Article ; Online: Frustrated Lewis Pair Chelation in the p-Block.
Chemistry (Weinheim an der Bergstrasse, Germany)
2023 Volume 29, Issue 65, Page(s) e202302332
Abstract: Frustrated Lewis pairs (FLPs) have been the subject of considerable study since the field's inception. While much of the research into FLPs has centered around small molecule activation for diverse stoichiometric and catalytic transformations, ... ...
| Abstract | Frustrated Lewis pairs (FLPs) have been the subject of considerable study since the field's inception. While much of the research into FLPs has centered around small molecule activation for diverse stoichiometric and catalytic transformations, intramolecular FLPs also show promise as chelating ligands. The cooperative action of Lewis basic and acidic moieties enables intramolecular FLPs to stabilize low oxidation state centers and (consequently) reactive molecular fragments through a donor-acceptor approach, making them an attractive ligand class in main group element chemistry. This review outlines the state of FLP chelation to date throughout the p-block, encompassing primarily groups 13-16. |
|---|---|
| Language | English |
| Publishing date | 2023-10-19 |
| Publishing country | Germany |
| Document type | Journal Article ; Review |
| ZDB-ID | 1478547-X |
| ISSN | 1521-3765 ; 0947-6539 |
| ISSN (online) | 1521-3765 |
| ISSN | 0947-6539 |
| DOI | 10.1002/chem.202302332 |
| Database | MEDical Literature Analysis and Retrieval System OnLINE |
More links
Kategorien
Order via subito
This service is chargeable due to the Delivery terms set by subito. Orders including an article and supplementary material will be classified as separate orders. In these cases, fees will be demanded for each order.