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  1. Article ; Online: Design of a Mesoionic Janus-type Dicarbene.

    Leung, Jia Nuo / Huynh, Han Vinh

    Journal of the American Chemical Society

    2024  Volume 146, Issue 6, Page(s) 3622–3626

    Abstract: A versatile synthetic strategy for the preparation of homo- and heterobimetallic complexes bearing an unprecedented mesoionic Janus-type diNHC is presented. Moreover, its electronic property is evaluated, and a preliminary catalytic application in the ... ...

    Abstract A versatile synthetic strategy for the preparation of homo- and heterobimetallic complexes bearing an unprecedented mesoionic Janus-type diNHC is presented. Moreover, its electronic property is evaluated, and a preliminary catalytic application in the direct diarylation of 1-methylpyrrole is demonstrated.
    Language English
    Publishing date 2024-02-02
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.3c13284
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Stereoelectronic Profiling of Neutral and Monoanionic Biimidazoles and Mixed Diimines.

    Leung, Jia Nuo / Luong, Huyen T T / Huynh, Han Vinh

    Inorganic chemistry

    2023  Volume 62, Issue 11, Page(s) 4606–4617

    Abstract: 14 mono-, di-, and tetranuclear palladium complexes were prepared to study the coordination chemistry of symmetrical and unsymmetrical azole-derived diimines and their anions. The diverse range of complexes obtained highlights the structural and ... ...

    Abstract 14 mono-, di-, and tetranuclear palladium complexes were prepared to study the coordination chemistry of symmetrical and unsymmetrical azole-derived diimines and their anions. The diverse range of complexes obtained highlights the structural and electronic diversities imposed by these ligands. Using the monopalladium species, the electronic properties of selected bidentate ligands were determined, ranked, and compared by
    Language English
    Publishing date 2023-03-06
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.3c00017
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Diverse Post-Metathesis Reactivities of Mixed Amido-Isothiocyanato Molybdenum Complexes.

    Do, Dinh Cao Huan / Đorđević, Nemanja / Huynh, Han Vinh

    Inorganic chemistry

    2023  Volume 62, Issue 45, Page(s) 18583–18590

    Abstract: Attempts to prepare mixed isothiocyanato-bis(imido) ... ...

    Abstract Attempts to prepare mixed isothiocyanato-bis(imido) Mo
    Language English
    Publishing date 2023-11-03
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.3c02885
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Donor Strength Determination of Anionic Ligands.

    Huynh, Han Vinh / Leung, Jia Nuo / Lam, Truc Tien

    Inorganic chemistry

    2023  Volume 62, Issue 34, Page(s) 13902–13909

    Abstract: 14 new gold(I) NHC complexes of the type [AuX( ...

    Abstract 14 new gold(I) NHC complexes of the type [AuX(
    Language English
    Publishing date 2023-08-12
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.3c01811
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination.

    Huynh, Han Vinh

    Chemical reviews

    2018  Volume 118, Issue 19, Page(s) 9457–9492

    Abstract: N-Heterocyclic carbenes (NHCs) have become without doubt one of the most exciting and popular species in chemical science due to the ease of their preparation and modularity in stereoelectronic properties. Numerous types of NHCs have been prepared, and ... ...

    Abstract N-Heterocyclic carbenes (NHCs) have become without doubt one of the most exciting and popular species in chemical science due to the ease of their preparation and modularity in stereoelectronic properties. Numerous types of NHCs have been prepared, and various experimental methodologies have been proposed for the study of their electronic properties in order to rationalize reactivities observed. The objective of this article is to provide a comprehensive overview of the most common and popular ones among them. In particular, these include the nickel(0)-based TEP, its rhodium(I) and iridium(I) variants, LEP and related electrochemical methods, the palladium(II)-based HEP, phosphinidene- and selenourea-based methods, as well as the use of direct
    Language English
    Publishing date 2018-03-30
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 207949-5
    ISSN 1520-6890 ; 0009-2665
    ISSN (online) 1520-6890
    ISSN 0009-2665
    DOI 10.1021/acs.chemrev.8b00067
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Bonn / Germany

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  6. Article ; Online: Electronic Profiling of

    Leung, Jia Nuo / Mondori, Yutaka / Ogoshi, Sensuke / Hoshimoto, Yoichi / Huynh, Han Vinh

    Inorganic chemistry

    2024  Volume 63, Issue 9, Page(s) 4344–4354

    Abstract: A detailed electronic study of ... ...

