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  1. Article ; Online: Enhanced thermoelectric properties of In-filled Co

    Ghosh, Sanyukta / Jain, Shubhanth / Mishra, Soumya Ranjan / Rogl, Gerda / Rogl, Peter / Bauer, Ernst / Murty, B S / Govindaraj, A / Mallik, Ramesh Chandra

    Dalton transactions (Cambridge, England : 2003)

    2024  Volume 53, Issue 2, Page(s) 715–723

    Abstract: Uniform dispersion of nanosized secondary phases in bulk thermoelectric materials has proven to be an effective strategy to reduce the lattice part of thermal conductivity and improve the thermoelectric efficiency. In this work, reduced graphene oxide ( ... ...

    Abstract Uniform dispersion of nanosized secondary phases in bulk thermoelectric materials has proven to be an effective strategy to reduce the lattice part of thermal conductivity and improve the thermoelectric efficiency. In this work, reduced graphene oxide (rGO) was uniformly dispersed in the In
    Language English
    Publishing date 2024-01-02
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt03399f
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Green synthesis, characterization, and antibacterial activity of

    Govindaraj, Aravinthrajkumar / Ramakrishnan, Mahesh / Shanmugam, Rajeshkumar / Sp, Saravana Dinesh

    Bioinformation

    2023  Volume 19, Issue 4, Page(s) 403–406

    Abstract: Due to their enhanced and unique physicochemical characteristics, such as their minimal dimensions, large surface area compared to their mass and increased reactivity, nanomaterials hold promise in the field of antibacterial therapy. The aim of this ... ...

    Abstract Due to their enhanced and unique physicochemical characteristics, such as their minimal dimensions, large surface area compared to their mass and increased reactivity, nanomaterials hold promise in the field of antibacterial therapy. The aim of this study is to evaluate the method for Green Synthesis, Characterization of
    Language English
    Publishing date 2023-04-30
    Publishing country Singapore
    Document type Journal Article
    ZDB-ID 2203786-X
    ISSN 0973-2063
    ISSN 0973-2063
    DOI 10.6026/97320630019403
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Raccoon eyes in cutaneous neonatal lupus syndrome.

    Mohanasundaram, Kavitha / Govindaraj, Ashok

    European journal of rheumatology

    2019  Volume 7, Issue 2, Page(s) 92–93

    Language English
    Publishing date 2019-11-25
    Publishing country Turkey
    Document type Journal Article
    ZDB-ID 2873727-1
    ISSN 2148-4279 ; 2147-9720
    ISSN (online) 2148-4279
    ISSN 2147-9720
    DOI 10.5152/eurjrheum.2019.19042
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Facile synthesis of Pd(ii) and Ni(ii) pincer carbene complexes by the double C-H bond activation of a new hexahydropyrimidine-based bis(phosphine): catalysis of C-N couplings.

    Subramaniyan, Vasudevan / Dutta, Bidisa / Govindaraj, Anbarasu / Mani, Ganesan

    Dalton transactions (Cambridge, England : 2003)

    2019  Volume 48, Issue 21, Page(s) 7203–7210

    Abstract: Hexahydropyrimidine-based bis(phosphine), a pro-NHC ligand, was synthesized in one step and excellent yield. It underwent spontaneous double C-H bond activation to give cationic pincer NHC complexes of the type [(PCP)MCl]X (M = Pd, Ni and X = Cl, BF4) in ...

    Abstract Hexahydropyrimidine-based bis(phosphine), a pro-NHC ligand, was synthesized in one step and excellent yield. It underwent spontaneous double C-H bond activation to give cationic pincer NHC complexes of the type [(PCP)MCl]X (M = Pd, Ni and X = Cl, BF4) in the absence of any external reagents. Their structures were determined by X-ray diffraction methods and the mechanism of formation of palladium carbene complexes as analyzed by DFT calculations showed two transition states. The Pd(ii) carbene complex effectively catalyzes a few C-N cross coupling reactions.
    Language English
    Publishing date 2019-01-17
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c8dt03413c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Crystal structure and DFT analyses of a pentacoordinated PCP pincer nickel(II) complex.

    Subramaniyan, Vasudevan / Kumar, Ashok / Govindaraj, Anbarasu / Mani, Ganesan

    Acta crystallographica. Section C, Structural chemistry

    2019  Volume 75, Issue Pt 6, Page(s) 734–739

    Abstract: The reaction of ... ...

    Abstract The reaction of NiCl
    Language English
    Publishing date 2019-05-21
    Publishing country England
    Document type Journal Article
    ZDB-ID 2025703-X
    ISSN 2053-2296 ; 1600-5759 ; 0108-2701
    ISSN (online) 2053-2296 ; 1600-5759
    ISSN 0108-2701
    DOI 10.1107/S2053229619006211
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Noteworthy performance of La(1-x)Ca(x)MnO3 perovskites in generating H2 and CO by the thermochemical splitting of H2O and CO2.

