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  1. Article ; Online: An Overview of Characterisation, Utilisation, and Leachate Analysis of Clinical Waste Incineration Ash.

    Ghazali, Ezliana / Johari, Megat Azmi Megat / Fauzi, Mohd Azrizal / Nor, Noorsuhada Md

    International journal of environmental research

    2022  Volume 16, Issue 5, Page(s) 69

    Abstract: As industrial globalisation and waste output continue to grow, solid waste management is one of the most pressing worldwide environmental challenges. Solid wastes include both the heterogeneous mass of urban throwaways and the homogeneous accumulations ... ...

    Abstract As industrial globalisation and waste output continue to grow, solid waste management is one of the most pressing worldwide environmental challenges. Solid wastes include both the heterogeneous mass of urban throwaways and the homogeneous accumulations of agricultural, industrial, and mineral wastes. Clinical waste (CW) has a significant negative influence on both human health and the environment. To dispose hazardous CW, a proper waste management system should be necessary, and incineration should be the best possible option for reducing the volume of this hazardous waste. Incineration is being developed in Malaysia as a means of disposing clinical and hazardous waste. Currently, 170 common CW treatment facilities with 140 incinerators are accessible around the country. The combustion procedure kills pathogens and reduces waste volume and weight, but it leaves a solid residue known as clinical waste ash (CWA), which raises heavy metal, inorganic salt, and organic compound levels in the environment. Because metals are not eliminated during incineration, dumping CWA in a landfill could contaminate groundwater. Leachate is the liquid created when waste decomposes in a landfill and water filters through it. The most common method of disposing of CW ashes is to transfer them to a landfill. Landfills should install a top cover after closure for hazardous waste landfills. Due to a lack of space and the high expense of land disposal, recycling technologies and the reuse of ash in various systems have developed. Clinical waste incineration fly ash (CWIFA), a solid waste substance from CW incineration, typically includes mobile heavy metals and can cause significant pollution when reused. The standard requirement for removing CWIFA in dumpsites should be below the metal limit stated by the U.S. Environmental Protection Agency (USEPA). Much recent research on the usage of CWIFA has concentrated on mitigating their effects on the environment. Several studies have confirmed the utilisation of CWIFA in the construction field and agriculture to reduce the leaching of its hazardous components into the environment. Compressive strength decreased with the percentage amount of CWIFA due to the substitution of cement with CWIFA. CWIFA mix with 20% cement is the broad-scale application of CWIFA for geotechnical constructions. Heavy metals (Cd, Cu, Ni, Pb, and Zn) are strongly immobilised by the cementitious matrix. Solidification/stabilisation (S/S) materials can be dumped in landfills with less environmental protection than untreated waste. When utilising a CWIFA in mortar, the primary environmental concern is if any harmful materials leach out during the initial curing process or throughout the life of the mortar. Toxicity characteristic of leaching procedure (TCLP) analysis of all CWIFA specimens found amounts of heavy metals below regulatory limits. Solidification of waste with cement and solidified waste has become a popular way of minimising the atmosphere's emissions. The amount of CWIFA generated is expected to increase nationally and globally. There is an immediate need for further evaluation of ash leachate investigations for proper disposal and usage of ash in construction materials.
    Language English
    Publishing date 2022-08-16
    Publishing country Switzerland
    Document type Journal Article ; Review
    ZDB-ID 2399844-1
    ISSN 2008-2304 ; 1735-6865
    ISSN (online) 2008-2304
    ISSN 1735-6865
    DOI 10.1007/s41742-022-00455-0
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: The influence of palm oil fuel ash heat treatment on the strength activity, porosity, and water absorption of cement mortar

    Shaladi, Ramzi J. / Johari, Megat Azmi Megat / Zainal Arifin Ahmad / Mijarsh, Mustafa Juma A.

