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  1. Article ; Online: The Kinetics of Adsorption and Desorption of Selected Semivolatile Hydrocarbons and H

    Iannarelli, Riccardo / Ludwig, Christian / Rossi, Michel J

    The journal of physical chemistry. A

    2022  Volume 126, Issue 46, Page(s) 8711–8726

    Abstract: A flowing gas experiment using a Knudsen flow reactor was performed on a series of seven semivolatile probe gases interacting with two often used mineral dust materials, namely, coarse Arizona test dust (ATD-C) and kaolinite. The semivolatile probe gases ...

    Abstract A flowing gas experiment using a Knudsen flow reactor was performed on a series of seven semivolatile probe gases interacting with two often used mineral dust materials, namely, coarse Arizona test dust (ATD-C) and kaolinite. The semivolatile probe gases used were applinate (acetate ester), pipol (ethyl ester of 2-methylvaleric acid), benzylacetate (acetate ester of benzylalcohol), menthol (alcohol), toluene, limonene, and γ-terpinene (terpene hydrocarbon). Uptake experiments under molecular flow conditions resulted in absolute coverages and initial uptake coefficients γ
    Language English
    Publishing date 2022-11-09
    Publishing country United States
    Document type Journal Article
    ISSN 1520-5215
    ISSN (online) 1520-5215
    DOI 10.1021/acs.jpca.2c04903
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Book ; Online: Multidiagnostic Observations on HCI and HNO₃ Hydrate Films in the Temperature Range 170-205 K

    Iannarelli, Riccardo

    A Kinetic Study

    2014  

    Abstract: Diss., Eidgenössische Technische Hochschule ETH Zürich, Nr. 21791, ... ...

    Abstract Diss., Eidgenössische Technische Hochschule ETH Zürich, Nr. 21791, 2014
    Keywords CHEMISCHE ZUSAMMENSETZUNG DER ATMOSPHÄRE (METEOROLOGIE) ; EIGENSCHAFTEN DÜNNER SCHICHTEN (PHYSIK VON MOLEKULARSYSTEMEN) ; VERDUNSTUNG + EVAPOTRANSPIRATION (METEOROLOGIE) ; KONDENSATION UND ABLAGERUNG (METEOROLOGIE) ; SALZSÄURE + CHLORIDE (ANORGANISCHE CHEMIE) ; SALPETERSÄURE UND NITRATE (ANORGANISCHE CHEMIE) ; CHEMISCHE KINETIK
    Language English
    Publisher Zürich, ETH-Zürich
    Publishing country ch
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Thesis ; Online: Multidiagnostic Observations on HCI and HNO₃ Hydrate Films in the Temperature Range 170-205 K

    Iannarelli, Riccardo

    A Kinetic Study

    2014  

    Keywords CHEMISCHE ZUSAMMENSETZUNG DER ATMOSPHÄRE (METEOROLOGIE) ; EIGENSCHAFTEN DÜNNER SCHICHTEN (PHYSIK VON MOLEKULARSYSTEMEN) ; VERDUNSTUNG + EVAPOTRANSPIRATION (METEOROLOGIE) ; KONDENSATION UND ABLAGERUNG (METEOROLOGIE) ; SALZSÄURE + CHLORIDE (ANORGANISCHE CHEMIE) ; SALPETERSÄURE UND NITRATE (ANORGANISCHE CHEMIE) ; CHEMISCHE KINETIK ; CHEMICAL COMPOSITION OF THE ATMOSPHERE (METEOROLOGY) ; PROPERTIES OF THIN LAYERS (PHYSICS OF MOLECULAR SYSTEMS) ; EVAPORATION + EVAPOTRANSPIRATION (METEOROLOGY) ; CONDENSATION AND DEPOSITS (METEOROLOGY) ; HYDROCHLORIC ACID + CHLORIDES (INORGANIC CHEMISTRY) ; NITRIC ACID AND NITRATES (INORGANIC CHEMISTRY) ; CHEMICAL KINETICS ; info:eu-repo/classification/ddc/540 ; info:eu-repo/classification/ddc/550 ; Chemistry ; Earth sciences
    Language English
    Publisher ETH-Zürich
    Publishing country ch
    Document type Thesis ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  4. Article ; Online: Metastable Nitric Acid Trihydrate in Ice Clouds.

    Weiss, Fabian / Kubel, Frank / Gálvez, Óscar / Hoelzel, Markus / Parker, Stewart F / Baloh, Philipp / Iannarelli, Riccardo / Rossi, Michel J / Grothe, Hinrich

    Angewandte Chemie (International ed. in English)

    2016  Volume 55, Issue 10, Page(s) 3276–3280

    Abstract: The composition of high-altitude ice clouds is still a matter of intense discussion. The constituents in question are ice and nitric acid hydrates, but the exact phase composition of clouds and its formation mechanisms are still unknown. In this work, ... ...

    Abstract The composition of high-altitude ice clouds is still a matter of intense discussion. The constituents in question are ice and nitric acid hydrates, but the exact phase composition of clouds and its formation mechanisms are still unknown. In this work, conclusive evidence for a long-predicted phase, alpha-nitric acid trihydrate (alpha-NAT), is presented. This phase was characterized by a combination of X-ray and neutron diffraction experiments, allowing a convincing structure solution. Furthermore, vibrational spectra (infrared and inelastic neutron scattering) were recorded and compared with theoretical calculations. A strong interaction between water ice and alpha-NAT was found, which explains the experimental spectra and the phase-transition kinetics. On the basis of these results, we propose a new three-step mechanism for NAT formation in high-altitude ice clouds.
    Language English
    Publishing date 2016-02-16
    Publishing country Germany
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.201510841
    Database MEDical Literature Analysis and Retrieval System OnLINE

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