    Dey, Sunita / Naidu, B S / Govindaraj, A / Rao, C N R

    Physical chemistry chemical physics : PCCP

    2015  Volume 17, Issue 1, Page(s) 122–125

    Abstract: Perovskite oxides of the composition La1-xCaxMnO3 (LCM) have been investigated for the thermochemical splitting of H2O and CO2 to produce H2 and CO, respectively. The study was carried out in comparison with La1-xSrxMnO3, CeO2 and other oxides. The LCM ... ...

    Abstract Perovskite oxides of the composition La1-xCaxMnO3 (LCM) have been investigated for the thermochemical splitting of H2O and CO2 to produce H2 and CO, respectively. The study was carried out in comparison with La1-xSrxMnO3, CeO2 and other oxides. The LCM system exhibits superior characteristics in high-temperature evolution of oxygen, and in reducing CO2 to CO and H2O to H2. The best results were obtained with La0.5Ca0.5MnO3 whose performance is noteworthy compared to that of other oxides including ceria. The orthorhombic structure of LCM seems to be a crucial factor.
    Language English
    Publishing date 2015-01-07
    Publishing country England
    Document type Journal Article
    ZDB-ID 1476244-4
    ISSN 1463-9084 ; 1463-9076
    ISSN (online) 1463-9084
    ISSN 1463-9076
    DOI 10.1039/c4cp04578e
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: In vitro Thrombolytic Potential of Actinoprotease from Marine Streptomyces violaceus VITYGM.

    Mohanasrinivasan, V / Yogesh, S / Govindaraj, A / Naine, S Jemimah / Devi, C Subathra

    Cardiovascular & hematological agents in medicinal chemistry

    2017  Volume 14, Issue 2, Page(s) 120–124

    Abstract: Back ground: One of the most prevailing diseases that required effective drug as therapeutic purposes is cardiac related illness includes myocardial infarction Current scenario makes enzyme to raises their sector towards therapeutic as effective active ... ...

    Abstract Back ground: One of the most prevailing diseases that required effective drug as therapeutic purposes is cardiac related illness includes myocardial infarction Current scenario makes enzyme to raises their sector towards therapeutic as effective active component for such diseases.
    Objectives: The main aim of the study was to isolate, screen, characterize and produce an extracellular thrombolytic protease from marine actinomycetes.
    Methods: Marine actinomycete was isolated and characterized on the basis of morphological, biochemical, and molecular characterization. The primary screening for protease activity was done by casein hydrolysis method followed by radial caseinolytic assay. The actinoprotease was partially purified using ammonium sulfate precipitation technique followed by dialysis and Sephadex G-50 gel permeation chromatography.
    Results: 16srDNA sequencing and BLAST search analysis of the sequence revealed close affiliation with Streptomyces genera and identified as Streptomyces violaceus VITYGM with 99% similarity. The specific activity of purified protease was found to be 1437 units/mg along with purification fold up to 1.5 times. The blood clot lysis activity was compared with the standard and found to lyse the blood clot with 97.43%. Till now very less evidences have been reported on actinoprotease. A single peak at retention time 0.9 min observed on high performance liquid chromatography (HPLC) confirmed the homogeneity of the preparation.
    Conclusion: This is the first study to report on actinoprotease from Streptomyces violaceus VITYGM. This study emphasizes the potency of novel actinoproteases as active compound in drugs for the treatment of cardiovascular diseases.
    MeSH term(s) Blood Coagulation/drug effects ; Cardiovascular Diseases/drug therapy ; Caseins/metabolism ; Fibrinolytic Agents/isolation & purification ; Fibrinolytic Agents/pharmacology ; Humans ; Peptide Hydrolases/isolation & purification ; Peptide Hydrolases/pharmacology ; Streptomyces/enzymology
    Chemical Substances Caseins ; Fibrinolytic Agents ; Peptide Hydrolases (EC 3.4.-)
    Language English
    Publishing date 2017
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 2215710-4
    ISSN 1875-6182 ; 1871-5257
    ISSN (online) 1875-6182
    ISSN 1871-5257
    DOI 10.2174/1871525715666161104112553
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Importance of trivalency and the e(g)(1) configuration in the photocatalytic oxidation of water by Mn and Co oxides.

    Maitra, Urmimala / Naidu, B S / Govindaraj, A / Rao, C N R

    Proceedings of the National Academy of Sciences of the United States of America

    2013  Volume 110, Issue 29, Page(s) 11704–11707

    Abstract: Prompted by the early results on the catalytic activity of LiMn2O4 and related oxides in the photochemical oxidation of water, our detailed study of several manganese oxides has shown that trivalency of Mn is an important factor in determining the ... ...

