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  1. Article ; Online: Flexible and Transparent Luminescent Cellulose-Transition Metal Cluster Composites

    Maria Amela-Cortes / Noée Dumait / Franck Artzner / Stéphane Cordier / Yann Molard

    Nanomaterials, Vol 13, Iss 580, p

    2023  Volume 580

    Abstract: Red-NIR luminescent polymers are principally obtained from petroleum-based derivatives in which emitters, usually a critical raw material such as rare-earth or platinum group metal ions, are embedded. Considering the strong ecological impact of their ... ...

    Abstract Red-NIR luminescent polymers are principally obtained from petroleum-based derivatives in which emitters, usually a critical raw material such as rare-earth or platinum group metal ions, are embedded. Considering the strong ecological impact of their synthesis and the major risk of fossil fuel energy shortage, there is an urgent need to find alternatives. We describe a luminescent nanocomposite based on red-NIR phosphorescent molybdenum nanoclusters, namely Cs 2 Mo 6 I 8 (OCOC 2 F 5 ) 6 , embedded in an eco-friendly cellulose biopolymer matrix that is obtained by a simple solvent casting technique. While homogeneity is kept up to 20 wt% of cluster complex doping, annealing hybrids leads to a large increase of their emission efficiency, as demonstrated by quantum yield measurements.
    Keywords NIR phosphorescence ; metal atom clusters ; biodegradable polymer ; Chemistry ; QD1-999
    Language English
    Publishing date 2023-01-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  2. Article ; Online: Force-Field Simulations of a Hydrated Lanreotide-Based Derivative

    Florian Pinzan / Franck Artzner / Aziz Ghoufi

    ACS Omega, Vol 5, Iss 39, Pp 25423-

    Hydration, Dynamics, and Numerical Evidence of Self-Assembly in Dimers

    2020  Volume 25431

    Keywords Chemistry ; QD1-999
    Language English
    Publishing date 2020-09-01T00:00:00Z
    Publisher American Chemical Society
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Article ; Online: Encapsulation of Luminescent Gold Nanoclusters into Synthetic Vesicles

    Regina M. Chiechio / Solène Ducarre / Célia Marets / Aurélien Dupont / Pascale Even-Hernandez / Xavier Pinson / Stéphanie Dutertre / Franck Artzner / Paolo Musumeci / Célia Ravel / Maria Jose Lo Faro / Valérie Marchi

    Nanomaterials, Vol 12, Iss 3875, p

    2022  Volume 3875

    Abstract: Gold nanoclusters (Au NCs) are attractive luminescent nanoprobes for biomedical applications. In vivo biosensing and bioimaging requires the delivery of the Au NCs into subcellular compartments. In this view, we explore here the possible encapsulation of ...

    Abstract Gold nanoclusters (Au NCs) are attractive luminescent nanoprobes for biomedical applications. In vivo biosensing and bioimaging requires the delivery of the Au NCs into subcellular compartments. In this view, we explore here the possible encapsulation of ultra-small-sized red and blue emitting Au NCs into liposomes of various sizes and chemical compositions. Different methods were investigated to prepare vesicles containing Au NCs in their lumen. The efficiency of the process was correlated to the structural and morphological aspect of the Au NCs’ encapsulating vesicles thanks to complementary analyses by SAXS, cryo-TEM, and confocal microscopy techniques. Cell-like-sized vesicles (GUVs) encapsulating red or blue Au NCs were successfully obtained by an innovative method using emulsion phase transfer. Furthermore, exosome-like-sized vesicles (LUVs) containing Au NCs were obtained with an encapsulation yield of 40%, as estimated from ICP-MS.
    Keywords gold nanoclusters ; vesicles ; encapsulation ; Chemistry ; QD1-999
    Subject code 540
    Language English
    Publishing date 2022-11-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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