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  1. AU="Grey, Clare P."
  2. AU="Zhu, Zhengbin"
  3. AU="Michele Simeone"
  4. AU="Reynolds, Kimberly A"
  5. AU=Hua Cheng-Ge AU=Hua Cheng-Ge
  6. AU="Sorli, Luisa"
  7. AU=Ahmad Shah Adil Ishtiyaq
  8. AU="Bock, Thomas"
  9. AU=Chang Hyejung
  10. AU="Messer, Alison"
  11. AU="Samarzija, Miroslav"
  12. AU="Oh, Yun-Hee"
  13. AU="Ramos, Jairo"
  14. AU="Chauhan Kushwah, Vinita"
  15. AU="Winter, Katrin"
  16. AU="Berro, Julien"
  17. AU=Cummins Claire B.
  18. AU="Damholt, A"
  19. AU="Muthu, Santhosh Kumar"
  20. AU="Tysinger, Emma"
  21. AU=Covarrubias David
  22. AU="Dino Papeš"
  23. AU="Assis, Daniel Barbosa"
  24. AU="Lauquin, Guy J-M"

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  1. Artikel: Solution NMR of Battery Electrolytes: Assessing and Mitigating Spectral Broadening Caused by Transition Metal Dissolution.

    Allen, Jennifer P / Grey, Clare P

    The journal of physical chemistry. C, Nanomaterials and interfaces

    2023  Band 127, Heft 9, Seite(n) 4425–4438

    Abstract: NMR spectroscopy is a powerful tool that is commonly used to assess the degradation of lithium-ion battery electrolyte solutions. However, dissolution of paramagnetic ... ...

    Abstract NMR spectroscopy is a powerful tool that is commonly used to assess the degradation of lithium-ion battery electrolyte solutions. However, dissolution of paramagnetic Ni
    Sprache Englisch
    Erscheinungsdatum 2023-02-28
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ISSN 1932-7447
    ISSN 1932-7447
    DOI 10.1021/acs.jpcc.2c08274
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  2. Artikel ; Online: Determining the oxidation states of dissolved transition metals in battery electrolytes from solution NMR spectra.

    Allen, Jennifer P / Grey, Clare P

    Chemical communications (Cambridge, England)

    2023  Band 59, Heft 12, Seite(n) 1677–1680

    Abstract: Dissolved transition metal ions can induce peak shifts in the NMR spectra of degraded battery electrolytes. Here, we exploit this staightforward, accessible method to calculate magnetic moments for dissolved ... ...

    Abstract Dissolved transition metal ions can induce peak shifts in the NMR spectra of degraded battery electrolytes. Here, we exploit this staightforward, accessible method to calculate magnetic moments for dissolved Ni
    Sprache Englisch
    Erscheinungsdatum 2023-02-07
    Erscheinungsland England
    Dokumenttyp Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc06655f
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  3. Artikel ; Online: John B. Goodenough (1922-2023).

    Grey, Clare P / Lewis, Laura H

    Science (New York, N.Y.)

    2023  Band 381, Heft 6660, Seite(n) 836

    Abstract: A giant in the fields of solid-state chemistry and physics. ...

    Abstract A giant in the fields of solid-state chemistry and physics.
    Sprache Englisch
    Erscheinungsdatum 2023-08-24
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ZDB-ID 128410-1
    ISSN 1095-9203 ; 0036-8075
    ISSN (online) 1095-9203
    ISSN 0036-8075
    DOI 10.1126/science.adj9263
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  4. Artikel ; Online: Engineering considerations for practical lithium-air electrolytes.

    Ellison, James H J / Grey, Clare P

    Faraday discussions

    2024  Band 248, Seite(n) 355–380

    Abstract: Lithium-air batteries promise exceptional energy density while avoiding the use of transition metals in their cathodes, however, their practical adoption is currently held back by their short lifetimes. These short lifetimes are largely caused by ... ...

    Abstract Lithium-air batteries promise exceptional energy density while avoiding the use of transition metals in their cathodes, however, their practical adoption is currently held back by their short lifetimes. These short lifetimes are largely caused by electrolyte breakdown, but despite extensive searching, an electrolyte resistant to breakdown has yet to be found. This paper considers the requirements placed on an electrolyte for it to be considered usable in a practical cell. We go on to examine ways, through judicious cell design, of relaxing these requirements to allow for a broader range of compounds to be considered. We conclude by suggesting types of molecules that could be explored for future cells. With this work, we aim to broaden the scope of future searches for electrolytes and inform new cell design.
    Sprache Englisch
    Erscheinungsdatum 2024-01-29
    Erscheinungsland England
    Dokumenttyp Journal Article
    ISSN 1364-5498
    ISSN (online) 1364-5498
    DOI 10.1039/d3fd00091e
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  5. Artikel ; Online: Solvent-dependent iodide interactions in LiO

    Jónsson, Erlendur / Berge, Astrid H / Grey, Clare P / Temprano, Israel

    Faraday discussions

    2024  Band 248, Seite(n) 145–159

    Abstract: Iodide-based redox mediation in Li- ... ...

    Abstract Iodide-based redox mediation in Li-O
    Sprache Englisch
    Erscheinungsdatum 2024-01-29
    Erscheinungsland England
    Dokumenttyp Journal Article
    ISSN 1364-5498
    ISSN (online) 1364-5498
    DOI 10.1039/d3fd00090g
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  6. Artikel: NMR Methodology for Measuring Dissolved O

    Wang, Evelyna / Jónsson, Erlendur / Grey, Clare P

    The journal of physical chemistry. C, Nanomaterials and interfaces

    2023  Band 127, Heft 21, Seite(n) 10001–10011

    Abstract: Similar to fuel cells, poor mass transport of redox active species, such as dissolved oxygen gas, is one of the challenges faced by lithium-air batteries (LABs). Capitalizing on the paramagnetic properties of ... ...

