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  1. Article: Using Remotely Sensed Sea Surface Salinity and Colored Detrital Matter to Characterize Freshened Surface Layers in the Kara and Laptev Seas during the Ice-Free Season

    Umbert, Marta / Gabarro, Carolina / Olmedo, Estrella / Gonçalves-Araujo, Rafael / Guimbard, Sebastien / Martinez, Justino

    Remote Sensing. 2021 Sept. 24, v. 13, no. 19

    2021  

    Abstract: The overall volume of freshwater entering the Arctic Ocean has been growing as glaciers melt and river runoff increases. Since 1980, a 20% increase in river runoff has been observed in the Arctic system. As the discharges of the Ob, Yenisei, and Lena ... ...

    Abstract The overall volume of freshwater entering the Arctic Ocean has been growing as glaciers melt and river runoff increases. Since 1980, a 20% increase in river runoff has been observed in the Arctic system. As the discharges of the Ob, Yenisei, and Lena rivers are an important source of freshwater in the Kara and Laptev Seas, an increase in river discharge might have a significant impact on the upper ocean circulation. The fresh river water mixes with ocean water and forms a large freshened surface layer (FSL), which carries high loads of dissolved organic matter and suspended matter into the Arctic Ocean. Optically active material (e.g., phytoplankton and detrital matter) are spread out into plumes, which are evident in satellite data. Russian river signatures in the Kara and Laptev Seas are also evident in recent SMOS Sea Surface Salinity (SSS) Arctic products. In this study, we compare the new Arctic+ SSS products, produced at the Barcelona Expert Center, with the Ocean Color absorption coefficient of colored detrital matter (CDM) in the Kara and Laptev Seas for the period 2011–2019. The SSS and CDM are found to be strongly negatively correlated in the regions of freshwater influence, with regression coefficients between −0.72 and −0.91 in the studied period. Exploiting this linear correlation, we estimate the SSS back to 1998 using two techniques: one assuming that the relationship between the CDM and SSS varies regionally in the river-influenced areas, and another assuming that it does not. We use the 22-year time-series of reconstructed SSS to estimate the interannual variability of the extension of the FSL in the Kara and Laptev Seas as well as their freshwater content. For the Kara and Laptev Seas, we use 32 and 28 psu as reference salinities, and 26 and 24 psu isohalines as FSL boundaries, respectively. The average FSL extension in the Kara Sea is 2089–2611 km2, with a typical freshwater content of 11.84–14.02 km3. The Laptev Sea has a slightly higher mean FSL extension of 2320–2686 km2 and a freshwater content of 10.15–12.44 km3. The yearly mean freshwater content and extension of the FSL, computed from SMOS SSS and Optical data, is (as expected) found to co-vary with in situ measurements of river discharge from the Arctic Great Rivers Observatory database, demonstrating the potential of SMOS SSS to better monitor the river discharge changes in Eurasia and to understand the Arctic freshwater system during the ice-free season.
    Keywords Soil Moisture and Ocean Salinity satellite ; absorbance ; color ; databases ; dissolved organic matter ; freshwater ; phytoplankton ; remote sensing ; river flow ; river water ; rivers ; runoff ; salinity ; seawater ; time series analysis ; Arctic Ocean ; Arctic region ; Eurasia ; Kara Sea
    Language English
    Dates of publication 2021-0924
    Publishing place Multidisciplinary Digital Publishing Institute
    Document type Article
    ZDB-ID 2513863-7
    ISSN 2072-4292
    ISSN 2072-4292
    DOI 10.3390/rs13193828
    Database NAL-Catalogue (AGRICOLA)

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  2. Article ; Online: Characterization of aquatic organic matter: Assessment, perspectives and research priorities.

    Derrien, Morgane / Brogi, Simona Retelletti / Gonçalves-Araujo, Rafael

    Water research

    2019  Volume 163, Page(s) 114908

    Abstract: Organic matter (OM) refers to the largest reactive reservoir of carbon-based compounds on Earth. Aside of its role as a source of carbon, OM is also actively involved in a wide range of ecological functions. It also plays an important role in the ... ...

