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  1. Article ; Online: Redox-active carborane clusters in bond activation chemistry and ligand design.

    Nussbaum, Bryce C / Humphries, Amanda L / Gange, Gayathri B / Peryshkov, Dmitry V

    Chemical communications (Cambridge, England)

    2023  Volume 59, Issue 66, Page(s) 9918–9928

    Abstract: ... ...

    Abstract Icosahedral
    Language English
    Publishing date 2023-08-15
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d3cc03011c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Activation of Alkynes by a Redox-Active Carboranyl Diphosphine and Formation of Boron-Containing Phosphacycles.

    Gange, Gayathri B / Humphries, Amanda L / Smith, Mark D / Peryshkov, Dmitry V

    Inorganic chemistry

    2022  Volume 61, Issue 46, Page(s) 18568–18573

    Abstract: In this work, we report the reactivity of the carboranyl diphosphine, 1- ... ...

    Abstract In this work, we report the reactivity of the carboranyl diphosphine, 1-P
    Language English
    Publishing date 2022-11-09
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.2c02919
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Paramedic-Performed Carotid Artery Ultrasound Heralds Return of Spontaneous Circulation in Out-of-Hospital Cardiac Arrest: A Case Report.

    Humphries, Amanda L / White, Jenna M B / Guinn, R Elliott / Braude, Darren A

    Prehospital emergency care

    2022  Volume 27, Issue 1, Page(s) 107–111

    Abstract: Point-of-Care Ultrasound (POCUS) has been demonstrated to have multiple applications in the care of critically ill and injured patients, especially given its portability and ease of use. These characteristics of POCUS make it ideal for use in the ... ...

    Abstract Point-of-Care Ultrasound (POCUS) has been demonstrated to have multiple applications in the care of critically ill and injured patients, especially given its portability and ease of use. These characteristics of POCUS make it ideal for use in the prehospital environment as well. We present a case that highlights a novel application of ultrasound in the prehospital management of out-of-hospital cardiac arrest (OHCA).
    MeSH term(s) Humans ; Emergency Medical Services ; Paramedics ; Out-of-Hospital Cardiac Arrest/diagnostic imaging ; Out-of-Hospital Cardiac Arrest/therapy ; Return of Spontaneous Circulation ; Cardiopulmonary Resuscitation ; Carotid Arteries
    Language English
    Publishing date 2022-02-03
    Publishing country England
    Document type Case Reports ; Journal Article
    ZDB-ID 1461751-1
    ISSN 1545-0066 ; 1090-3127
    ISSN (online) 1545-0066
    ISSN 1090-3127
    DOI 10.1080/10903127.2021.2022257
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Metal-Free Bond Activation by Carboranyl Diphosphines

    Gange, Gayathri B. / Humphries, Amanda L. / Royzman, Dmitry E. / Smith, Mark D. / Peryshkov, Dmitry V.

    Journal of the American Chemical Society. 2021 July 13, v. 143, no. 29

    2021  

    Abstract: We report metal-free bond activation by the carboranyl diphosphine 1-PᵗBu₂-2-PⁱPr₂-C₂B₁₀H₁₀. This main group element system contains basic binding sites and possesses the ability to cycle through two-electron redox states. The reported reactions with ... ...

    Abstract We report metal-free bond activation by the carboranyl diphosphine 1-PᵗBu₂-2-PⁱPr₂-C₂B₁₀H₁₀. This main group element system contains basic binding sites and possesses the ability to cycle through two-electron redox states. The reported reactions with selected main group hydrides and alcohols occur via the formal oxidation of the phosphine groups and concomitant reduction of the boron cage. These transformations, which are driven by the cooperation between the electron-donating exohedral substituents and the electron-accepting cluster, differ from those of “regular” phosphines and are reminiscent of oxidative addition to transition metal centers, thus representing a new approach to metal-free bond activation.
    Keywords boron ; cages ; oxidation ; phosphine
    Language English
    Dates of publication 2021-0713
    Size p. 10842-10846.
    Publishing place American Chemical Society
    Document type Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.1c05387
    Database NAL-Catalogue (AGRICOLA)

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