    Abstract Similar to fuel cells, poor mass transport of redox active species, such as dissolved oxygen gas, is one of the challenges faced by lithium-air batteries (LABs). Capitalizing on the paramagnetic properties of O
    Sprache Englisch
    Erscheinungsdatum 2023-05-22
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ISSN 1932-7447
    ISSN 1932-7447
    DOI 10.1021/acs.jpcc.3c00991
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  7. Artikel ; Online: Spiers Memorial Lecture: Lithium air batteries - tracking function and failure.

    Fritzke, Jana B / Ellison, James H J / Brazel, Laurence / Horwitz, Gabriela / Menkin, Svetlana / Grey, Clare P

    Faraday discussions

    2024  Band 248, Seite(n) 9–28

    Abstract: The lithium-air battery (LAB) is arguably the battery with the highest energy density, but also a battery with significant challenges to be overcome before it can be used commercially in practical devices. Here, we discuss experimental approaches ... ...

    Abstract The lithium-air battery (LAB) is arguably the battery with the highest energy density, but also a battery with significant challenges to be overcome before it can be used commercially in practical devices. Here, we discuss experimental approaches developed by some of the authors to understand the function and failure of lithium-oxygen batteries. For example, experiments in which nuclear magnetic resonance (NMR) spectroscopy was used to quantify dissolved oxygen concentrations and diffusivity are described.
    Sprache Englisch
    Erscheinungsdatum 2024-01-29
    Erscheinungsland England
    Dokumenttyp Journal Article
    ISSN 1364-5498
    ISSN (online) 1364-5498
    DOI 10.1039/d3fd00154g
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  8. Artikel ; Online: The Interplay of Solvation and Polarization Effects on Ion Pairing in Nanoconfined Electrolytes.

    Fong, Kara D / Sumić, Barbara / O'Neill, Niamh / Schran, Christoph / Grey, Clare P / Michaelides, Angelos

    Nano letters

    2024  

    Abstract: The nature of ion-ion interactions in electrolytes confined to nanoscale pores has important implications for energy storage and separation technologies. However, the physical effects dictating the structure of nanoconfined electrolytes remain debated. ... ...

    Abstract The nature of ion-ion interactions in electrolytes confined to nanoscale pores has important implications for energy storage and separation technologies. However, the physical effects dictating the structure of nanoconfined electrolytes remain debated. Here we employ machine-learning-based molecular dynamics simulations to investigate ion-ion interactions with density functional theory level accuracy in a prototypical confined electrolyte, aqueous NaCl within graphene slit pores. We find that the free energy of ion pairing in highly confined electrolytes deviates substantially from that in bulk solutions, observing a decrease in contact ion pairing but an increase in solvent-separated ion pairing. These changes arise from an interplay of ion solvation effects and graphene's electronic structure. Notably, the behavior observed from our first-principles-level simulations is not reproduced even qualitatively with the classical force fields conventionally used to model these systems. The insight provided in this work opens new avenues for predicting and controlling the structure of nanoconfined electrolytes.
    Sprache Englisch
    Erscheinungsdatum 2024-04-09
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ISSN 1530-6992
    ISSN (online) 1530-6992
    DOI 10.1021/acs.nanolett.4c00890
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  9. Artikel: Clarifying the Dopant Local Structure and Effect on Ionic Conductivity in Garnet Solid-State Electrolytes for Lithium-Ion Batteries.

    Vema, Sundeep / Berge, Astrid H / Nagendran, Supreeth / Grey, Clare P

    Chemistry of materials : a publication of the American Chemical Society

    2023  Band 35, Heft 22, Seite(n) 9632–9646

    Abstract: The high Li-ion conductivity and wide electrochemical stability of Li-rich garnets ( ... ...

    Abstract The high Li-ion conductivity and wide electrochemical stability of Li-rich garnets (Li
    Sprache Englisch
    Erscheinungsdatum 2023-11-14
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ZDB-ID 1500399-1
    ISSN 1520-5002 ; 0897-4756
    ISSN (online) 1520-5002
    ISSN 0897-4756
    DOI 10.1021/acs.chemmater.3c01831
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  10. Artikel: Quantifying Dissolved Transition Metals in Battery Electrolyte Solutions with NMR Paramagnetic Relaxation Enhancement.

    Allen, Jennifer P / O'Keefe, Christopher A / Grey, Clare P

    The journal of physical chemistry. C, Nanomaterials and interfaces

    2023  Band 127, Heft 20, Seite(n) 9509–9521

    Abstract: Transition metal dissolution is an important contributor to capacity fade in lithium-ion cells. NMR relaxation rates are proportional to the concentration of paramagnetic species, making them suitable to quantify dissolved transition metals in battery ... ...

    Abstract Transition metal dissolution is an important contributor to capacity fade in lithium-ion cells. NMR relaxation rates are proportional to the concentration of paramagnetic species, making them suitable to quantify dissolved transition metals in battery electrolytes. In this work,
    Sprache Englisch
    Erscheinungsdatum 2023-05-16
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ISSN 1932-7447
    ISSN 1932-7447
    DOI 10.1021/acs.jpcc.3c01396
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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