    Abstract Organic matter (OM) refers to the largest reactive reservoir of carbon-based compounds on Earth. Aside of its role as a source of carbon, OM is also actively involved in a wide range of ecological functions. It also plays an important role in the solubility, toxicity, bioavailability, mobility and distribution of pollutants. Therefore, OM is a key component in the local and global carbon cycle. About 12,000 articles containing organic matter in the title were published during the past decade, with a continuous increasing number each year (ISI Web of Science). Although this topic was widely explored and its interest has significantly increased, some limitations remain. These limitations can be technical (e.g., pre-treatment processes, low-resolution instrument, data handling) and can be related to the current approach. In this review, we first present the current strategies and tools to characterize the organic matter in the aquatic environment, then we tackle several aspects of current characterization limitations. Finally, we suggest new perspectives and priorities of research to improve the current limitations. From our point of view, simultaneous studies of particulate and dissolved OM fractions should be prioritized and multi-disciplinary approach, creation of databases, controlled experiments and collaborative works should be the next targets for future OM research priorities.
    MeSH term(s) Carbon ; Environmental Pollutants ; Minerals ; Organic Chemicals
    Chemical Substances Environmental Pollutants ; Minerals ; Organic Chemicals ; Carbon (7440-44-0)
    Language English
    Publishing date 2019-07-23
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 202613-2
    ISSN 1879-2448 ; 0043-1354
    ISSN (online) 1879-2448
    ISSN 0043-1354
    DOI 10.1016/j.watres.2019.114908
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: High colored dissolved organic matter (CDOM) absorption in surface waters of the central-eastern Arctic Ocean: Implications for biogeochemistry and ocean color algorithms.

    Gonçalves-Araujo, Rafael / Rabe, Benjamin / Peeken, Ilka / Bracher, Astrid

    PloS one

    2018  Volume 13, Issue 1, Page(s) e0190838

    Abstract: As consequences of global warming sea-ice shrinking, permafrost thawing and changes in fresh water and terrestrial material export have already been reported in the Arctic environment. These processes impact light penetration and primary production. To ... ...

    Abstract As consequences of global warming sea-ice shrinking, permafrost thawing and changes in fresh water and terrestrial material export have already been reported in the Arctic environment. These processes impact light penetration and primary production. To reach a better understanding of the current status and to provide accurate forecasts Arctic biogeochemical and physical parameters need to be extensively monitored. In this sense, bio-optical properties are useful to be measured due to the applicability of optical instrumentation to autonomous platforms, including satellites. This study characterizes the non-water absorbers and their coupling to hydrographic conditions in the poorly sampled surface waters of the central and eastern Arctic Ocean. Over the entire sampled area colored dissolved organic matter (CDOM) dominates the light absorption in surface waters. The distribution of CDOM, phytoplankton and non-algal particles absorption reproduces the hydrographic variability in this region of the Arctic Ocean which suggests a subdivision into five major bio-optical provinces: Laptev Sea Shelf, Laptev Sea, Central Arctic/Transpolar Drift, Beaufort Gyre and Eurasian/Nansen Basin. Evaluating ocean color algorithms commonly applied in the Arctic Ocean shows that global and regionally tuned empirical algorithms provide poor chlorophyll-a (Chl-a) estimates. The semi-analytical algorithms Generalized Inherent Optical Property model (GIOP) and Garver-Siegel-Maritorena (GSM), on the other hand, provide robust estimates of Chl-a and absorption of colored matter. Applying GSM with modifications proposed for the western Arctic Ocean produced reliable information on the absorption by colored matter, and specifically by CDOM. These findings highlight that only semi-analytical ocean color algorithms are able to identify with low uncertainty the distribution of the different optical water constituents in these high CDOM absorbing waters. In addition, a clustering of the Arctic Ocean into bio-optical provinces will help to develop and then select province-specific ocean color algorithms.
    MeSH term(s) Algorithms ; Arctic Regions ; Chlorophyll/analysis ; Chlorophyll A ; Color ; Oceans and Seas ; Organic Chemicals/chemistry ; Physical Phenomena ; Solubility ; Spectrum Analysis/methods
    Chemical Substances Organic Chemicals ; Chlorophyll (1406-65-1) ; Chlorophyll A (YF5Q9EJC8Y)
    Language English
    Publishing date 2018-01-05
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2267670-3
    ISSN 1932-6203 ; 1932-6203
    ISSN (online) 1932-6203
    ISSN 1932-6203
    DOI 10.1371/journal.pone.0190838
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Basin-scale variability in phytoplankton size-abundance spectra across the Atlantic Ocean

