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  1. Article ; Online: In Vitro Assessment of the Physiologically Relevant Oral Bioaccessibility of Metallic Elements in Edible Herbs Using the Unified Bioaccessibility Protocol.

    Choleva, Tatiana G / Tziasiou, Charikleia / Gouma, Vasiliki / Vlessidis, Athanasios G / Giokas, Dimosthenis L

    Molecules (Basel, Switzerland)

    2023  Volume 28, Issue 14

    Abstract: In this work, the total content of seven metallic elements (Fe, Cu, Zn, Mg, Pb, Ni, and Co) in common edible herbs was determined and related to their bioaccessibility by an in vitro human digestion model. Specifically, the unified bioaccessibility ... ...

    Abstract In this work, the total content of seven metallic elements (Fe, Cu, Zn, Mg, Pb, Ni, and Co) in common edible herbs was determined and related to their bioaccessibility by an in vitro human digestion model. Specifically, the unified bioaccessibility protocol developed by the BioAccessibility Research Group of Europe (BARGE) was used to determine the release of each element during gastric and gastrointestinal digestion. The results show that Fe, Zn, and Mg are released during gastric digestion (34-57% Fe, 28-80% Zn, 79-95% Mg), but their overall bioaccessibility is reduced in the gastrointestinal tract (<30%). On the contrary, Cu is more bioaccessible during gastrointestinal digestion (38-60%). Pb, Ni, and Co exhibited similar bioaccessibility in both gastric and gastrointestinal fluids. Principle component analysis of the data shows that the classification of the nutritional value of herbs differs between the total and the gastrointestinal concentration, suggesting that the total concentration alone is not an adequate indicator for drawing secure conclusions concerning the nutritional benefits of edible plant species.
    MeSH term(s) Humans ; Lead/analysis ; Gastrointestinal Tract/metabolism ; Europe ; Stomach/chemistry ; Soil Pollutants/analysis ; Environmental Monitoring/methods ; Biological Availability
    Chemical Substances Lead (2P299V784P) ; Soil Pollutants
    Language English
    Publishing date 2023-07-14
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules28145396
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Fabric phase sorpitive extraction and passive sampling of ultraviolet filters from natural waters using a zirconium metal organic framework-cotton composite.

    Gouma, Vasiliki / Pournara, Anastasia D / Manos, Manolis J / Giokas, Dimosthenis L

    Journal of chromatography. A

    2022  Volume 1670, Page(s) 462945

    Abstract: In this work, we introduce the use of MOFs immobilized on cotton fabrics as a sorbent phase for the fabric phase sorptive extraction and passive sampling of non-polar organic compounds from water samples. A water-stable, ... ...

    Abstract In this work, we introduce the use of MOFs immobilized on cotton fabrics as a sorbent phase for the fabric phase sorptive extraction and passive sampling of non-polar organic compounds from water samples. A water-stable, Zr
    MeSH term(s) Chromatography, High Pressure Liquid/methods ; Metal-Organic Frameworks/chemistry ; Phthalic Acids ; Water ; Zirconium/chemistry
    Chemical Substances Metal-Organic Frameworks ; Phthalic Acids ; UiO-66 ; Water (059QF0KO0R) ; Zirconium (C6V6S92N3C)
    Language English
    Publishing date 2022-03-13
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 1171488-8
    ISSN 1873-3778 ; 0021-9673
    ISSN (online) 1873-3778
    ISSN 0021-9673
    DOI 10.1016/j.chroma.2022.462945
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Fabric phase sorpitive extraction and passive sampling of ultraviolet filters from natural waters using a zirconium metal organic framework-cotton composite

    Gouma, Vasiliki / Pournara, Anastasia D. / Manos, Manolis J. / Giokas, Dimosthenis L.

    Journal of chromatography. 2022 May 10, v. 1670

    2022  

    Abstract: In this work, we introduce the use of MOFs immobilized on cotton fabrics as a sorbent phase for the fabric phase sorptive extraction and passive sampling of non-polar organic compounds from water samples. A water-stable, Zr⁴⁺-based MOF (UiO-66(Zr)-NH₂) ... ...

    Abstract In this work, we introduce the use of MOFs immobilized on cotton fabrics as a sorbent phase for the fabric phase sorptive extraction and passive sampling of non-polar organic compounds from water samples. A water-stable, Zr⁴⁺-based MOF (UiO-66(Zr)-NH₂) was irreversibly immobilized on polydopamine decorated cotton through a step-wise synthetic procedure that maximized the amount of MOF immobilized on the fabric surface. In this manner it was possible to combine the permeability and the large contact surface area of the host cotton substrate with the high specific surface area and sorption capacity of the MOF. The MOF@cotton composite was used as a new sorbent phase for the fabric phase sorptive extraction of UV filters, as model organic compounds, not only under static (i.e. stirring assisted) but also in dynamic, flow-through extraction mode (i.e. as a solid phase extraction sorbent phase), producing satisfactory analytical results in terms of linearity of calibration curves (10–250 µg L⁻¹), precision (<11%), detection limits <10 µg L⁻¹ (using a single wavelength UV detector) and recoveries (86 - 119%) from various natural water samples. As a passive sampling sorbent phase, the MOF@cotton composite could linearly accumulate UV filters over time period of 35 days with sampling rates from 0.026 to 0.352 L d⁻¹, which are comparable to other passive sampling sorbent phases.
    Keywords calibration ; chromatography ; cotton ; permeability ; solid phase extraction ; sorbents ; sorption ; surface area ; wavelengths ; zirconium
    Language English
    Dates of publication 2022-0510
    Publishing place Elsevier B.V.
    Document type Article
    ZDB-ID 218139-3
    ISSN 0021-9673 ; 0378-4355 ; 0376-737X
    ISSN 0021-9673 ; 0378-4355 ; 0376-737X
    DOI 10.1016/j.chroma.2022.462945
    Database NAL-Catalogue (AGRICOLA)

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  4. Article ; Online: Biothiol modulated growth and aggregation of gold nanoparticles and their determination in biological fluids using digital photometry.

    Akrivi, Elli / Kappi, Foteini / Gouma, Vasiliki / Vlessidis, Athanasios G / Giokas, Dimosthenis L / Kourkoumelis, Nikolaos

    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy

    2020  Volume 249, Page(s) 119337

    Abstract: This work describes a novel and easy to use method for the determination of biologically important thiols that relies on their ability to inhibit the catalytic enlargement of AuNP seeds in the presence of ... ...

    Abstract This work describes a novel and easy to use method for the determination of biologically important thiols that relies on their ability to inhibit the catalytic enlargement of AuNP seeds in the presence of ACl
    MeSH term(s) Colorimetry ; Gold ; Metal Nanoparticles ; Photometry ; Reproducibility of Results
    Chemical Substances Gold (7440-57-5)
    Language English
    Publishing date 2020-12-10
    Publishing country England
    Document type Journal Article
    ZDB-ID 210413-1
    ISSN 1873-3557 ; 0370-8322 ; 0584-8539 ; 1386-1425
    ISSN (online) 1873-3557
    ISSN 0370-8322 ; 0584-8539 ; 1386-1425
    DOI 10.1016/j.saa.2020.119337
    Database MEDical Literature Analysis and Retrieval System OnLINE

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