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  1. Article ; Online: Simultaneous Mapping of Thermal Conductivity, Thermal Diffusivity, and Volumetric Heat Capacity of Halide Perovskite Thin Films: A Novel Nanoscopic Thermal Measurement Technique.

    Haeger, Tobias / Wilmes, Maximilian / Heiderhoff, Ralf / Riedl, Thomas

    The journal of physical chemistry letters

    2019  Volume 10, Issue 11, Page(s) 3019–3023

    Abstract: Local thermal conductivity, thermal diffusivity, and volumetric heat capacity of all-inorganic halide perovskite thin films are mapped simultaneously and with highest spatial resolution for the first time. These various thermal properties are detected by ...

    Abstract Local thermal conductivity, thermal diffusivity, and volumetric heat capacity of all-inorganic halide perovskite thin films are mapped simultaneously and with highest spatial resolution for the first time. These various thermal properties are detected by a scanning near-field thermal microscope operated at two different frequencies simultaneously. We apply this technique to analyze the thermal properties of halide perovskites on the nanoscale. In addition to an ultralow thermal conductivity of 0.43 ± 0.03 and 0.33 ± 0.02 W/(m·K), a low thermal diffusivity of 0.3 ± 0.1 mm
    Language English
    Publishing date 2019-05-22
    Publishing country United States
    Document type Journal Article
    ISSN 1948-7185
    ISSN (online) 1948-7185
    DOI 10.1021/acs.jpclett.9b01053
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Bifacial Color-Tunable Electroluminescent Devices

    Gahlmann, Tobias / Tschorn, Tobias / Maschwitz, Timo / Gomell, Leonie / Haeger, Tobias / Grötsch, Georg / Heiderhoff, Ralf / Riedl, Thomas

    ACS applied materials & interfaces. 2021 June 11, v. 13, no. 24

    2021  

    Abstract: Alternate current electroluminescent (ACEL) devices provide a range of interesting properties, such as facile large-area processability, mechanical flexibility, and outstanding resilience, when compared with other large-area light-emitting technologies. ... ...

    Abstract Alternate current electroluminescent (ACEL) devices provide a range of interesting properties, such as facile large-area processability, mechanical flexibility, and outstanding resilience, when compared with other large-area light-emitting technologies. To widen the scope of possible applications for ACEL devices, color tunability and white light emission are desirable. Here, we introduce a novel three-terminal device architecture based on two monolithically stacked ACEL devices (e.g., orange and blue) that allows for color tunability via independent operation of the subdevices. The tandem devices comprise semitransparent bottom and top electrodes based on networks of silver nanowires, which endow the tandem ACEL device with bifacial Janus-type emission. We provide a detailed analysis of the sources of optical losses in single and tandem ACEL devices. Our novel device concept enables novel facets of applications for ACEL in signage and lighting.
    Keywords color ; nanowires ; silver ; white light
    Language English
    Dates of publication 2021-0611
    Size p. 28514-28520.
    Publishing place American Chemical Society
    Document type Article
    ISSN 1944-8252
    DOI 10.1021/acsami.1c08360
    Database NAL-Catalogue (AGRICOLA)

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  3. Article ; Online: Imaging the Terahertz Nanoscale Conductivity of Polycrystalline CsPbBr

    Schäffer, Stephan / Ogolla, Charles Otieno / Loth, Yannik / Haeger, Tobias / Kreusel, Cedric / Runkel, Manuel / Riedl, Thomas / Butz, Benjamin / Wigger, Anna Katharina / Bolívar, Peter Haring

    Nano letters

    2023  Volume 23, Issue 6, Page(s) 2074–2080

    Abstract: Terahertz (THz) radiation is a valuable tool to investigate the electronic properties of lead halide perovskites (LHPs). However, attaining high-resolution information remains elusive, as the diffraction-limited spatial resolution (∼300 μm) of ... ...

    Abstract Terahertz (THz) radiation is a valuable tool to investigate the electronic properties of lead halide perovskites (LHPs). However, attaining high-resolution information remains elusive, as the diffraction-limited spatial resolution (∼300 μm) of conventional THz methods prevents a direct analysis of microscopic effects. Here, we employ THz scattering scanning near-field optical microscopy (THz-sSNOM) for nanoscale imaging of cesium lead bromide (CsPbBr
    Language English
    Publishing date 2023-03-02
    Publishing country United States
    Document type Journal Article
    ISSN 1530-6992
    ISSN (online) 1530-6992
    DOI 10.1021/acs.nanolett.2c03214
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Bifacial Color-Tunable Electroluminescent Devices.