    Abstract A detailed electronic study of the
    Language English
    Publishing date 2024-02-22
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.3c04600
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Controlled Access to Four- and Six-Membered Palladacycles

    Do, Dinh Cao Huan / Huynh, Han Vinh

    Inorganic chemistry

    2022  Volume 61, Issue 49, Page(s) 20087–20094

    Abstract: The synthesis of Pd complexes of the type [PdBr( ...

    Abstract The synthesis of Pd complexes of the type [PdBr(
    Language English
    Publishing date 2022-11-23
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.2c03515
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Donor Strength Determination of Pyridinylidene-amide Ligands using Their Palladium-NHC Complexes.

    Huynh, Han Vinh / Vossen, Jeroen Thomas

    Inorganic chemistry

    2020  Volume 59, Issue 17, Page(s) 12486–12493

    Abstract: Pyridinylidene-amides (PYAs) are a relatively new type of N-donor ligands that can exist in three isomeric forms and adopt various resonance structures. This makes them electronically flexible, and in order to evaluate their electronic profile using the ... ...

    Abstract Pyridinylidene-amides (PYAs) are a relatively new type of N-donor ligands that can exist in three isomeric forms and adopt various resonance structures. This makes them electronically flexible, and in order to evaluate their electronic profile using the Huynh electronic parameter (HEP), seven structurally diverse mixed
    Language English
    Publishing date 2020-08-11
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.0c01585
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Mixed NHC-thiolato complexes of palladium: understanding the formation of di-

    Huynh, Han Vinh / Ong, Hong Lee / Ghatak, Kausani

    Dalton transactions (Cambridge, England : 2003)

    2021  Volume 50, Issue 48, Page(s) 18118–18127

    Abstract: The preference for the formation of mono- ...

    Abstract The preference for the formation of mono-
    Language English
    Publishing date 2021-12-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d1dt03714e
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article: Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination

    Huynh, Han Vinh

    Chemical reviews. 2018 Mar. 30, v. 118, no. 19

    2018  

    Abstract: N-Heterocyclic carbenes (NHCs) have become without doubt one of the most exciting and popular species in chemical science due to the ease of their preparation and modularity in stereoelectronic properties. Numerous types of NHCs have been prepared, and ... ...

    Abstract N-Heterocyclic carbenes (NHCs) have become without doubt one of the most exciting and popular species in chemical science due to the ease of their preparation and modularity in stereoelectronic properties. Numerous types of NHCs have been prepared, and various experimental methodologies have been proposed for the study of their electronic properties in order to rationalize reactivities observed. The objective of this article is to provide a comprehensive overview of the most common and popular ones among them. In particular, these include the nickel(0)-based TEP, its rhodium(I) and iridium(I) variants, LEP and related electrochemical methods, the palladium(II)-based HEP, phosphinidene- and selenourea-based methods, as well as the use of direct ¹J(C–H) coupling constants of the precarbene carbon in azolium salts. Each individual method and the underlying principle of detection it utilizes will be critically discussed in terms of strength and weakness. In addition, comprehensive amounts of data from various NHCs are compiled for the purpose of comparison. These are also meant to help the scientist in better understanding their own research data and possibly providing directions for their future research, which rely on the unique electronic properties of NHCs.
    Keywords carbenes ; carbon ; electrochemistry ; heterocyclic nitrogen compounds ; iridium ; nickel ; palladium ; rhodium ; salts
    Language English
    Dates of publication 2018-0330
    Size p. 9457-9492.
    Publishing place American Chemical Society
    Document type Article
    ZDB-ID 207949-5
    ISSN 1520-6890 ; 0009-2665
    ISSN (online) 1520-6890
    ISSN 0009-2665
    DOI 10.1021/acs.chemrev.8b00067
    Database NAL-Catalogue (AGRICOLA)

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