DOI	10.1186/s12909-023-04602-9
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Article ; Online: Synthesis, Crystal Structure, Quantum Chemical Analysis, Electrochemical Behavior, and Antibacterial and Photocatalytic Activity of Co Complex with Pyridoxal-(S-Methyl)-isothiosemicarbazone Ligand

Violeta Jevtović / Haneen Hamoud / Salma Al-Zahrani / Khalaf Alenezi / Salman Latif / Tahani Alanazi / Fahad Abdulaziz / Dušan Dimić

Molecules, Vol 27, Iss 4809, p

2022 Volume 4809

Abstract: New complex Co(III) with ligand Pyridoxal-S-methyl-isothiosemicarbazone, (PLITSC) was synthesized. X-ray analysis showed the bis-ligand octahedral structure of the cobalt complex [Co(PLITSC-H) 2 ]BrNO 3 ·CH 3 OH (compound 1 ). The intermolecular ... ...

Abstract	New complex Co(III) with ligand Pyridoxal-S-methyl-isothiosemicarbazone, (PLITSC) was synthesized. X-ray analysis showed the bis-ligand octahedral structure of the cobalt complex [Co(PLITSC-H) 2 ]BrNO 3 ·CH 3 OH (compound 1 ). The intermolecular interactions governing the crystal structure were described by the Hirsfeld surface analysis. The structure of compound 1 and the corresponding Zn complex (([Zn(PLTSC)(H 2 O) 2 ]SO 4 ·H 2 O)) were optimized at the B3LYP/6–31 + G (d,p)/LanL2DZ level of theory, and the applicability was assessed by comparison with the crystallographic structure. The natural bond orbital analysis was used for the discussion on the stability of formed compounds. The antibacterial activity of obtained complexes towards S. aureus and E. coli was determined, along with the effect of compound 1 on the formation of free radical species. Activity of compound 1 towards the removal of methylene blue was also investigated. The voltammograms of these compounds showed the reduction of metal ions, as well as the catalyzed reduction of CO 2 in acidic media.
Keywords	DFT ; Co and Zn complexes ; crystal structure ; catalytic activity ; biological activity ; Organic chemistry ; QD241-441
Subject code	540
Language	English
Publishing date	2022-07-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
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Article: Prevalence of insomnia and related psychological factors with coping strategies among medical students in clinical years during the COVID-19 pandemic.

Alrashed, Fahad Abdulaziz / Sattar, Kamran / Ahmad, Tauseef / Akram, Ashfaq / Karim, Syed Irfan / Alsubiheen, Abdulrahman Mohammed

Saudi journal of biological sciences

2021 Volume 28, Issue 11, Page(s) 6508–6514

Abstract: We explored the prevalence of insomnia, confirm the associated psychological factors and current coping strategies among undergraduate medical during their clinical years. This cross-sectional, quantitative, descriptive study was conducted at the ... ...

Abstract	We explored the prevalence of insomnia, confirm the associated psychological factors and current coping strategies among undergraduate medical during their clinical years. This cross-sectional, quantitative, descriptive study was conducted at the department of medical education, college of medicine, King Saud University (KSU), Riyadh, Saudi Arabia. The participants (n = 463) were the 3rd to 5th year, and intern medical clinical students. We collected responses about sleep, using the Insomnia Severity Index (ISI). We also used Kessler-10 (K10), Psychological Distress and the Patient Health Questionnaire (PHQ-9). Items related to Coping strategies were also used from our previously published study and COVID-19 issues were explored using a self-developed questionnaire. According to the ISI ranking, 162 (34.9 %) of the participants had insomnia, among them 57.4% of females and 42.6% were males. Age groups between 22 and 25 have more sleeping disorder (43.2%) as compared to other age groups. 3rd-year students have more insomnia 36.41% as compared to other years. Individuals with insomnia symptoms were more likely (1.67 times higher) to be female students (OR = 1.67; P = 0.005) as compared to male students. A significantly high prevalence (3.37 times high) of insomnia was noted for those students or interns who have attended their clinical training irregularly as compare to regularly attending participants (OR = 2.32; P = 0.12) during COVID-19. Transition time i.e. year 3 of medical program was more stressful for the students and female students perceived stress and insomnia more than their male counterparts. It is important to address identified disorder early in order to reduce psychological morbidity and its harmful implications for medical students and young physicians.
Language	English
Publishing date	2021-07-12
Publishing country	Saudi Arabia
Document type	Journal Article
ZDB-ID	2515206-3
ISSN	2213-7106 ; 1319-562X
ISSN (online)	2213-7106
ISSN	1319-562X
DOI	10.1016/j.sjbs.2021.07.022
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Article ; Online: Crystallographic Structure and Quantum-Chemical Analysis of Biologically Active Co(III)-Pyridoxal–Isothiosemicarbazone Complex