    González-García, Cristina / Agustí, Susana / Aiken, J. / Bertrand, Arnaud / Bittencourt Farias, Gabriel / Bode, Antonio / Carré, Claire / Gonçalves-Araujo, Rafael / Harbour, Derek S. / Huete-Ortega, María / Melo, Pedro A.M.C. / Moreno-Ostos, Enrique / Rees, Andrew P. / Rodríguez, Jaime / da Silva, Sonia / Zubkov, Mikhail / Marañón, Emilio

    Progress in Oceanography. 2023 Sept., Oct., v. 217 p.103104-

    2023  

    Abstract: Phytoplankton size structure, a major determinant of trophic structure and biogeochemical functioning in pelagic ecosystems, can be described by the slope of the size-abundance spectrum (SAS). Previous observational studies reporting spatio-temporal ... ...

    Abstract Phytoplankton size structure, a major determinant of trophic structure and biogeochemical functioning in pelagic ecosystems, can be described by the slope of the size-abundance spectrum (SAS). Previous observational studies reporting spatio-temporal changes in phytoplankton SAS slope have focused on particular open-ocean or coastal environments. Therefore, the overall variability in phytoplankton SAS slope still has not been investigated over wide ranges of biomass and productivity including both oligotrophic open-ocean regions and productive coastal waters. Here we present a multi-cruise overview of the basin-scale variability in phytoplankton biomass and SAS slope across the Atlantic Ocean, covering coastal, shelf, and oceanic environments over the 50°N-50°S latitude range. We find the inverse relationship between cell size and abundance to be pervasive across the studied regions, even in highly productive coastal waters. In oceanic regions, consistent latitudinal patterns are observed in the relationship between nutricline depth, phytoplankton biomass and SAS slope. There is a strong degree of covariation between SAS slope at the surface and at the base of the euphotic layer, indicating that geographical changes in phytoplankton size structure override vertical variability. A basin-scale relationship exists between increasing resource supply, enhanced phytoplankton biomass, and progressively less steep SAS slopes, reflecting increasing importance of large cells in more productive waters. However, the relationship between ecosystem productivity and both SAS slope and mean community cell size is saturating, which means there is no continuous trend towards ever increasing contribution by larger cells. Similar phytoplankton size structures, with a biomass dominance by the 2–20 μm size class, are found in both moderately and highly eutrophic waters. Our results provide an observational benchmark for testing the predictions of size-based plankton models and for assessing future, climate-related shifts in phytoplankton size structure in both coastal and oceanic regions of the Atlantic Ocean.
    Keywords biomass ; ecosystems ; eutrophication ; latitude ; oceanography ; phytoplankton ; Atlantic Ocean
    Language English
    Dates of publication 2023-09
    Publishing place Elsevier Ltd
    Document type Article ; Online
    ISSN 0079-6611
    DOI 10.1016/j.pocean.2023.103104
    Database NAL-Catalogue (AGRICOLA)

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  5. Article: Insights Into Water Mass Origins in the Central Arctic Ocean From In‐Situ Dissolved Organic Matter Fluorescence

    Stedmon, Colin A. / Amon, Rainer M. W. / Bauch, Dorothea / Bracher, Astrid / Gonçalves‐Araujo, Rafael / Hoppmann, Mario / Krishfield, Richard / Laney, Samuel / Rabe, Benjamin / Reader, Heather / Granskog, Mats A.