    Gahlmann, Tobias / Tschorn, Tobias / Maschwitz, Timo / Gomell, Leonie / Haeger, Tobias / Grötsch, Georg / Heiderhoff, Ralf / Riedl, Thomas

    ACS applied materials & interfaces

    2021  Volume 13, Issue 24, Page(s) 28514–28520

    Abstract: Alternate current electroluminescent (ACEL) devices provide a range of interesting properties, such as facile large-area processability, mechanical flexibility, and outstanding resilience, when compared with other large-area light-emitting technologies. ... ...

    Abstract Alternate current electroluminescent (ACEL) devices provide a range of interesting properties, such as facile large-area processability, mechanical flexibility, and outstanding resilience, when compared with other large-area light-emitting technologies. To widen the scope of possible applications for ACEL devices, color tunability and white light emission are desirable. Here, we introduce a novel three-terminal device architecture based on two monolithically stacked ACEL devices (e.g., orange and blue) that allows for color tunability via independent operation of the subdevices. The tandem devices comprise semitransparent bottom and top electrodes based on networks of silver nanowires, which endow the tandem ACEL device with bifacial Janus-type emission. We provide a detailed analysis of the sources of optical losses in single and tandem ACEL devices. Our novel device concept enables novel facets of applications for ACEL in signage and lighting.
    Language English
    Publishing date 2021-06-10
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.1c08360
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Nonlinear refraction in CH

    Kriso, Christian / Stein, Markus / Haeger, Tobias / Pourdavoud, Neda / Gerhard, Marina / Rahimi-Iman, Arash / Riedl, Thomas / Koch, Martin

    Optics letters

    2020  Volume 45, Issue 8, Page(s) 2431–2434

    Abstract: We measure both nonlinear absorption and nonlinear refraction in a ${{\rm CH}_3}{{\rm NH}_3}{{\rm PbBr}_3}$ ... ...

    Abstract We measure both nonlinear absorption and nonlinear refraction in a ${{\rm CH}_3}{{\rm NH}_3}{{\rm PbBr}_3}$CH
    Language English
    Publishing date 2020-04-14
    Publishing country United States
    Document type Journal Article
    ISSN 1539-4794
    ISSN (online) 1539-4794
    DOI 10.1364/OL.383917
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Physical Origin of Negative Differential Resistance in V

    Das, Sujan Kumar / Nandi, Sanjoy Kumar / Marquez, Camilo Verbel / Rúa, Armando / Uenuma, Mutsunori / Puyoo, Etienne / Nath, Shimul Kanti / Albertini, David / Baboux, Nicolas / Lu, Teng / Liu, Yun / Haeger, Tobias / Heiderhoff, Ralf / Riedl, Thomas / Ratcliff, Thomas / Elliman, Robert Glen

    Advanced materials (Deerfield Beach, Fla.)

    2022  Volume 35, Issue 8, Page(s) e2208477

    Abstract: Oxides that exhibit an insulator-metal transition can be used to fabricate energy-efficient relaxation oscillators for use in hardware-based neural networks but there are very few oxides with transition temperatures above room temperature. Here the ... ...

    Abstract Oxides that exhibit an insulator-metal transition can be used to fabricate energy-efficient relaxation oscillators for use in hardware-based neural networks but there are very few oxides with transition temperatures above room temperature. Here the structural, electrical, and thermal properties of V
    Language English
    Publishing date 2022-12-30
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1474949-X
    ISSN 1521-4095 ; 0935-9648
    ISSN (online) 1521-4095
    ISSN 0935-9648
    DOI 10.1002/adma.202208477
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Book ; Online: Microstructure manipulation by laser-surface remelting of a full-Heusler compound to enhance thermoelectric properties

    Gomell, Leonie / Haeger, Tobias / Roscher, Moritz / Bishara, Hanna / Heiderhoff, Ralf / Riedl, Thomas / Scheu, Christina / Gault, Baptiste

    2021  

    Abstract: There is an increasing reckoning that the thermoelectric performance of a material is dependent on its microstructure. However, the microstructure-properties relationship often remains elusive, in part due to the complexity of the hierarchy and scales of ...

    Abstract There is an increasing reckoning that the thermoelectric performance of a material is dependent on its microstructure. However, the microstructure-properties relationship often remains elusive, in part due to the complexity of the hierarchy and scales of features that influence transport properties. Here, we focus on the promising Heusler-Fe2VAl compound. We directly correlate microstructure and local properties, using advanced scanning electron microscopy methods including in-situ four-point-probe technique for electron transport measurements. The local thermal conductivity is investigated by scanning thermal microscopy. Finally, atom probe tomography provides near-atomic scale compositional analysis. To locally manipulate the microstructure, we use laser surface remelting. The rapid quenching creates a complex microstructure with a high density of dislocations and small, elongated grains. We hence showcase that laser surface remelting can be employed to manipulate the microstructure to reduce the thermal conductivity and electrical resistivity, leading to a demonstrated enhancement of the thermoelectric performance at room temperature.
    Keywords Condensed Matter - Materials Science ; Physics - Applied Physics
    Subject code 669 ; 530
    Publishing date 2021-07-15
    Publishing country us
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  8. Article ; Online: A carbene stabilized precursor for the spatial atomic layer deposition of copper thin films.