Fahad Abdulaziz / Khulood Fahad Alabbosh / Odeh Abdullah Odeh Alshammari / Wasan Mohammed Bin Tuwalah / Tahani Y. A. Alanazi / Aleksandra Rakić / Miljan Barić / Milica Marković / Violeta Jevtovic / Dušan Dimić

Inorganics, Vol 11, Iss 12, p

2023 Volume 466

Abstract: Semicarbazones and their transition metal complexes have been investigated as biologically active compounds. This study explores the synthesis, X-ray crystallographic structure, and characterization of a novel Co(III) complex cation with a pyridoxal- ... ...

Abstract	Semicarbazones and their transition metal complexes have been investigated as biologically active compounds. This study explores the synthesis, X-ray crystallographic structure, and characterization of a novel Co(III) complex cation with a pyridoxal-isothiosemicarbazone (PLITSC) ligand, [Co(PLITSC-2H)(NH 3 ) 3 ] + . The structure of the complex was further elucidated by the elemental analysis and spectroscopic techniques (IR and UV–VIS). Hirshfeld surface analysis was applied for the investigation of intermolecular interactions governing crystal structure. Optimization was performed at the B3LYP/6-31 + G(d,p)(H,C,N,O,S)/LanL2DZ(Co) level of theory without any geometrical constraints. The selected level of theory’s applicability was proven after comparing experimental and theoretical bond lengths and angles. The antibacterial activity of the complex towards E. coli and B. subtilis was determined and qualified as moderate compared to Streptomycin. The formation of free radical species in the presence of the complex was further verified in the fluorescence microscopy measurements. The molecular docking towards neural nitric-oxide synthase in the brain has shown that the complex structure and relative distribution of ligands were responsible for the binding to amino acids in the active pocket.
Keywords	DFT ; Co complex ; antimicrobial activity ; methylene blue ; QTAIM ; Inorganic chemistry ; QD146-197
Subject code	540
Language	English
Publishing date	2023-12-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
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Article ; Online: Impact of COVID-19 on Kidney of Diabetic Patients

Fahad Abdulaziz Al-Muhanna / Waleed Ibraham Ali Albakr / Arun Vijay Subbarayalu / Cyril Cyrus / Hend Ahmed Aljenaidi / Lamees Ali Alayoobi / Othman Al-Muhanna

Medicina, Vol 58, Iss 644, p

2022 Volume 644

Abstract: Given the current state of COVID-19, it is crucial to reveal its evolving relationship with and effect on different body organ systems and their diseases. The severity and outcome of COVID-19 have a very complex relationship, especially to the vital ... ...

Abstract	Given the current state of COVID-19, it is crucial to reveal its evolving relationship with and effect on different body organ systems and their diseases. The severity and outcome of COVID-19 have a very complex relationship, especially to the vital organs including the kidney, either in their state of health or disease. Additionally, it is well known that diabetes affects the kidney, leading to diabetic nephropathy. The kidney is also affected by different pathological and immunopathological reactions with COVID-19 infection, leading to acute kidney injury. Therefore, this review intended to extract the recent advances, updates, and discoveries about the effects of COVID-19 on diabetic patients and the relationship between COVID-19 invasion and the diabetic kidney and to discuss the current state of knowledge that has not yet been proved or disproved, leading to numerous controversial issues in looking for the effect of COVID-19 associated with diabetes mellitus on the human kidney.
Keywords	chronic kidney disease ; coronavirus disease 2019 (COVID-19) ; diabetic kidney disease ; diabetes mellitus ; human kidney ; Medicine (General) ; R5-920
Subject code	616
Language	English
Publishing date	2022-05-01T00:00:00Z
Publisher	MDPI AG
Document type	Article ; Online
Database	BASE - Bielefeld Academic Search Engine (life sciences selection)