    Environ Sci Pollut Res. 2022 Oct., v. 29, no. 48 p.72493-72514

    2022  

    Abstract: The current study aims to explore the impact of palm oil fuel ash (POFA) heat treatment on the strength activity, porosity, and water absorption of cement mortar. The cement mortar mixtures were typically comprising cement or cement in combination with ... ...

    Abstract The current study aims to explore the impact of palm oil fuel ash (POFA) heat treatment on the strength activity, porosity, and water absorption of cement mortar. The cement mortar mixtures were typically comprising cement or cement in combination with ultrafine treated POFA (u-TPOFA) which is the final form of the treated POFA, sand, water, and a superplasticizer. Before utilizing the u-TPOFA in mortar mixtures, the treatment processes of POFA were undertaken via five steps (drying at 105 ℃, sieving, grinding, heat treatment, re-grinding) to form u-TPOFA. The heat treatment was performed at three different heating temperatures (i.e., 550 ℃, 600 ℃, and 650 ℃). The ratio on mass/mass basis of the blended ordinary Portland cement (OPC) with u-TPOFA was OPC:u-TPOFA of 70%:30%. A total of four mixtures were prepared, consisting of a plain control mixture (designated as PCM) and three mixtures containing 30% of u-TPOFA treated at three different temperatures designated as M1 “550 ℃,” M2 “600 ℃,” and M3 “650 ℃”. The results show that the optimum mixture was M2 which achieved the highest strength activity index (SAI) of 101.84% and 107% among all mixtures at 7 days and 28 days, respectively. Meanwhile, the porosity (P%) and water absorption (Abs%) of M2 exhibited the lowest values of 9.3% and 4.5%, respectively, among all the mixtures at 28 days. This superior performance of u-TPOFA treated at 600 ℃ represented in the M2 mixture was due to the formation of more binding phases consisting of calcium silicate hydrate (C–S–H) type gel originated from a higher pozzolanic reaction and the filler effects caused by the fine u-TPOFA microparticles. These observations were further confirmed by the improved performance of the M2 mix among all the designed mixes which also exhibited better results in terms of bulk density (BD), ultrasonic pulse velocity (UPV), X-ray diffraction (XRD) as well as thermogravimetry (TGA) and field emission scanning electron microscopy (FESEM-EDX) analyses.
    Keywords X-ray diffraction ; bulk density ; calcium silicate ; cement ; electron microscopy ; fuels ; gels ; heat treatment ; palm oils ; porosity ; sand ; thermogravimetry ; ultrasonics ; water uptake
    Language English
    Dates of publication 2022-10
    Size p. 72493-72514.
    Publishing place Springer Berlin Heidelberg
    Document type Article ; Online
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-022-20710-3
    Database NAL-Catalogue (AGRICOLA)

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  3. Article ; Online: The influence of palm oil fuel ash heat treatment on the strength activity, porosity, and water absorption of cement mortar.

    Shaladi, Ramzi J / Johari, Megat Azmi Megat / Ahmad, Zainal Arifin / Mijarsh, Mustafa Juma A

    Environmental science and pollution research international

    2022  Volume 29, Issue 48, Page(s) 72493–72514

    Abstract: The current study aims to explore the impact of palm oil fuel ash (POFA) heat treatment on the strength activity, porosity, and water absorption of cement mortar. The cement mortar mixtures were typically comprising cement or cement in combination with ... ...