    Boysen, Nils / Misimi, Bujamin / Muriqi, Arbresha / Wree, Jan-Lucas / Hasselmann, Tim / Rogalla, Detlef / Haeger, Tobias / Theirich, Detlef / Nolan, Michael / Riedl, Thomas / Devi, Anjana

    Chemical communications (Cambridge, England)

    2020  Volume 56, Issue 89, Page(s) 13752–13755

    Abstract: This paper demonstrates a carbene stabilized precursor [Cu( ...

    Abstract This paper demonstrates a carbene stabilized precursor [Cu(
    Language English
    Publishing date 2020-10-16
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d0cc05781a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Book ; Online: Nonlinear refraction in CH$_3$NH$_3$PbBr$_3$ single crystals

    Kriso, Christian / Stein, Markus / Haeger, Tobias / Pourdavoud, Neda / Gerhard, Marina / Rahimi-Iman, Arash / Riedl, Thomas / Koch, Martin

    2019  

    Abstract: Hybrid lead halide perovskites, such as CH$_3$NH$_3$PbX$_3$ (X=I, Br), are direct gap semiconductors that offer many superior optoelectronic properties combined with extremely simple solution-processing fabrication methods. This makes them very ... ...

    Abstract Hybrid lead halide perovskites, such as CH$_3$NH$_3$PbX$_3$ (X=I, Br), are direct gap semiconductors that offer many superior optoelectronic properties combined with extremely simple solution-processing fabrication methods. This makes them very attractive for use in applications like solar cells or light-emitting devices. Recently, also their nonlinear optical properties have received increased attention due to reports of high nonlinear refraction in thin films and nanoparticles. However, understanding of the underlying mechanisms is poor and limited by the lack of knowledge of fundamental parameters like the nonlinear refractive index of the bulk material. Here, we measure both nonlinear absorption and nonlinear refraction in a CH$_3$NH$_3$PbBr$_3$ single crystal using the Z-scan technique with femtosecond laser pulses. At 1000 nm, we obtain values of 5.2 cm/GW and 9.5$\cdot$10$^{-14}$ cm$^2$/W for nonlinear absorption and nonlinear refraction, respectively. Sign and magnitude of the observed refractive nonlinearity are reproduced well by the two-band model. To our knowledge, these measurements mark the first characterization of nonlinear refraction in any metal halide perovskite single crystal and thus will serve as an important reference for assessing the potential of this emerging material class for nonlinear optical applications.
    Keywords Physics - Optics ; Condensed Matter - Materials Science
    Subject code 535
    Publishing date 2019-10-28
    Publishing country us
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  10. Article ; Online: Anhydrous Amorphous Calcium Oxalate Nanoparticles from Ionic Liquids: Stable Crystallization Intermediates in the Formation of Whewellite.

    Gehl, Aaron / Dietzsch, Michael / Mondeshki, Mihail / Bach, Sven / Häger, Tobias / Panthöfer, Martin / Barton, Bastian / Kolb, Ute / Tremel, Wolfgang

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2015  Volume 21, Issue 50, Page(s) 18192–18201

    Abstract: The mechanisms by which amorphous intermediates transform into crystalline materials are not well understood. To test the viability and the limits of the classical crystallization, new model systems for crystallization are needed. With a view to ... ...

    Abstract The mechanisms by which amorphous intermediates transform into crystalline materials are not well understood. To test the viability and the limits of the classical crystallization, new model systems for crystallization are needed. With a view to elucidating the formation of an amorphous precursor and its subsequent crystallization, the crystallization of calcium oxalate, a biomineral widely occurring in plants, is investigated. Amorphous calcium oxalate (ACO) precipitated from an aqueous solution is described as a hydrated metastable phase, as often observed during low-temperature inorganic synthesis and biomineralization. In the presence of water, ACO rapidly transforms into hydrated whewellite (monohydrate, CaC2 O4 ⋅H2 O, COM). The problem of fast crystallization kinetics is circumvented by synthesizing anhydrous ACO from a pure ionic liquid (IL-ACO) for the first time. IL-ACO is stable in the absence of water at ambient temperature. It is obtained as well-defined, non-agglomerated particles with diameters of 15-20 nm. When exposed to water, it crystallizes to give (hydrated) COM through a dissolution/recrystallization mechanism.
    Language English
    Publishing date 2015-12-07
    Publishing country Germany
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 1478547-x
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.201502229
    Database MEDical Literature Analysis and Retrieval System OnLINE

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