    Journal of geophysical research. 2021 July, v. 126, no. 7

    2021  

    Abstract: The Arctic Ocean receives a large supply of dissolved organic matter (DOM) from its catchment and shelf sediments, which can be traced across much of the basin's upper waters. This signature can potentially be used as a tracer. On the shelf, the ... ...

    Abstract The Arctic Ocean receives a large supply of dissolved organic matter (DOM) from its catchment and shelf sediments, which can be traced across much of the basin's upper waters. This signature can potentially be used as a tracer. On the shelf, the combination of river discharge and sea‐ice formation, modifies water densities and mixing considerably. These waters are a source of the halocline layer that covers much of the Arctic Ocean, but also contain elevated levels of DOM. Here we demonstrate how this can be used as a supplementary tracer and contribute to evaluating ocean circulation in the Arctic. A fraction of the organic compounds that DOM consists of fluoresce and can be measured using in‐situ fluorometers. When deployed on autonomous platforms these provide high temporal and spatial resolution measurements over long periods. The results of an analysis of data derived from several Ice Tethered Profilers (ITPs) offer a unique spatial coverage of the distribution of DOM in the surface 800 m below Arctic sea‐ice. Water mass analysis using temperature, salinity and DOM fluorescence, can clearly distinguish between the contribution of Siberian terrestrial DOM and marine DOM from the Chukchi shelf to the waters of the halocline. The findings offer a new approach to trace the distribution of Pacific waters and its export from the Arctic Ocean. Our results indicate the potential to extend the approach to separate freshwater contributions from, sea‐ice melt, riverine discharge and the Pacific Ocean.
    Keywords basins ; dissolved organic matter ; exports ; fluorescence ; freshwater ; geophysics ; research ; riparian areas ; river flow ; salinity ; sea ice ; temperature ; watersheds ; Arctic Ocean ; Arctic region ; Pacific Ocean
    Language English
    Dates of publication 2021-07
    Publishing place John Wiley & Sons, Ltd
    Document type Article
    Note JOURNAL ARTICLE
    ZDB-ID 161667-5
    ISSN 2169-9291 ; 2169-9275 ; 0148-0227 ; 0196-2256
    ISSN (online) 2169-9291
    ISSN 2169-9275 ; 0148-0227 ; 0196-2256
    DOI 10.1029/2021JC017407
    Database NAL-Catalogue (AGRICOLA)

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  6. Book ; Online ; Thesis: Tracing environmental variability in the changing Arctic Ocean with optical measurements of dissolved organic matter

    Gonçalves Araujo, Rafael [Verfasser] / Bracher, Astrid [Akademischer Betreuer] [Gutachter] / Stedmon, Colin [Gutachter]

    2016  

    Author's details Rafael Gonçalves Araujo ; Gutachter: Astrid Bracher, Colin Stedmon ; Betreuer: Astrid Bracher
    Keywords Naturwissenschaften ; Science
    Subject code sg500
    Language English
    Publisher Staats- und Universitätsbibliothek Bremen
    Publishing place Bremen
    Document type Book ; Online ; Thesis
    Database Digital theses on the web

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  7. Article ; Online: Towards Cost-Effective Operational Monitoring Systems for Complex Waters: Analyzing Small-Scale Coastal Processes with Optical Transmissometry.

    Ramírez-Pérez, Marta / Gonçalves-Araujo, Rafael / Wiegmann, Sonja / Torrecilla, Elena / Bardaji, Raul / Röttgers, Rüdiger / Bracher, Astrid / Piera, Jaume

    PloS one

    2017  Volume 12, Issue 1, Page(s) e0170706

    Abstract: The detection and prediction of changes in coastal ecosystems require a better understanding of the complex physical, chemical and biological interactions, which involves that observations should be performed continuously. For this reason, there is an ... ...