    Abstract Prompted by the early results on the catalytic activity of LiMn2O4 and related oxides in the photochemical oxidation of water, our detailed study of several manganese oxides has shown that trivalency of Mn is an important factor in determining the catalytic activity. Thus, Mn2O3, LaMnO3, and MgMn2O4 are found to be very good catalysts with turnover frequencies of 5 × 10(-4) s(-1), 4.8 × 10(-4) s(-1), and 0.8 × 10(-4) s(-1), respectively. Among the cobalt oxides, Li2Co2O4 and LaCoO3--especially the latter--exhibit excellent catalytic activity, with the turnover frequencies being 9 × 10(-4) s(-1) and 1.4 × 10(-3) s(-1), respectively. The common feature among the catalytic Mn and Co oxides is not only that Mn and Co are in the trivalent state, but Co(3+) in the Co oxides is in the intermediate t2g(5)e(g)(1) state whereas Mn(3+) is in the t2g(3e(g)(1) state. The presence of the e(g)(1) electron in these Mn and Co oxides is considered to play a crucial role in the photocatalytic properties of the oxides.
    MeSH term(s) Catalysis ; Cobalt/chemistry ; Electrons ; Manganese Compounds/chemistry ; Molecular Conformation ; Nanoparticles/chemistry ; Oxides/chemistry ; Oxygen/chemistry ; Photochemistry/methods ; Photosynthesis ; Solar Energy ; Water/chemistry ; X-Ray Diffraction
    Chemical Substances Manganese Compounds ; Oxides ; Water (059QF0KO0R) ; Cobalt (3G0H8C9362) ; manganese oxide (64J2OA7MH3) ; Oxygen (S88TT14065) ; cobalt oxide (USK772NS56)
    Language English
    Publishing date 2013-07-01
    Publishing country United States
    Document type Evaluation Study ; Journal Article
    ZDB-ID 209104-5
    ISSN 1091-6490 ; 0027-8424
    ISSN (online) 1091-6490
    ISSN 0027-8424
    DOI 10.1073/pnas.1310703110
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Selective generation of single-walled carbon nanotubes with metallic, semiconducting and other unique electronic properties.

    Rao, C N R / Voggu, Rakesh / Govindaraj, A

    Nanoscale

    2009  Volume 1, Issue 1, Page(s) 96–105

    Abstract: As-synthesized single-walled carbon nanotubes (SWNTs) are mixtures of semiconducting and metallic species and separation of the two is of crucial importance for many applications. In this article, the methods employed for the enrichment of semiconducting ...

    Abstract As-synthesized single-walled carbon nanotubes (SWNTs) are mixtures of semiconducting and metallic species and separation of the two is of crucial importance for many applications. In this article, the methods employed for the enrichment of semiconducting and metallic SWNTs are presented, along with possible procedures to prepare either of the species selectively. Equally important are the methods for chirality selection. The discovery of metal-semiconductor transitions in SWNTs induced by interaction with electron donor and acceptor molecules is not only of academic interest, but may also find applications. Synthesis of Y-junction SWNTs with unique electronic properties at the junction is yet to be fully accomplished.
    Language English
    Publishing date 2009-10
    Publishing country England
    Document type Journal Article
    ZDB-ID 2515664-0
    ISSN 2040-3372 ; 2040-3364
    ISSN (online) 2040-3372
    ISSN 2040-3364
    DOI 10.1039/b9nr00104b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Synthesis, characterization, and properties of few-layer MoO3.

    Sreedhara, M B / Matte, H S S Ramakrishna / Govindaraj, A / Rao, C N R

    Chemistry, an Asian journal

    2013  Volume 8, Issue 10, Page(s) 2430–2435

    Abstract: Nanosheets of MoO3 that consist of only a few layers have been prepared by using four methods, including the oxidation of MoS2 nanosheets, intercalation with LiBr, and ultrasonication. These nanosheets have been characterized by atomic force microscopy ... ...

    Abstract Nanosheets of MoO3 that consist of only a few layers have been prepared by using four methods, including the oxidation of MoS2 nanosheets, intercalation with LiBr, and ultrasonication. These nanosheets have been characterized by atomic force microscopy and other techniques. Besides showing a blue-shift of the optical absorption band compared to the bulk sample, few-layer MoO3 exhibits enhanced photocatalytic activity. In combination with a borocarbonitride, few-layer MoO3 shows good performance characteristics as a supercapacitor electrode.
    Language English
    Publishing date 2013-10
    Publishing country Germany
    Document type Journal Article
    ISSN 1861-471X
    ISSN (online) 1861-471X
    DOI 10.1002/asia.201300470
    Database MEDical Literature Analysis and Retrieval System OnLINE

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