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Article ; Online: New route for removal of Cu(II) using fabricated nanocomposite based on cationic surfactant/Ag-nanoparticles/silica gel

Eid.M.S. Azzam / Walaa I. Elsofany / Ghanimah K. Alrashdi / Khalaf M. Alenezi / Abdulmohsen K.D. Alsukaibi / Salman Latif / Fahad Abdulaziz / Ayman M. Atta

Arabian Journal of Chemistry, Vol 15, Iss 7, Pp 103897- (2022)

2022

Abstract: Generally, the treated wastewater must at least achieve the minimum safety standards for the purpose of the treatment process. The main target of this work is the combination of the features of surfactants, nanoparticles, and silica gel in one system for ...

Abstract	Generally, the treated wastewater must at least achieve the minimum safety standards for the purpose of the treatment process. The main target of this work is the combination of the features of surfactants, nanoparticles, and silica gel in one system for Cu(II) removal from the aqueous solution. To achieve this goal, the attempt would be made by the fabrication of nanocomposite based on 4-amino-N-tetradecyl pyridinium bromide (C14) coated silver nanoparticles and silica gel. The fabricated nanocomposite (C14-Ag-SG) was characterized using different techniques such as FTIR, XRD, XRF, SEM, and TEM. We examined the adsorption of Cu(II) ions onto the fabricated nanocomposite using batch adsorption. The effect of the contact time, pH of the solution, and mass of the adsorbent on the efficiency of adsorption was evaluated. The adsorption capacity of Cu(II) increased by increasing of the contact time with a neutral pH. The maximum removal of Cu(II) ions (98.57 %) was found using 0.4 g of the (C14-Ag-SG) nanocomposite. The fabricated nanocomposite showed high adsorption efficiency which clarifies the effect of the surfactant compound (C14) and silver nanoparticles in improving the adsorption efficiency. The results in this work suggest that the fabricated nanocomposite has high efficiency in the removal of Cu(II).
Keywords	Cationic surfactant ; Silica gel ; Nanocomposites ; Wastewater ; Cu(II) ; Chemistry ; QD1-999
Subject code	620
Language	English
Publishing date	2022-07-01T00:00:00Z
Publisher	Elsevier
Document type	Article ; Online
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Article: Implications of the COVID-19 Pandemic on the Mental Health and Professional Psychomotor Skills of Dental Students.

Alrashed, Fahad Abdulaziz / Sattar, Kamran / Habib, Syed Rashid / Ahmad, Tauseef / Al Rashoud, Abdulaziz Saud / Safhi, Turki Ali Y / Almajed, Abdulrhman Hamad M / Alnafisah, Hamad Ali H / Alharbi, Norah Hamad / Alsubiheen, Abdulrahman

Psychology research and behavior management

2021 Volume 14, Page(s) 675–685

Abstract: Purpose: To estimate dental students' self-perception of mental well-being (MWB) and its effects on their clinical psychomotor skills (CPS) once they (or their family members) get infected with COVID-19.: Materials and methods: This is a cross- ... ...

Abstract	Purpose: To estimate dental students' self-perception of mental well-being (MWB) and its effects on their clinical psychomotor skills (CPS) once they (or their family members) get infected with COVID-19. Materials and methods: This is a cross-sectional (n =268) study from a public dental college in Riyadh. We collected data on MWB and CPS. An 18-item online survey was used to collect the responses from the participants. The inter-rater reliability for the finalised survey came out to be 0.86. Results: The participants (54.3%) who were infected with COVID-19 recorded that their CPS were significantly affected (almost 4 times higher) as compared to others ( Conclusion: The study spotlighted the extent of dental students' MWB and its significant effect on their CPS once (themselves or a family member) infected with COVID-19. Moreover, levels of infection control measures at clinics resulted in psychological upsets for dental students. Clinical significance: The issue is fundamental as participants enter the clinical workforce and face the ever-increasing demands of dental practice.
Language	English
Publishing date	2021-06-03
Publishing country	New Zealand
Document type	Journal Article
ZDB-ID	2495093-2
ISSN	1179-1578
ISSN	1179-1578
DOI	10.2147/PRBM.S317641
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