    Abstract The detection and prediction of changes in coastal ecosystems require a better understanding of the complex physical, chemical and biological interactions, which involves that observations should be performed continuously. For this reason, there is an increasing demand for small, simple and cost-effective in situ sensors to analyze complex coastal waters at a broad range of scales. In this context, this study seeks to explore the potential of beam attenuation spectra, c(λ), measured in situ with an advanced-technology optical transmissometer, for assessing temporal and spatial patterns in the complex estuarine waters of Alfacs Bay (NW Mediterranean) as a test site. In particular, the information contained in the spectral beam attenuation coefficient was assessed and linked with different biogeochemical variables. The attenuation at λ = 710 nm was used as a proxy for particle concentration, TSM, whereas a novel parameter was adopted as an optical indicator for chlorophyll a (Chl-a) concentration, based on the local maximum of c(λ) observed at the long-wavelength side of the red band Chl-a absorption peak. In addition, since coloured dissolved organic matter (CDOM) has an important influence on the beam attenuation spectral shape and complementary measurements of particle size distribution were available, the beam attenuation spectral slope was used to analyze the CDOM content. Results were successfully compared with optical and biogeochemical variables from laboratory analysis of collocated water samples, and statistically significant correlations were found between the attenuation proxies and the biogeochemical variables TSM, Chl-a and CDOM. This outcome depicted the potential of high-frequency beam attenuation measurements as a simple, continuous and cost-effective approach for rapid detection of changes and patterns in biogeochemical properties in complex coastal environments.
    MeSH term(s) Chlorophyll/analysis ; Cost-Benefit Analysis ; Ecosystem ; Environmental Monitoring/economics ; Environmental Monitoring/methods ; Mediterranean Sea ; Optical Phenomena ; Seawater/chemistry
    Chemical Substances Chlorophyll (1406-65-1) ; chlorophyll a (YF5Q9EJC8Y)
    Language English
    Publishing date 2017
    Publishing country United States
    Document type Journal Article
    ISSN 1932-6203
    ISSN (online) 1932-6203
    DOI 10.1371/journal.pone.0170706
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Using fluorescent dissolved organic matter to trace and distinguish the origin of Arctic surface waters.

    Gonçalves-Araujo, Rafael / Granskog, Mats A / Bracher, Astrid / Azetsu-Scott, Kumiko / Dodd, Paul A / Stedmon, Colin A

    Scientific reports

    2016  Volume 6, Page(s) 33978

    Abstract: Climate change affects the Arctic with regards to permafrost thaw, sea-ice melt, alterations to the freshwater budget and increased export of terrestrial material to the Arctic Ocean. The Fram and Davis Straits represent the major gateways connecting the ...

    Abstract Climate change affects the Arctic with regards to permafrost thaw, sea-ice melt, alterations to the freshwater budget and increased export of terrestrial material to the Arctic Ocean. The Fram and Davis Straits represent the major gateways connecting the Arctic and Atlantic. Oceanographic surveys were performed in the Fram and Davis Straits, and on the east Greenland Shelf (EGS), in late summer 2012/2013. Meteoric (f
    Language English
    Publishing date 2016-09-26
    Publishing country England
    Document type Journal Article
    ZDB-ID 2615211-3
    ISSN 2045-2322 ; 2045-2322
    ISSN (online) 2045-2322
    ISSN 2045-2322
    DOI 10.1038/srep33978
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  9. Book ; Online: The influence of dissolved organic matter on the marine production of carbonyl sulfide (OCS) and carbon disulfide (CS2) in the Peruvian upwelling

    Lennartz, Sinikka T. / Hobe, Marc / Booge, Dennis / Bittig, Henry C. / Fischer, Tim / Gonçalves-Araujo, Rafael / Ksionzek, Kerstin B. / Koch, Boris P. / Bracher, Astrid / Röttgers, Rüdiger / Quack, Birgit / Marandino, Christa A.

    eISSN: 1812-0792

    2019  

    Abstract: Oceanic emissions of the climate-relevant trace gases carbonyl sulfide (OCS) and carbon disulfide ( CS 2 ) are a major source to their atmospheric budget. Their current and future emission estimates are still uncertain due to incomplete process ... ...