    Abstract The current study aims to explore the impact of palm oil fuel ash (POFA) heat treatment on the strength activity, porosity, and water absorption of cement mortar. The cement mortar mixtures were typically comprising cement or cement in combination with ultrafine treated POFA (u-TPOFA) which is the final form of the treated POFA, sand, water, and a superplasticizer. Before utilizing the u-TPOFA in mortar mixtures, the treatment processes of POFA were undertaken via five steps (drying at 105 ℃, sieving, grinding, heat treatment, re-grinding) to form u-TPOFA. The heat treatment was performed at three different heating temperatures (i.e., 550 ℃, 600 ℃, and 650 ℃). The ratio on mass/mass basis of the blended ordinary Portland cement (OPC) with u-TPOFA was OPC:u-TPOFA of 70%:30%. A total of four mixtures were prepared, consisting of a plain control mixture (designated as PCM) and three mixtures containing 30% of u-TPOFA treated at three different temperatures designated as M1 "550 ℃," M2 "600 ℃," and M3 "650 ℃". The results show that the optimum mixture was M2 which achieved the highest strength activity index (SAI) of 101.84% and 107% among all mixtures at 7 days and 28 days, respectively. Meanwhile, the porosity (P%) and water absorption (Abs%) of M2 exhibited the lowest values of 9.3% and 4.5%, respectively, among all the mixtures at 28 days. This superior performance of u-TPOFA treated at 600 ℃ represented in the M2 mixture was due to the formation of more binding phases consisting of calcium silicate hydrate (C-S-H) type gel originated from a higher pozzolanic reaction and the filler effects caused by the fine u-TPOFA microparticles. These observations were further confirmed by the improved performance of the M2 mix among all the designed mixes which also exhibited better results in terms of bulk density (BD), ultrasonic pulse velocity (UPV), X-ray diffraction (XRD) as well as thermogravimetry (TGA) and field emission scanning electron microscopy (FESEM-EDX) analyses.
    MeSH term(s) Compressive Strength ; Construction Materials/analysis ; Hot Temperature ; Palm Oil ; Porosity ; Water/analysis
    Chemical Substances Water (059QF0KO0R) ; Palm Oil (5QUO05548Z)
    Language English
    Publishing date 2022-05-24
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-022-20710-3
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Ammoniacal nitrogen and COD removal from semi-aerobic landfill leachate using a composite adsorbent: fixed bed column adsorption performance.

    Halim, Azhar Abdul / Aziz, Hamidi Abdul / Johari, Megat Azmi Megat / Ariffin, Kamar Shah / Adlan, Mohd Nordin

    Journal of hazardous materials

    2010  Volume 175, Issue 1-3, Page(s) 960–964

    Abstract: The performance of a carbon-mineral composite adsorbent used in a fixed bed column for the removal of ammoniacal nitrogen and aggregate organic pollutant (COD), which are commonly found in landfill leachate, was evaluated. The breakthrough capacities for ...

    Abstract The performance of a carbon-mineral composite adsorbent used in a fixed bed column for the removal of ammoniacal nitrogen and aggregate organic pollutant (COD), which are commonly found in landfill leachate, was evaluated. The breakthrough capacities for ammoniacal nitrogen and COD adsorption were 4.46 and 3.23 mg/g, respectively. Additionally, the optimum empty bed contact time (EBCT) was 75 min. The column efficiency for ammoniacal nitrogen and COD adsorption using fresh adsorbent was 86.4% and 92.6%, respectively, and these values increased to 90.0% and 93.7%, respectively, after the regeneration process.
    MeSH term(s) Adsorption ; Aerobiosis ; Ammonia/chemistry ; Biodegradation, Environmental ; Bioreactors ; Nitrogen/chemistry ; Oxygen/chemistry ; Refuse Disposal/methods ; Soil Pollutants/isolation & purification ; Time Factors ; Waste Disposal, Fluid/methods ; Water Pollutants/isolation & purification ; Water Pollutants, Chemical/chemistry ; Water Pollutants, Chemical/isolation & purification ; Water Purification/methods
    Chemical Substances Soil Pollutants ; Water Pollutants ; Water Pollutants, Chemical ; Ammonia (7664-41-7) ; Nitrogen (N762921K75) ; Oxygen (S88TT14065)
    Language English
    Publishing date 2010-03-15
    Publishing country Netherlands
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 1491302-1
    ISSN 1873-3336 ; 0304-3894
    ISSN (online) 1873-3336
    ISSN 0304-3894
    DOI 10.1016/j.jhazmat.2009.10.103
    Database MEDical Literature Analysis and Retrieval System OnLINE

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