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  1. Article ; Online: Visible-Light Enabled C(s

    Yedase, Girish Suresh / Jha, Avishek Kumar / Yatham, Veera Reddy

    The Journal of organic chemistry

    2022  Volume 87, Issue 8, Page(s) 5442–5450

    Abstract: We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and ... ...

    Abstract We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and tolerates a variety of functional groups affording C(s
    MeSH term(s) Bromides ; Catalysis ; Halogens ; Nickel ; Oxidation-Reduction
    Chemical Substances Bromides ; Halogens ; Nickel (7OV03QG267)
    Language English
    Publishing date 2022-03-31
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.2c00251
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Redox-Neutral Radical Cascade Cyclization of

    Jha, Avishek Kumar / Nair, Dhananjay P / Arif, Munaifa / Yedase, Girish Suresh / Kuniyil, Rositha / Yatham, Veera Reddy

    The Journal of organic chemistry

    2023  Volume 88, Issue 21, Page(s) 15389–15394

    Abstract: Herein, we report the first metal-free, redox-neutral strategy for radical cascade alkylative radical addition, cyclization ... ...

    Abstract Herein, we report the first metal-free, redox-neutral strategy for radical cascade alkylative radical addition, cyclization of
    Language English
    Publishing date 2023-10-24
    Publishing country United States
    Document type Journal Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.3c01904
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Visible-Light-Driven α-Aminoalkyl Radical-Mediated C(sp³)–C(sp) Cross-Coupling of Iodoalkanes and Alkynyl Bromides

    Tripathy, Alisha Rani / Kumar, Amit / Rahmathulla A, Rizwana / Jha, Avishek Kumar / Yatham, Veera Reddy

    Organic letters. 2022 July 14, v. 24, no. 28

    2022  

    Abstract: We herein report a simple protocol for metal-free cross-coupling between unactivated alkyl iodides and terminal alkynyl bromides promoted by visible light. The salient features of this transformation are the utilization of an organic photocatalyst and ... ...

    Abstract We herein report a simple protocol for metal-free cross-coupling between unactivated alkyl iodides and terminal alkynyl bromides promoted by visible light. The salient features of this transformation are the utilization of an organic photocatalyst and commercially available tri-n-butylamine as a reductant. This protocol couples a variety of unactivated iodoalkanes containing different functional groups and with a variety of terminal alkynyl bromides under mild reaction conditions to afford the substituted alkynes in good yields.
    Keywords alkynes ; cross-coupling reactions ; light ; photocatalysts ; reducing agents
    Language English
    Dates of publication 2022-0714
    Size p. 5186-5191.
    Publishing place American Chemical Society
    Document type Article
    ISSN 1523-7052
    DOI 10.1021/acs.orglett.2c02018
    Database NAL-Catalogue (AGRICOLA)

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  4. Article: Visible-Light Enabled C(sp³)–C(sp²) Cross-Electrophile Coupling via Synergistic Halogen-Atom Transfer (XAT) and Nickel Catalysis

    Yedase, Girish Suresh / Jha, Avishek Kumar / Yatham, Veera Reddy

    Journal of organic chemistry. 2022 Mar. 31, v. 87, no. 8

    2022  

    Abstract: We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and ... ...

    Abstract We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and tolerates a variety of functional groups affording C(sp³)–C(sp²) cross-coupling products in good to moderate yields.
    Keywords catalytic activity ; cross-coupling reactions ; halogens ; light ; nickel ; organic chemistry
    Language English
    Dates of publication 2022-0331
    Size p. 5442-5450.
    Publishing place American Chemical Society
    Document type Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.2c00251
    Database NAL-Catalogue (AGRICOLA)

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  5. Article ; Online: Visible-Light-Driven α-Aminoalkyl Radical-Mediated C(sp

    Tripathy, Alisha Rani / Kumar, Amit / Rahmathulla A, Rizwana / Jha, Avishek Kumar / Yatham, Veera Reddy

    Organic letters

    2022  Volume 24, Issue 28, Page(s) 5186–5191

    Abstract: We herein report a simple protocol for metal-free cross-coupling between unactivated alkyl iodides and terminal alkynyl bromides promoted by visible light. The salient features of this transformation are the utilization of an organic photocatalyst and ... ...

    Abstract We herein report a simple protocol for metal-free cross-coupling between unactivated alkyl iodides and terminal alkynyl bromides promoted by visible light. The salient features of this transformation are the utilization of an organic photocatalyst and commercially available tri-n-butylamine as a reductant. This protocol couples a variety of unactivated iodoalkanes containing different functional groups and with a variety of terminal alkynyl bromides under mild reaction conditions to afford the substituted alkynes in good yields.
    MeSH term(s) Alkynes ; Bromides ; Catalysis ; Iodides ; Light
    Chemical Substances Alkynes ; Bromides ; Iodides
    Language English
    Publishing date 2022-07-14
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ISSN 1523-7052
    ISSN (online) 1523-7052
    DOI 10.1021/acs.orglett.2c02018
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    Kategorien

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