    Abstract Oceanic emissions of the climate-relevant trace gases carbonyl sulfide (OCS) and carbon disulfide ( CS 2 ) are a major source to their atmospheric budget. Their current and future emission estimates are still uncertain due to incomplete process understanding and therefore inexact quantification across different biogeochemical regimes. Here we present the first concurrent measurements of both gases together with related fractions of the dissolved organic matter (DOM) pool, i.e., solid-phase extractable dissolved organic sulfur (DOS SPE , n =24 , 0.16±0.04 µ mol L −1 ), chromophoric (CDOM, n =76 , 0.152±0.03 ), and fluorescent dissolved organic matter (FDOM, n =35 ), from the Peruvian upwelling region (Guayaquil, Ecuador to Antofagasta, Chile, October 2015). OCS was measured continuously with an equilibrator connected to an off-axis integrated cavity output spectrometer at the surface ( 29.8±19.8 pmol L −1 ) and at four profiles ranging down to 136 m. CS 2 was measured at the surface ( n =143 , 17.8±9.0 pmol L −1 ) and below, ranging down to 1000 m (24 profiles). These observations were used to estimate in situ production rates and identify their drivers. We find different limiting factors of marine photoproduction: while OCS production is limited by the humic-like DOM fraction that can act as a photosensitizer, high CS 2 production coincides with high DOS SPE concentration. Quantifying OCS photoproduction using a specific humic-like FDOM component as proxy, together with an updated parameterization for dark production, improves agreement with observations in a 1-D biogeochemical model. Our results will help to better predict oceanic concentrations and emissions of both gases on regional and, potentially, global scales.
    Subject code 511 ; 333
    Language English
    Publishing date 2019-08-14
    Publishing country de
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  10. Book ; Online: The influence of dissolved organic matter on the marine production of carbonyl sulfide (OCS) and carbon disulfide (CS2) in the Eastern Tropical South Pacific

    Lennartz, Sinikka T. / Hobe, Marc / Booge, Dennis / Bittig, Henry / Fischer, Tim / Gonçalves-Araujo, Rafael / Ksionzek, Kerstin B. / Koch, Boris P. / Bracher, Astrid / Röttgers, Rüdiger / Quack, Birgit / Marandino, Christa A.

    eISSN: 1812-0792

    2019  

    Abstract: Oceanic emissions of the climate relevant trace gases carbonyl sulfide (OCS) and carbon disulfide (CS2) are a major source to their atmospheric budget. Their current and future emission estimates are still uncertain due to incomplete process ... ...

    Abstract Oceanic emissions of the climate relevant trace gases carbonyl sulfide (OCS) and carbon disulfide (CS2) are a major source to their atmospheric budget. Their current and future emission estimates are still uncertain due to incomplete process understanding and, therefore, inexact quantification across different biogeochemical regimes. Here we present the first concurrent measurements of both gases together with related fractions of the dissolved organic matter (DOM) pool, i.e. solid-phase extractable dissolved organic sulfur (DOSSPE), chromophoric (CDOM) and fluorescent dissolved organic matter (FDOM) from the Eastern Tropical South Pacific (ETSP). These observations are used to estimate in-situ production rates and identify their drivers. We find different limiting factors of marine photoproduction: while OCS production is limited by the humic-like DOM fraction that can act as a photosensitizer, high CS2 production coincides with high DOSSPE concentration. The lack of correlation between OCS production and DOSSPE may be explained by the active cycling of sulfur between OCS and dissolved inorganic sulfide via OCS photoproduction and hydrolysis. In addition, the only existing parameterization for OCS dark production is validated and updated with new rates from the ETSP and the Indian Ocean. Our results will help to predict oceanic concentrations and emissions of both gases on regional and, potentially, global scales.
    Subject code 551
    Language English
    Publishing date 2019-03-01
    Publishing country de
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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