Article: Mercuric triflate-catalyzed reaction of propargyl acetates with water leading vinyl ketones.
Organic letters
2006 Volume 8, Issue 3, Page(s) 447–450
Abstract: reaction: see text]. Reaction of propargyl acetate with water catalyzed by Hg(OTf)2 afforded vinyl ketone as the major product along with a dimeric vinyl mercuric product and normal hydration products in small amounts. The reaction is an alternative to ... ...
Abstract | [reaction: see text]. Reaction of propargyl acetate with water catalyzed by Hg(OTf)2 afforded vinyl ketone as the major product along with a dimeric vinyl mercuric product and normal hydration products in small amounts. The reaction is an alternative to the Meyer-Schuster and Rupe rearrangement applicable to primary alcohols, although the mechanism is entirely different. |
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Language | English |
Publishing date | 2006-02-02 |
Publishing country | United States |
Document type | Journal Article |
ISSN | 1523-7060 |
ISSN | 1523-7060 |
DOI | 10.1021/ol0527431 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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